Cenozoic folding in the Cumuruxatiba basin,Brazil: An approach to the deformation trigger by the Abrolhos magmatism

The Cumuruxatiba basin is located in the central portion of the eastern Brazilian margin surrounded by Cenozoic magmatic highs that belong to the Abrolhos Magmatic Complex. This basin was formed by rifting, in the Neocomian followed by thermal subsidence during late Cretaceous like other basins along the Eastern Brazilian margin. In the Cenozoic, the Abrolhos magmatism took place as sills and dykes intruded the sedimentary section, primarily during the Paleogene. In that time, there was a strong NS contractional deformation in the basin represented by folds related to reverse faults coeval with Abrolhos magmatism activity. The structural restorations of regional 2D seismic sections revealed that most of the contractional deformation was concentrated at the beginning of the Cenozoic with maximum peak at the Eocene (up to 33% of total shortening and rate of 6 km/Ma). The Post-Eocene period was marked by a decrease in the strain rate that continues to the present day (around 4 km/Ma to less than 1). 3D structural modelling exhibited a major, well-developed E–W to NE–SW fold belt that accommodated most of the contractional Cenozoic deformation between Royal Charlotte and Sulphur Minerva magmatic highs. Volcanic eruptions and magmatic flows from the Abrolhos complex resulted in differential overburden on edge of the basin, acting as a trigger for halokinesis and the subsequent formation of fault-related folds. In general, such structures were developed close to adjacent magmatic highs, commonly exhibiting vergence towards the centre of the basin. Some magmatic features formed coeval with Cenozoic syn-deformation sediments clearly indicate that Abrolhos magmatism activity and contractional deformation development were associated. The study of the thickness variation of the syn-deformation section in relation to fault-related folds on deformation maps and maximum strain diagrams revealed that most folds were activated and re-activated several times during the Cenozoic without a systematic kinematic pattern. This lack of systematic deformation might be related to the variation of the magmatic pulse activity of adjacent magmatic highs resulting in a complex interference pattern of Cenozoic folds. These structural interpretations of the timing of fault-related folds that are potential Cenozoic traps in the Cumuruxatiba basin play a fundamental role in petroleum systems and exploration of low-risk hydrocarbon prospects.     

Lacustrine basin unconventional resource plays: Key differences

There has been a revival in hydrocarbon source rock characterization and development associated with growing interest in unconventional resources, where these fine-grained organic-rich rocks act as both source and reservoir. To-date, the exploration focus on shale reservoirs has been largely on marine systems. Lacustrine source rocks for conventional resources are geographically important, dominating regions such as China, Indonesia, and Brazil's resource-base. However, they have been generally untested for unconventional resources.There are a number of key differences in the nature of these hydrocarbon systems that should be considered when assessing whether lacustrine systems may represent future unconventional opportunities in areas where the conventional resource-base is dominated by lacustrine-sourced oil. Among the key differences between these depositional systems is the greater sensitivity to high frequency climatic variability within lacustrine systems. Lacustrine systems are highly sensitive to changes in the balance between precipitation and evaporation, which may lead to rapid changes in lake level, potentially exceeding 600 m. These changes in depositional conditions are geologically rapid and may occur over periods of thousands of years. Such changes can reduce the areal extent of potentially thick source rock intervals to only those portions of a basin where a permanent deep lake was present. Thus the core unconventional target area may be geographically limited compared with their marine counterpart. Although potentially areally limited, a review of many lacustrine source rocks suggests that their thicknesses are often significantly greater than marine source rocks. An examination of the more distal portions of lacustrine systems, where better source rock potential is present reveals that there is generally limited connectivity between source and conventional reservoir. In these settings, such as the Wind River basin (Waltman Shale), the hydrocarbons remain trapped within the shales, potentially leading to over-pressured hydrocarbon charged systems. Such conditions suggest that although areally limited, viable unconventional targets may exist, if suitable reservoir conditions are present. Finally, the character of the oils produced is different in these settings, with lacustrine oils being waxy and displaying different hydrocarbon generation and cracking kinetics. High wax oils display distinct flow characteristics, being more viscous, and may offer different production challenges than their non-waxy marine equivalents. Additionally, differences in their cracking kinetics may indicate that the timing of gas generation for shale gas plays may differ significantly from marine systems.     

