中国北方裂隙岩溶不资源开发和保护中若干问题的研究

我国由于人口多、水资源贫乏,裂隙岩溶水成为北方重要的供水不源。本文从裂隙岩溶水和裂隙岩溶含水层的水力特性出发,研究了裂隙岩溶水井的成井深度,裂隙岩溶水资源的特点,补给量和储存量对水资源开发的影响,裂隙岩溶含水层中污染物的运移特征和治理对策以及城市总体规划或选厂址时如何保护裂隙岩溶水资源等问题。本文以解决实际应用问题为目的,从地下水水力学的角度研究中国北方的裂隙岩溶水的开发和保护。     

环境介质中高氯酸盐污染及微生物修复技术研究进展

高氯酸盐(ClO4-)是一种有毒的无机阴离子,其环境污染问题引起了广泛关注,控制与修复高氯酸盐污染环境成为新的研究热点,其中微生物修复技术最具应用前景。国外已开展环境中高氯酸盐污染现状的调查工作,利用微生物修复技术去除高氯酸盐取得了一定的成果,但我国的相关研究较少。文章综述了近年来国内外高氯酸盐的污染现状及微生物修复高氯酸盐的最新研究进展。由于高氯酸盐的高水溶性和低吸附性,当前研究最多的是高氯酸盐水体污染,这些水体通过饮用水(源水)或食物链直接或间接地对人类健康造成影响。在微生物修复方面,从有机电子供体,无机电子供体(H2、Fe0等),电子受体(O2、NO3-、SO24-)及微生物的生长环境因素(pH值、温度、氧化还原电位、盐度)等方面总结了各因素对微生物修复技术去除高氯酸盐效果的影响,以期为我国开展微生物处理技术在高氯酸盐污染修复领域的实践应用提供参考。     

Bioavailability of crops to environmental hormone Pb in soils and its remediation

Lead （Pb）, as an environmental hormone, acts as an estrogen in animal and human bodies, and its environmental pollution can result in many procreant anomalies, such as maladjustment of incretion, weakening of procreation function and descending of genital immunity. Experiments on pot-growth of paddies and corns in this study indicated that these crops did not show any macro-toxic symptoms in the observed contents of Pb added （0-4000 mg/kg） in soils. However, lead in soils can be easily absorbed by crops and accumulated in the different parts of plants. Statistical analysis showed that Pb contents in the crops are strongly positively correlated to the Pb contents in soils. In the crops, the Pb contents of roots are highest, tens to thousands of times those of straws and seeds. It is suggested that the root is a barrier of Pb absorbed by straws and seeds. Based on this fact, Pb pollution in soils can be gradually reduced by planting crops and subsequently removing the roots from the soil. This biotechnology may be used in environmental remediation, which embraces the quality of sustainable agricultural economy and a healthy environment.     

不同微生物肥对植烟区镉污染土壤的修复效果

为研究不同微生物肥对土壤中Cd的钝化效果和烟叶Cd含量的影响,选取南方植烟区3种不同类型(红泥田、黄泥田及青紫泥田)Cd污染土壤,以南方主栽烤烟云-87和K-326为测试品种,采用盆栽试验,测定了3种微生物肥(DY、AMS和HMD)在不同浓度下对烟草生物量、不同部位烟叶Cd含量、土壤Cd形态以及土壤中微生物种类的影响。结果表明：(1)3种微生物肥均能增加烟叶生物量,其中HMD增重效果最好。(2)与对照相比,3种微生物肥能有效地降低土壤中Cd的有效性和烟叶Cd的含量。针对3种土壤施用微生物肥浓度为1.5%时,叶片中Cd的降Cd率(与对照相比)分别达到17.2%~63.9%、20.4%~58.3%及18.9%~48.3%,DTPA-Cd下降比例分别为13.8%~17.3%、17.2%~22.8%及12.8%~16.2%;而随着施用微生物肥浓度增加到3.0%后,上述土壤烟叶中Cd的降Cd率显著增加,分别为20.3%~59%、31.3%~66.6%及25.2%~56.1%,DTPA-Cd下降比例分别为15.5%~28.2%、19.6%~26.6%及13.8%~17.3%。HMD效果最好,其次为DY和AMS。(3)3种微生物肥都增加土壤中微生物种类和数量,优化了烟草生长环境。总体来说,该植烟区土壤,DY和HMD增加产量的同时降Cd效果较好,可以在大田推广使用。     

