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111.
112.
We collected surface water along the 142nd E meridian from Tasmania to Antarctica in December 1999. We measured temperature,
salinity and total chlorophyll a; additionally, we collected suspended particle size fractions and used fluorometric analysis to determine the quantity of
chlorophyll a in each of four cell size classes: picoplankton (<3 μm), two nanoplankton fractions (3–10 μm and 10–20 μm) and microplankton
(> 20 μm). Changes in temperature and salinity show that we crossed 6 water masses separated by 5 fronts. We found low abundance
(<0.2 mg m−3) of chlorophyll in all size classes, with the exception of higher values near the continent (0.2 to 0.4 mg m−3). Lowest chlorophyll values (<0.1 mg m−3) were found in the Polar Frontal Zone (51° to 54°S). Microplankton made up the largest portion of total chlorophyll throughout
most of the region. We conclude that biomass of all phytoplankton fractions, especially pico-and nanoplankton, was constrained
by limiting factors, most probably iron, throughout the region and that ecosystem dynamics within a zone are not circumpolar
but are regionalized within sectors. 相似文献
113.
The photochemical instability of several related pteridines in seawater was investigated by aseptic incubation of solutions at 20–22°C under illumination from cool-white light of intensity 6 kerg cm−2 sec−1, and the chemical changes were spectrophotometrically monitored. All the pteridines showed markedly accelerated degradation from this illumination relative to their behaviour in total darkness.Pterin and lumazine were degraded very slowly with zero-order reaction kinetics, while the other pteridines photolysed rapidly (according to first-order kinetics) with decomposition rates increasing in the order dioxylumazine (2,4,6,7-tetrahydroxypteridine) < leucopterin < isoxanthopterin < xanthopterin < oxylumazine (2,4,6-trihydroxypteridine). Excepting leucopterin and dioxylumazine, the photolysis rates were attributable to the pH of seawater and not its salt content; this was also the case with oxylumazine which required the salt content of seawater for decomposition in darkness. Leucopterin and dioxylumazine (both 6,7-dihydroxylated pteridines) gave evidence of complexation with the major divalent cations (Ca2+, Mg2+) of seawater, by virtue of which their photolytic degradation rates were enhanced to magnitudes obtained in pH-10 buffer without seawater. It is proposed that such complexation produces structural forms of these pteridines analogous to their normal ionic forms at pH 10–12.The photolysis of the 6-hydroxylated pteridines (xanthopterin, oxylumazine) proceeded via intermediate formation of their corresponding 7-hydroxylated derivatives (leucopterin, dioxylumazine). 相似文献
114.
115.
The ridge located between 31° S and 34°30′S is spreading at a rate of 35 mm yr−1, a transitional velocity between the very slow (≤20 mm yr−1) opening rates of the North Atlantic and Southwest Indian Oceans, and the intermediate rates (60 mm yr−1) of the northern limb of the East Pacific Rise, and the Galapagos and Juan de Fuca Ridges. A synthesis of multi-narrow beam,
magnetics and gravity data document that in this area the ridge represents a dynamically evolving system. Here the ridge is
partitioned into an ensemble of six distinct segments of variable lengths (12 to 100 km) by two transform faults (first-order
discontinuities) and three small offset (< 30 km) discontinuities (second-order discontinuities) that behave non-rigidly creating
complex and heterogeneous morphotectonic patterns that are not parallel to flow lines. The offset magnitudes of both the first
and second-order discontinuities change in response to differential asymmetric spreading. In addition, along the fossil trace
of second-order discontinuities, the lengths of abyssal hills located to either side of a discordant zone are observed to
lengthen and shorten creating a saw-toothed pattern. Although the spreading rate remains the same along the length of the
ridge studied, the morphology of the spreading segments varies from a deep median valley with characteristics analogous to
the rift segments of the North Atlantic to a gently rifted axial bulge that is indistinguishable from the shape and relief
of the intermediate rate spreading centers of the East Pacific Rise (i.e., 21°N). Like other carefully surveyed ridge segments
at slow and fast rates of accretion, the along-axis profiles of each ridge segment are distinctly convex upwards, and exhibit
along-strike changes in relief of 500m to 1500 between the shallowest portion of the segment (approximate center) and the
segment ends. Such spatial variations create marked along-axis changes in the morphology and relief of each segment. A relatively
low mantle Bouguer anomaly is known to be associated with the ridge segment characterized by a gently rifted axial bulge and
is interpreted to indicate the presence of focused mantle upwelling (Kuo and Forsyth, 1988). Moreover, the terrain at the
ends of each segment are known to be highly magnetized compared to the centers of each segment (Carbotte et al, 1990). Taken
together, these data clearly establish that these profound spatial variations in ridge segment properties between adjoining
segments, and along and across each segment, indicate that the upper mantle processes responsible for the formation of this
contrasting architecture are not solely related to passive upwelling of the asthenosphere beneath the ridge axis. Rather,
there must be differences in the thermal and mechanical structure of the crust and upper mantle between and along the ridge
segments to explain these spatial variations in axial topography, crustal structure and magnetization. These results are consistent
with the results of investigations from other parts of the ridge and suggest that the emplacement of magma is highly focused
along segments and positioned beneath the depth minimum of a given segment. The profound differences between segments indicate
that the processes governing the behavior of upwelling mantle are decoupled and the variations in the patterns of axis flanking
morphology and rate of accretion indicate that processes controlling upwelling and melt production vary markedly in time as
well. At this spreading rate and in this area, the accretionary processes are clearly three-dimensional. In addition, the
morphology of a ridge segment is not governed so much by opening rate as by the thermal structure of the mantle which underlies
the segment. 相似文献
116.