Organic geochemistry of marine source rocks and pyrobitumen-containing reservoir rocks of the Sichuan Basin and neighbouring areas,SW China

Three bitumen fractions were obtained and systematically analysed for the terpane and sterane composition from 30 Paleozoic source rocks and 64 bitumen-containing reservoir rocks within the Upper Sinian, Lower Cambrian, Lower Silurian, Middle Carboniferous, Upper Permian and Lower Triassic strata in the Sichuan Basin and neighbouring areas, China. These bitumen fractions include extractable oils (bitumen I), oil-bearing fluid inclusions and/or closely associated components with the kerogen or pyrobitumen/mineral matrix, released during kerogen or pyrobitumen isolation and demineralization (bitumen II), and bound compounds within the kerogen or pyrobitumen released by confined pyrolysis (bitumen III). In addition, atomic H/C and O/C ratios and carbon isotopic compositions of kerogen and pyrobitumen from some of the samples were measured. Geochemical results and geological information suggest that: (1) in the Central Sichuan Basin, hydrocarbon gases in reservoirs within the fourth section of the Upper Sinian Dengying Formation were derived from both the Lower Cambrian and Upper Sinian source rocks; and (2) in the Eastern Sichuan Basin, hydrocarbon gases in Middle Carboniferous Huanglong Formation reservoirs were mainly derived from Lower Silurian source rocks, while those in Upper Permian and Lower Triassic reservoirs were mainly derived from both Upper Permian and Lower Silurian marine source rocks. For both the source and reservoir rocks, bitumen III fractions generally show relatively lower maturity near the peak oil generation stage, while the other two bitumen fractions show very high maturities based on terpane and sterane distributions. Tricyclic terpanes evolved from the distribution pattern C₂₀ < C₂₁ < C₂₃, through C₂₀ < C₂₁ > C₂₃, finally to C₂₀ > C₂₁ > C₂₃ during severe thermal stress. The concentration of C₃₀ diahopane in bitumen III (the bound components released from confined pyrolysis) is substantially lower than in the other two bitumen fractions for four terrigenous Upper Permian source rocks, demonstrating that this compound originated from free hopanoid precursors, rather than hopanoids bound to the kerogen.     

Evaluating the mechanical compaction of quartzarenites: The importance of sorting (Llanos foreland basin,Colombia)

Mechanical compaction is the main porosity-reducing process in sandstones, including high-reservoir-quality rigid-grain sandstones. For such sandstones, the extrapolation of theoretical or experimental compaction algorithms needs calibration with rocks having well constrained burial histories. Evaluating the compaction of these rocks is achieved by comparing current intergranular volume (IGV) with depositional IGV, which is strongly dependent on sorting. However, because sandstone sorting is difficult to measure accurately, its impact on depositional porosity and compaction state is largely underestimated. We use the quartzarenites of the Oligocene Carbonera Formation in the subsurface of the hydrostatically-pressured Llanos basin to illustrate the importance of sorting when evaluating the compaction of rigid-grain sandstones. IGV and sorting were measured in core samples using a combination of transmitted-light and cathodoluminescence images, resulting in improved accuracy over standard procedures. The compaction state of clean quartzarenites at given depths is best described using IGV-versus-sorting plots, which are used to derive compaction curves for specified sorting values. The IGV-versus-sorting trends are displaced to lower IGV values with increasing burial depth. The differences in IGV caused by differences in sorting exceed the differences in IGV resulting from 1000 m of burial, illustrating the high impact of sorting when evaluating compaction. Contrasting with published experimental results, the compaction of the Llanos basin ductile-grain-poor quartzarenites is independent of grain size, and grain rearrangement is the main compaction mechanism during the first ∼1.6 km of burial. Based on the Llanos data, we have generated IGV-versus-depth curves for clean pure quartzarenites of specific sorting, which can be used to predict their maximum primary porosity up to moderate burial depths. Differences with other published burial curves are probably related to unaccounted variations in sorting, ductile-grain content and framework-strengthening cements. However, the Llanos basin quartzarenites contain virtually no cements, explaining their high degree of compaction relative to other rigid-grain sandstones, and making them ideal to isolate the effects of compaction on the IGV of quartzarenites. The Llanos basin data suggest that, below ∼2.5 km of depth, clean well- to moderately well sorted quartzarenites continue reducing their IGV by mechanical compaction below the 26% limit, which should apply only to extremely well sorted, rigid grain, uncemented sandstones.     

南黄海盆地中部隆起的形成与演化

南黄海盆地是在前震旦系克拉通基础上发育的中、古生界海相与中、新生界陆相多旋回叠合盆地。通过地震资料解释,结合邻区钻井与区域地质资料,对南黄海盆地中部隆起中、古生代地层及其形成演化进行了研究,结果表明,南黄海盆地中部隆起沉积了较全的中、古生界海相地层,发育第四系—新近系、中—下三叠统青龙组、上二叠统、下二叠统—上泥盆统、中—下志留统,奥陶系—震旦系和前震旦系变质岩系等7套地震地质层序;主要经历了前震旦纪基底形成、震旦纪—早古生代克拉通发育、晚古生代—中三叠世稳定台地—陆内裂陷、晚三叠世—古近纪形成与抬升剥蚀及新近纪-第四纪坳陷沉降5个阶段。     

海道测量水位改正通用软件研制

综合近几年海道测量水位改正的最新理论研究成果,以"海洋测量信息处理工程"软件系统为基础平台,根据直观性、通用性、可靠性等基本原则,开发了适用于单波束、多波束多种测深数据接口的海道测量水位改正通用软件,并从内、外符合精度方面对软件的水位改正效果进行了检验评估。     