安徽铁炉地区放射性污染调查分析及防治措施

对安徽东至县铁炉地区开展了放射性污染调查工作,并提出了防治方案和治理措施。其方法是采用6台FD-3013γ辐射仪、1台FD-3022N道γ谱仪和1台FD-3017氡射气仪对该地区进行大比例尺地面γ辐射剂量率、地面γ能谱、水中氡浓度等测量。获得了该地区γ辐射剂量率为0．11～4.38μGy/h;铀质量活度为123-1 230Bq／kg,钍质量活度为21-411 Bq/kg,钾质量活度为264-528Bq／kg;水中铀活度浓度为4-12 300 Bq／L,水中氡活度浓度为2-155Bq／L;剥露的岩矿、矿渣中铀质量活度为1230-151 290 Bq／kg,钍质量活度为25-411 Bq／kg。该地区地面γ辐射剂量率、地层中铀、钍质量活度均高于安徽省平均值,而剥露的岩矿、矿渣中铀质量活度远大于地层中的铀质量活度,是该地区环境中最大的潜在污染源之一,并为此提出了4项治理措施。     

用生态修复调控浮游植物种群局部控制富营养化——以贵州红枫湖水质生态修复工程为例

利用物理生态工程在水深10 m左右,水位变幅7 m左右的贵阳红枫湖/水库(正常水位时57.2 km2)右二湾富营养水体进行局部(围隔水体面积1.33 hm2)生态修复.对工程前后和内外水体浮游植物的群落结构、丰度、生物量等进行比较,结果表明,当植物浮岛覆盖率超过1/5～1/3时(可视为阈值),物理生态工程可以调控浮游植物种群结构和丰度,浮游植物优势种群由生态修复前的微囊藻属、角甲藻属及同期外环境的蓝藻门蓝纤维藻属转变为硅藻门的直链藻属.工程内与工程外比较,种属数减少了29.4%,特别是减少了蓝藻中可能释放藻毒素的微囊藻、鱼腥藻等属,蓝藻丰度和生物量分别减少了55.5%和57.9%;而硅藻的种属数则增多120.0%,且其丰度和生物量分别增加了56.4%和60.3%.从藻类总体统计资料看,工程内与工程外比较,藻类丰度减少53.6%,生物量减少39.1%,透明度提高了数十厘米以上,稳定在120～220 cm.当工程区外浮游植物优势种群是蓝藻,暴发蓝藻水华,且可释放藻毒素的种属有多次检出时,工程区内仍然以硅藻为优势种,未曾检测出可释放藻毒素的种属,从而在红枫湖局部水体实现了水质改善和富营养化控制.在目前高污染负荷下恢复浅水湖泊沉水植被时,本项目发展的可全年镶嵌式种植包括香根草、杞柳等高杆植物在内的多种水面植物的浮岛可作为防浪削浪、遏制蓝藻、改善水质、提高透明度的先锋性措施,以保障局部水面植被覆盖面积超过上述阈值,成为保护沉水植物生长、遏制暴发蓝藻水华的可操作途径.     

Surfactant-enhanced remediation of contaminated soil: a review

Extracting aqueous solutions with or without additives are employed to solubilize contaminants in soil. Since water solubility is the controlling removing mechanism, additives are used to enhance efficiencies. These additives can reduce the time to treat a site compared to the use of water alone. Additives must be of low toxicity and biodegradable. The research in this area has focussed mainly on halogenated volatile organic compounds (VOCs) and is still quite limited for metal removal. Additives include surfactants, organic and inorganic acids, sodium hydroxide, which can dissolve organic soil matter, water-soluble solvents such as methanol, displacement of cations with nontoxic ones, complexing agents such as EDTA, acids in combination with complexing agents or oxidizing/reducing agents. Cationic, anionic and nonionic surfactants are particularly used for soil washing or flushing. They contain both hydrophobic and hydrophilic portions, making them ideal for solubilization of hydrophobic compounds. Numerous studies have indicated that surfactants enhance recoveries of non-aqueous phase liquids (NAPLs). There have also been indications that pretreatment of soil with surfactant washing to solubilize hydrophobic compounds such as PAHs enhances biodegradation of these contaminants. A few in situ field studies have been performed with surfactants. Large-scale treatment has been done mostly for organic removal. Soil pH, soil type, cation exchange capacity (CEC), particle size, permeabilities and contaminants all affect removal efficiencies. High clay and organic matter contents are particularly detrimental. Understanding the chemistry of the binding of the contaminant and the hydrogeology of the site are very important. Once the water is pumped from the soil, it must be extracted and then treated to remove the hydrocarbons and metals. Several technologies exist such as sodium hydroxide or sodium sulfide precipitation, ion exchange, activated carbon adsorption, ultrafiltration, reverse osmosis, electrodialysis and biological processes. Recycling of the surfactants is desired to decrease treatment costs.