Bulk particulate organic carbon in the East China Sea: Tidal influence and bottom transport 总被引:4,自引:0,他引:4
Five oceanographic surveys were carried out in the East China Sea (ECS) and Yellow Sea from 1999 to 2003. In all, seven different sections were surveyed, but one section (the PN section) was observed on every cruise. Two time-series stations were also surveyed, one located at the Changjiang River mouth, the other over the continental shelf in the PN section.We identified biogeochemical characteristics for waters close to the Changjiang Estuary and in the Kuroshio waters (KW), respectively. Resuspension is a strong feature near bottom over the ECS continental shelf, with suspended matter values 13 times higher than that for the surface. A model of particulate organic carbon (POC) dynamics based on a rectangle equation reveals that POC concentration close to the Changjiang Estuary varies with a semidiurnal period of ∼13 h, coinciding with the tidal period. The upper limit for POC residence times in the seasons we covered over the shelf are estimated to be on the order of weeks and generally increase seaward from near the Changjiang Estuary to the KW. Short POC residence times suggest that POC in the ECS is rapidly exported from euphotic waters.A nepheloid layer, observed as elevated suspended matter in near the bottom of the water column, is important in particle transfer over the shelf, especially in winter when the residual current flows mainly eastward. Cross-shelf transport of POC via the nepheloid layer is estimated to be 0.22 × 1012 g yr−1. Comparison with other work indicates that POC transport is ∼2% of the Changjiang POC input. 相似文献
117.
This paper studies the adsorption isotherm curves of four amino acids (glyucine,aspartic acid,glutamic acid and lysine)and the effects of existences of different concentrations of Cu(Ⅱ) on them.Both the adsorption isotherm of the amino acids on the kaolinite and that when the copper ion Cu(Ⅱ) exists belong to the Langmuir type.The slopes of these adsorption isotherm increase with the increasing concentrations of Cu(Ⅱ) added.It can be explained in terms of formation of the type(Ⅰ) ternary surface complexes in these systems.The regular pattern of the effects of copper ion Cu(Ⅱ) on the adsorption isotherm of amino acids on the kaolinite is identical with that of its effects on the exchange and adsorption percentage E(%)-pH on the kaolinite in the same system. 相似文献
118.
A preliminary optical classification of lakes in Estonia and south Finland which can also be used for small bays of the Baltic Sea is elaborated. The classification is based on the optical properties of water (diffuse attenuation coefficient, diffuse reflectance) and parameters that are routinely monitored in water bodies (Secchi depth, concentration of chlorophyll-a, total suspended matter and yellow substance). The data complex used for our classification covers different types of water ecosystems (ranging from oligotrophic to hypertrophic) and the variability of water constituent concentrations in the ice-free period in Estonia and south Finland. Using cluster analysis, we found 5 optical classes of waters: clear (C), moderate (M), turbid (T), very turbid (V) and brown (B). There is satisfactory correspondence between class of water, shape of diffuse attenuation coefficient and diffuse reflectance spectra and trophic state of the lakes. 相似文献
119.
离子色谱分析在黄土和粉尘研究中的应用 总被引:1,自引:0,他引:1
黄土中存在着大量的碱金属及碱土金属,以往的测试方法多为原子吸收和ICP—MS,离子色谱法在测试黄土样品的碱金属和碱土金属元素含量中应用不多。将黄土地质标准样品进行消解后用离子色谱进行测试,测试效果良好,重复测试的相对标准偏差小于5%,与推荐值的相对误差小于5%,准确度和精密度符舍相关的质量控制要求。本实验方法测试的离子含量都在仪器响应呈线性的最佳测试范围之内,标准曲线经回归后相关系数均达到0.9999。黄土样品的分析结果与粉尘气溶胶样品的离子分析结果对比表明,此方法对于探讨粉尘起源以及沙尘暴天气的研究具有重要意义。 相似文献
120.
大亚湾微表层和次表层海水营养盐的研究 总被引:11,自引:0,他引:11
根据1998年秋季(10、11月)、1999年春、秋季(4、5、10月)5个航次对大亚湾海区微、次表层的调查结果,分析了微表层海水对氮、磷、硅营养盐的富集概况,讨论了营养盐与环境因子的关系。结果表明:大亚湾海区微表层海水对氮、磷、硅营养盐均有富集作用,因海况及季节不同,富集因数(EF)与其他海区的有所差别;无论夏季或秋季,大亚湾海区微表层海水中无机氮都以NH4-N为主要存在形态;其余水层则以NO3-N为主要存在形态。结果还表明,微表层、次表层海水中NH4-N与BOD5、COD测值都呈高度显著正相关,与PO4-P和SiO3-Si含量均无相关,说明大亚湾海区水中含氮有机物较含磷有机物丰富。 相似文献