港池泊稳的能量平衡方程数值模拟

对基于能量平衡方程的多向随机波浪传播数学模型进行改进,通过模拟不同防波堤绕射引起的港池泊稳,验证模型的合理性和有效性。利用非线性弥散关系提高模型计算浅水变形的精度;采用二次逆风差分格式离散控制方程,避免了加入绕射项引起的数值耗散;并将文氏谱加入模型中,使其更加适合中国海域的工程应用。应用改进后模型绘制的双突堤和岛式防波堤绕射系数图与我国《海港水文规范》图进行了对比。对比结果十分接近,可以较好地描述港池的泊稳状况,为综合计算波浪在近岸的浅水变形、折射、绕射、反射和能量耗散等作用奠定了基础。     

因子分析在海河流域石油类污染综合评价中的应用(英文)

基于因子分析对2012~2013年海河流域pH、DO、COD、BOD5、氨态氮和总石油烃等6项水质指标的监测数据进行统计,并对其中四项指标进行水污染综合指数评估,旨在对海河水质进行较为系统的评价。结果显示,BJ1和HB2两个站位水质属于Ⅳ类标准,其余各站位均为Ⅴ类;各站位综合评价结果得到海河流域指数为1.44,说明海河流域处于污染状态,其污染程度超过该流域功能区的标准。因子分析发现,COD、DO和NH3-N之间差异显著(P0.05);主成分分析显示,除pH和BOD5外,其余指标都在0.70以上;COD、DO、NH3-N和TPH的贡献率较高,其中总石油烃的贡献率为100%,因此可以认为该海域的污染类型属于有机污染,且石油烃污染较为突出。     

哈拉哈塘地区东河砂岩段-角砾岩段沉积模式探讨

塔北的哈拉哈塘地区是东河砂岩油气勘探的重点地区,该地区目前已发现并探明了东河塘和哈得4两个东河砂岩油气藏,油气储量丰富,显示出良好的勘探前景。基于哈拉哈塘地区东河砂岩段和角砾岩段的岩性段穿时沉积现象异常明显,根据层序地层学原理和方法对哈拉哈塘地区东河砂岩段一角砾岩段进行了重新分层和对比,在层序分层等时地层框架的基础上重新进行了东河砂岩段一角砾岩段沉积模式研究,弄清该地区地层分布规律、演化规律、砂体分布及储层分布规律对该地区的油气勘探具有重要指导意义。     

Molecular and isotopic compositions of bitumens in Silurian tar sands from the Tarim Basin,NW China: Characterizing biodegradation and hydrocarbon charging in an old composite basin

Biodegradation and oil mixing in Silurian sandstone reservoirs of the Tarim Basin, one of the largest composite basins in China, were investigated by analyzing the molecular characteristics and stable carbon isotopic signatures of low-molecular-weight (LMW) saturated hydrocarbons and high-molecular-weight (HMW) asphaltenes. Detection of 25-norhopanes and 17-nortricyclic terpanes in most Silurian tar sands from the Tabei Uplift in the Tarim Basin suggests a much greater degree of biodegradation here than in the Tazhong Uplift. This explains the relatively more abundant tricyclic terpanes, gammacerane, pregnane and diasteranes in tar sands from the Tabei Uplift than in those from the Tazhong Uplift. Hence, care must be taken when assigning oil source correlations using biomarkers in tar sands because of the biodegradation and mixing of oils derived from multiple sources in such an old composite basin. Asphaltenes in the tar sands seem to be part of the oil charge before biodegradation, depending on the relative anti-biodegradation characteristics of asphaltenes, the similarity in carbon isotopic signatures for asphaltenes and their pyrolysates, and the consistent product distribution for flash pyrolysis and for regular steranes in asphaltene pyrolysates, regardless of whether the tar sands were charged with fresh oil. According to the relative distributions of regular steranes and the relatively abundant 1,2,3,4-tetramethylbenzene significantly enriched in ¹³C, the oil sources for asphaltenes in the tar sands might be related to lower Paleozoic marine source rocks formed in euxinic conditions. Nevertheless, the relatively low abundance of gammacerane and C₂₈ regular steranes observed in asphaltene pyrolysates and residual hydrocarbons, within limited samples investigated in this work, made a direct correlation of oils originally charged into Silurian tar sands with those Cambrian source rocks, reported so far, seem not to be possible. Comparison of carbon isotopic signatures of n-alkanes in asphaltene pyrolysates with those of LMW saturated hydrocarbons is helpful in determining if the abundant n-alkanes in tar sands are derived from fresh oil charges after biodegradation. The limited carbon isotopic data for n-alkanes in LMW saturated hydrocarbons from the tar sands can be used to classify oils charged after biodegradation in the composite basin into four distinct groups.