我国矿区棕地综合治理及再利用

矿区土地治理与再利用是一项紧迫的任务,由于多年的矿产开采,导致矿区的大面积土地破坏和废弃,土壤及地下水污染,从而形成了矿区棕地并造成大量的土地价值损失,加剧了矿区的人地矛盾。因此,研究棕地这一类特殊土地的再利用对于矿区的可持续发展具有重要的现实意义。通过分析国内外矿区棕地研究相关理论与方法,结合我国矿区棕地的现状,探讨了矿区棕地综合治理的方案和措施。建议我国矿区棕地治理和再利用方案框架可划分为调查评价、生态修复和土地复垦与景观再造3个阶段：调查评价阶段主要包括棕地土壤环境质量评价与可持续利用评价;生态修复阶段可选择适宜的技术方法进行污染土壤和地下水修复;土地复垦与景观再造阶段是根据矿区棕地类型及分布特点,因地制宜,进行棕地复垦和综合治理利用。同时讨论了每个阶段的主要工作内容和措施,比较了不同修复技术方法的优劣,给出了我国矿区棕地复垦和综合利用的模式建议。     

陕北环境地质条件脆弱区黄土滑坡的勘察与治理

陕北环境地质条件脆弱区某330kV变电站在大面积挖填方施工过程中,填方区内出现了多条拉张与剪切裂缝,工程被迫停工,需查明原因。通过大范围工程地质测绘、钻探、井探、槽探与多种方法的抗剪强度试验以及稳定性分析计算,查明该场地选在了一个稳定性程度不高、滑面呈直线形的大型古滑体上,滑面为黄土与砂泥岩接触面,滑面倾角与滑动方向同单斜构造的岩层产状(300°～310°∠8°～12°),场地前缘出露的砂泥岩非原状基岩而为滑坡堆积物。堆积物的存在阻断了坡体降水的排泄通道,致使滑面以上形成大范围的软弱土层,且工程施工时的大面积挖填方破坏了古滑坡的原有力学平衡,导致局部复活,形成了3个不稳的工程滑坡。得出了在环境地质条件脆弱区进行工程建设时应重视选址勘察,单斜构造上滑面呈直线形的黄土与砂泥岩接触面滑坡稳定性计算采用饱和残剪的抗剪强度参数(c=6.6kPa,φ=5.6°)是可行的,对剪出口在沟谷中的黄土滑坡采用既能增加耕地又能改善当地生态环境的淤地坝与局部支挡等综合治理方案有广阔的前景。     

Influence Factors on the In-situ Remediation of Halogenated Organic Compounds by Nanoscale Zerovalent Iron

The pollution of soil and groundwater by halogenated organic compounds (HOCs) is more and more severe. HOCs are of strong toxicity and difficult to be biodegraded. Due to its unique advantages, nanoscale zerovalent iron (NZVI) has become a hot research topic in the field of in situ remediation around the world. In this paper, basic reaction theories and kinetics of HOCs degradation by NZVI are briefly summarized. The influence factors on the in situ remediation of HOCs by NZVI are comprehensively discussed. The influence factors include the intrinsic properties of NZVI due to its different preparation and modification methods, and environment factors, such as pH, dissolved oxygen, ionic species, metals, nonreactive hydrophobic and natural organic compounds, concentrations and components of HOCs, microorganisms and subsurface heterogeneity. The effects of all these factors on NZVI stability, deliverability, targeting ability, and reactivity during in situ remediation are emphasized. Finally, the practical application of this technology are summarized and prospected.     

过硫酸钠修复土壤中多环芳烃的准确测定

多环芳烃(PAHs)是一类具有致癌、致突变、致畸的碳氢化合物,具有较高的辛醇-水分配系数,易被土壤颗粒吸附而影响环境和人体健康。过硫酸钠(Na₂S₂O₈)氧化法是近些年来国内外修复PAHs污染土壤较为常用的方法,但现阶段在测定修复后土壤中PAHs含量、进行土壤修复效果评估时亟待解决的问题是：经该方法修复的土壤,若土壤中残留有过硫酸钠,在样品前处理过程中由于提取温度较高,可能会进一步加速多环芳烃的氧化反应,从而影响土壤中PAHs的准确测定。本文建立了一种在修复后土壤中加入还原剂抗坏血酸,与残留的过硫酸钠反应生成脱氢抗坏血酸,采用索氏提取结合气相色谱-质谱法(GC-MS)同时测定土壤中16种PAHs的方法,PAHs加标回收率为76.2%～110.0%。而修复后土壤若不加还原剂直接进行索氏提取,用GC-MS测定,可能会使部分PAHs及替代物的测定不准确,PAHs加标回收率仅为6.0%～72.4%。通过对比分析表明,在样品提取前加入还原剂,可以有效地消除残留过硫酸钠的影响,提高测定修复后土壤中PAHs含量的准确性。     

过硫酸盐氧化修复后土壤对建筑物的腐蚀性分析

过硫酸盐作为良好的氧化剂被广泛应用于有机污染土壤的修复领域,但残留的过硫酸盐和氧化反应产生的副产物对建筑物的混凝土和钢结构产生的腐蚀性影响往往被忽视.通过对某多环芳烃类土壤污染地块修复前后的土壤相关指标的分析检测,分析了该地块污染土壤采用过硫酸钠体系修复后对建筑材料的腐蚀性产生的影响.实验结果表明,修复后土壤对混凝土和...     

