A comparative study on the illite crystallinity and the clay mineral reflectance spectral index for subdividing the very low-grade metamorphic belt along the Lizhou-Hekou geological section in the Youjiang sedimentary basin, Guangxi, China

To examine the application potential of hyperspectral remote sensing techniques in classifying very low-grade metamorphic belts, the composition of clay minerals and the cyrstallinity of illite from mudstones were measured using XRD and VIS-SWIR (400-2500 nm) reflectance spectroscopy. Based on the illite cyrstallinity, Kubler Index (KI), the Early Triassic LuoLou Group and the Middle Triassic lower Baifeng Formation were classified as the lower Epizone with KI△2θ° ranging from 0.22 to 0.25, the upper Baifeng Formation as upper anchizone with KI△2θ°ranging from 0.26 to 0.33, and the Hekou Formation as lower anchizone with KI△2θ° ranging from 0.38 to 0.40. According to a KI△2θ° value of 0.43, it is possible that there may exist a local diagenetic zone in the upper strata. The illite cyrstallinity Kubler index and the metamorphic grade increase from the bottom to the top of the stratigraphic sequence. The metamorphic grade boundaries nearly match the stratigraphic boundaries, indicating a burial metamorphism nature for the stratigraphic sequence. From the bottom to the top of the sequence, the spectral absorption band center of clay minerals from fresh rocks is around 2200 nm. The absorption band centers change towards shorter wavelengths: the Luolou Group being at 2220 nm, the Baifeng Formation at 2217-2213 nm, the lower member of the Hekou Formation at 2214-2206 nm, and the upper member of the Hekou Formation at 2205-2197 nm. The spectral absorption band center of illite shows the same change pattern. These results indicate that very low-grade metamorphic belts can be subdivided using spectral indices of clay minerals, which are measured by using field portable spectroradiometers. However, it may not work well with satellite and airborne sensors.     

淮南深地重力观测的环境噪声评估与慢地震探测潜力

深地实验室的低噪声特性为高精度连续重力观测提供了理想的外部条件.为了揭示深地观测环境对重力观测精度的提升效果,本研究利用CG-5型和CG-6型各两台重力仪,在淮南煤矿的地下和地表同时开展重力观测.为减小仪器性能差异对结果的影响,先在淮北重力站进行同址观测.研究结果表明,相比于地表观测,地下观测可以减少1/3至1/2的线性漂移和1/3左右的非线性漂移,提取的潮汐因子精度也更高.地下非线性漂移的功率谱密度比地表低,二者差异在半日波频段最大可达15 dB.相比于地表和山洞,深地观测在次地震频段有明显的低噪声优势.地震位错理论计算结果表明,冲绳海沟7级左右的地震可在淮南深地试验场产生大约0.003 μGal的重力变化,超过0.001 μGal的超导重力静态观测精度.因此有望利用淮南深地实验室,在次地震频段的低噪声优势环境下开展超导连续重力观测,捕捉冲绳海沟可能存在的7级以上慢地震事件.

     

乳砷铅铜石的发现与研究

乳砷铅铜石发现于1984年,在广西德保和平桂等矿区的硫化物型矿床的氧化带铁帽中.对该矿物的物理、化学和X射线粉晶分析、红外光谱分析以及差热分析等方面进行了测试研究,其结果与国外已知数据基本一致.矿物呈淡黄绿或深绿色,细粒状或葡萄状,硬度H=4,比重D=5.35,透明,二轴晶负光性,2V大,Ng=1.9817,Nm=1.9703,NP=1.9584.化学成分为PbO 35.19,CuO 30.64,As_2O_5 30.09,FeO 0.28,ZnO 0.05,H_2O 4.10(%).相应的化学分子式为Cu_(2.96)Pb_(1.21)(AsO_4)_(2.01)(OH)_(2.31)·0.59H_2O.X射线粉晶数据与JCPDS26～1410卡基本一政,衍射强线为3.14(10),3.24(8),2.92(8),2.55(8),2.74(7),2.49(7),2.27(7),4.51(6),4.94(5),2.66(4),1.902(4),1.817(4).计算的晶胞参数为a=10.236(?).b=5.904(?),C=14.213(?),β=106.39°,z=4,单斜晶系;空间群为A2/a.红外吸收光谱波数为3440、1640、870、820、775、465和1100、590、557(cm~(-1));差热分析吸收峰为580、773、812、889、898(℃).     

Thermal history of the Hodgkinson Province and Laura Basin,Queensland: Multiple cooling episodes identified from apatite fission track analysis and vitrinite reflectance data

Apatite fission track analysis and vitrinite reflectance data from outcrop and well samples in the Hodgkinson Province and Laura Basin reveal regional Cretaceous cooling. Apatite fission track analysis appears to define two discrete cooling episodes, in the mid‐Cretaceous (110–100 Ma) and Late Cretaceous (80–70 Ma), although in most samples data allow only definition of a single episode. Rocks now at outcrop cooled from Cretaceous palaeotemperatures generally between 50 and 130°C in the south of the region, and from >100°C in the north. Some samples from the Hodgkinson Province also show evidence for an Early Jurassic cooling episode, characterised by maximum palaeotemperatures varying from at least 95°C (from apatite fission track analysis) to ～200–220°C (from vitrinite reflectance), with cooling beginning at around 200 Ma. Apatite fission track analysis data do not reveal the earlier event in the Laura Basin, but on the basis of vitrinite reflectance data from Permian? units this event is also inferred to have affected the pre‐Jurassic basin units in this region. The regional extent of the Cretaceous cooling episode in the Hodgkinson Province suggests that the elevated palaeotemperatures in this region were most likely due to greater depth of burial, with subsequent cooling due to kilometre‐scale denudation. For a palaeogeothermal gradient of 30°C/km and a palaeosurface temperature of 25°C the total degree of Cretaceous cooling experienced by the samples corresponds to removal of between ～0.8 and >3.0 km of Triassic and younger section removed by denudation, beginning some time between ca 110 and 80 Ma. Higher palaeogradients would require correspondingly lower amounts of removed section. The geology of the Laura Basin suggests that an explanation of the observed Cretaceous palaeotemperatures in this region in terms of deeper burial may be untenable. Heating due to hot fluid flow may be a more realistic mechanism for producing the observed Cretaceous palaeothermal effects in the Laura Basin.     