This paper will provide an overview of the laboratory research, field demonstration and full-scale application of surfactants for the remediation of contaminated soil. The majority of pilot scale in situ flushing tests, particularly in the United States, have involved the use of surfactants and co-solvents. There are only a few full-scale projects however. Recent laboratory scale efforts by the authors concerning the use of biosurfactants, biologically produced surfactants, to enhance the removal of copper, cadmium and zinc from contaminated soils and sediments are discussed. Three types of biosurfactants were evaluated for their effectiveness. They included a lipopeptide called surfactin from Bacillus subtilis, a rhamnolipid from Pseudomonas aeruginosa and a sophorolipid from Torulopsis bombicola. The results indicated the feasibility of removing the metals with the anionic biosurfactants even though the exchangeable fractions were not significant.     

南疆铁路K230段冻土区滑坡泥石流勘察整治

本文结合南疆铁路K230滑坡、泥石流的勘察与治理工程设计,深入分析了冻土地区滑坡的成因,滑面特性,泥石流产生的原因等,进而针对原因分析提出了采用对原地层扰动较小的锚索框架治理滑坡、采用拦挡坝治理泥石流,且采用保温盲沟疏排地下水的综合治理措施。该段地质病害的成功治理,对类似冻土地区地质病害的勘察与整治具有一定的借鉴意义。     

空气扰动技术修复氯苯污染地下水的影响因素研究

通过实验室一维砂柱模拟研究了不同影响因素下空气扰动技术(air sparging,AS)修复氯苯污染地下水的效果,包括介质渗透性、曝气方式、共存污染物、残余饱和态氯苯。结果表明:介质渗透性极大地影响着AS的效果,渗透系数越大,去除效果越好。对渗透系数为10-5m/s数量级及其以下的介质应用AS较为困难;在曝气时间相同的情况下,对于渗透系数为5.1×10-4m/s的中砂,脉冲曝气较连续曝气效果好,对于渗透系数为6.2×10-3m/s的粗砂,2种曝气方式效果相仿;苯和氯苯共存时各污染物的去除存在协同作用;AS对残余饱和态氯苯的去除存在着明显的拖尾效应。     

汶川大地震诱发地质灾害主要类型与特征研究

“5．12”汶川大地震诱发了数以万计的次生地质灾害,对灾区人民生命财产安全构成严重威胁,并成为影响灾区灾后恢复重建的重要因素之一。本文在对汶川I地震区地质灾害进行大量现场调查的基础上,结合室内分析模拟,对汶川地震诱发的滑坡、崩塌、不稳定斜坡（震裂山体）和泥石流等主要次生地质灾害的主要类型及特征进行了较系统地分析研究。结果表明,强震诱发滑坡灾害发生特点与岩性结构和地形条件有较明显的关系,在硬岩、软岩和松散堆积物分布区,滑坡的启动、运动和停积形式有较大的差别,但总体上都具有高速、高动能、强大动力等特征。强震诱发的崩塌主要包括高位大型崩塌;小规模块石崩落、抛射;崩塌诱发大规模滑坡3类。强震条件下大多数崩塌都表现出一定的水平抛射特征。强烈的地震动力使极震区众多山体大范围震裂松动,形成了大量震裂山体。这些震裂山体的地表裂缝具体又可细分为断裂裂缝、震裂裂缝和滑裂裂缝3类。汶川地震形成了巨量泥石流物源,再加上震后泥石流爆发的临界降雨量大大降低,其启动和运动方式发生明显改变,在今后数年内,泥石流将是影响灾区恢复重建的最大地质灾害隐患,应高度重视,采取切实有效措施加以防范。