天然有机质对纳米零价铁去除水中六价铬的影响

应用纳米零价铁进行地下水污染治理是近年迅速发展的环境修复新技术,但在实际应用中,纳米零价铁的反应活性受到环境条件的影响,其中自然界中广泛存在的天然有机质就是重要影响因素。通过批实验研究腐殖酸(天然有机质代表物)对纳米零价铁去除水中六价铬的影响,结果表明,腐殖酸的存在能够极大地抑制纳米铁去除六价铬的反应速度和去除效率,原因在于纳米铁对腐殖酸具有一定的吸附作用,从而减少了纳米铁表面的有效活性位点,降低了对六价铬的作用。此外发现,水体中溶解氧的存在有利于纳米铁对六价铬的去除。关于腐殖酸-纳米零价铁-六价铬的相互作用研究,对于进一步揭示修复体系作用机制具有重要的理论和应用价值。     

Spatial variability of soils and stream sediments and the remediation effects in a Portuguese uranium mine area

The old Senhora das Fontes uranium mine, located in central Portugal, was closed down in 1971. The treatment of ores from this mine and other mines by heap-leach ended in 1982. Seven dumps partially covered by vegetation were left in the area. Soil and stream sediment samples were collected in December 2009. The remediation was carried out from May 2010 to January 2011. Stream sediment samples were collected again in October 2013. Before the remediation, soils from inside the mine influence area have higher Al, As, Co, Cr, Cu, Fe, Ni, Sr, Th, U and Zn concentrations than soils from outside this area, due to radionuclides, metals and metalloid released from the mine dumps. The principal component analysis (PCA) shows a distinction between soils from inside and outside the mine influence area. The U(VI), As(V) and metals from soils can be adsorbed to Fe-oxyhydroxides and the humic acid can increase the U uptake. Soils must not be used for public or private green and residential areas, because they are contaminated in U, As, Co, Cd and Ni. Before the remediation, downstream sediments have higher Al, As, Cu, Mn, Ni, Pb, U and Zn than upstream sediments, due to erosion and percolation of water through the mine dumps. The PCA shows a distinction between downstream and upstream sediments. The U(VI), Th and As(V) can be adsorbed to Fe-oxyhydroxides. The stream sediments are contaminated in As, Mn, Th and U. Downstream sediments are the most contaminated in U and As. After the remediation, upstream and downstream sediments have generally higher Al, Fe, As, Cr, Ni, Th, U and Zn concentrations than before the remediation, attributed to the relocation of dumps. Radionuclides, metals and metalloids were transported by surface water. Consequently downstream sediments have higher Al, As, Cu, Mn, Ni, Th, U and Zn concentrations than upstream sediments. The U(VI), Th and As(V) can be adsorbed to Fe-oxyhydroxides. Stream sediments became more contaminated in U, Th and As than before the remediation, but more intensively downstream.     

基于行为与结果的土地整治项目绩效评价研究

目前我国土地整治项目绩效评价研究多基于项目实施评价或项目效益评价,缺乏可操作性。该文将实施者的行为过程与实施结果相结合,对土地整治项目绩效评价的内涵及内容进行界定,分别从土地整治项目的实施绩效(包括资金使用、管理规范、工程实施等情况)及效益绩效(包括经济效益、社会效益和生态效益)构建了土地整治项目绩效评价体系,并以河南省两个典型土地整治项目为例进行实证研究。将土地整治项目的实施评价与效益评价相结合,便于较全面地对项目进行绩效评价,所构建的指标体系基本合理。     

凹凸棒石用于修复铜锌镉重金属污染土壤的研究

利用凹凸棒石黏土矿物优异的物化性能对采集的安徽铜陵地区重金属污染土壤进行盆栽修复试验,以降低种植蔬菜中重金属污染物的有效态含量。凹凸棒石与矿区土壤的质量配比设置5组(1∶10、1∶20、1∶40、1∶100以及原土),选择适宜在北京生长的四季小白菜和北京快菜进行种植,盆栽试验结果表明,使用凹凸棒石黏土矿物可以将土壤的pH值提高到5～8,改善了矿区的土壤环境条件,提高黏土矿物对重金属的吸附性能;通过适量添加凹凸棒石黏土矿物,对Cu元素的平均修复率达到31.50%,Zn元素的平均修复率达到26.15%,Cd元素的平均修复率达到34.92%,能够有效减少蔬菜对Cu、Zn、Cd三种重金属元素的吸收。凹凸棒石与土壤的质量比为1∶20时,对污染土壤的修复效果最佳。