生物成因与无机成因文石的FTIR光谱区别

对16种贝壳交叉页片层中生物成因文石的FT IR谱进行测量,并与无机成因文石进行对比和统计分析后,首次发现生物成因与无机成因文石的FT IR光谱有明显可区分的特征,生物成因文石2ν带(面外弯曲振动)频率平均值为863.4 cm-1,而无机成因文石该带的平均值为855.5 cm-1,两者频率位移达7.9 cm-1。因此文石的2ν带可作为指纹带鉴别生物和无机成因文石。     

杭州湾HJ CCD影像悬浮泥沙遥感定量反演

利用环境小卫星CCD（HJCCD）影像对杭州湾悬浮泥沙浓度（SSC）进行了反演研究。通过对杭州湾水体遥感反射率（Rrs）与SSC进行相关性分析发现,在690nm和830nm左右出现显著的反射峰,分别位于HJCCD影像的第3和第4波段范围内;大于700nm波长处的Rrs与SSC相关性较好。基于实测Rrs和SSC之间的相关关系,利用第4和第3波段比值作为遥感因子建立SSC反演模型,模型决定系数达到0.90。借鉴近红外-短波红外（NIR-SWIR）结合的大气校正方法反演出的准同步MODIS气溶胶数据,实现了HJCCD影像的大气校正,第3、第4波段的大气校正结果相对误差分别为5.54%和6.97%。结果显示,HJCCD影像反演的SSC相对误差为7.12%;杭州湾悬浮泥沙浓度要显著高于长江口,且内部差异明显。研究表明,通过适当的大气校正方法和反演算法,HJCCD影像可用于杭州湾悬浮泥沙浓度的估计。     

REMOTE SENSING OF THE SEASONAL VARIATION IN COLUMN ABUNDANCE OF ATMOSPHERIC CH4*

Infrared solar spectra on clear days were measured automatically by an infrared solar spectrometer(ISS) with 0.4 cm^-1 resolution developed by us.A line-by line(LBL) computation method was used to calculate theoretical atmospheric absorption.In the wavelength range of 3.410-3.438 μm.the absorption is mainly due to atmospheric methane and water vapor.Columnatmospheric methane was retrieved from the recorded infrared solar spectra.The seasonal variation of column atmospheric methane in Hefei has been obtained from the measuremental data of nearly 18 months since the April of 1997.and found that it is similar to that of background data.The instruments.principles of measurement and some of results were introduced,and the results are also discussed briefly in the paper.     

利用高光谱对生物变量进行估计

该文分析了非光合背景物质—土壤光谱信号的特点 ,认为利用对光谱信号进行一阶导数的运算就能对混合光谱中的土壤光谱信号进行压缩 ,由此而得到的生物指数如LAI、SApar等的估计值更能客观地反映实际 ,这对于利用成象光谱进行环境应用有很大的实用价值。     

大型沉水植物狐尾藻不同盖度的光谱特征

地物特征与其光谱特征的关系是解译遥感影像的关键。本研究利用ASD便携式地物光谱仪对上海崇明国际湿地公园人工湖中的沉水植物狐尾藻的反射光谱进行了初步研究。结果表明,随狐尾藻盖度的增加,其光谱反射率、一阶和二阶导数红边斜率的峰值也相应增加,不同盖度狐尾藻的光谱反射率的差异主要表现在500—650nm和700—900nm波段范围。分别对狐尾藻盖度与这些波段的光谱反射率及根据一阶和二阶导数获得的光谱指数进行回归分析,得到了较好的线性关系。应用回归分析得到的线性方程,可以根据测定的光谱反射率定量反演水体中的狐尾藻盖度。研究结果可为监测大型沉水植物的高光谱遥感影像解译和分类提供技术支撑,为大尺度遥感监测沉水植物的分布和动态变化提供科学依据。     

PARASOL/POLDER3卫星数据的海洋上空云检测

在卫星海洋遥感中,云作为海气耦合系统最重要的调节器之一,其检测结果对海洋上空云微物理特性的反演精度有较大影响。因此,快速而准确识别海洋上空的云像元是卫星遥感数据处理过程中首要解决的关键问题。以PARASOL (Polarization and Anisotropy of Reflectances for Atmospheric Sciences coupled with Observations from a Lidar)卫星搭载的POLDER3载荷遥感数据为研究对象,提出一种改进的海洋上空云检测方法。首先剔除海洋耀光;接着利用有云与晴空区近红外反射率差异检验识别有云像元,并利用偏振反射率检验进一步识别低反射率的云像元;然后利用近红外与可见光反射率比值检验识别晴空像元;最后建立多角度云检测结果空间融合规则,重新标记有云、晴空和未定像元。以印度洋海区为例进行实验分析,将云检测结果与Buriez方法进行对比,发现检测精度基本相当,而有云像元的识别速度却平均提高约3倍。结果表明:该方法能有效的检测出海洋上空的云像元,满足业务化数据处理的高精度及时效性要求,为后续云微物理特性反演提供可靠的数据源。