通过类比法确定磷矿选矿指标可行性之探讨——以江苏陶湾磷矿为例

陶湾磷矿是近年来在锦屏、新浦磷矿附近新发现并勘探的中型矿床,其可选性指标通过与相邻老矿山类比确定。近期浅部坑采试选表明,勘探期间所定陶湾磷矿选矿指标是合理、可行的。     

Determination of the Platinum-Group Elements and Gold in Twenty Rock Reference Materials by Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) after Pre-Concentration by Nickel Sulfide Fire Assay

The platinum-group elements (PGE) and gold have been determined in twenty international rock reference materials by inductively coupled plasma-mass spectrometry (ICP-MS) after pre-concentration by a nickel sulfide fire assay. It was possible to achieve determination limits for a 50 g sample that ranged from 1 pg g^-1 (Rh) to 23 pg g^-1 (Au). Compared to published certified and recommended values for rock reference materials, the trueness of the method was found to be good. However, in some cases we observed large deviations for all elements in the sub 10 ng g^-1 range within individual reference sample splits. Our results show that the PGE and Au are inhomogeneously distributed in the reference materials analysed here, where they are present in low concentrations, using 50 g test portions.     

Platinum-Group Element Geochemical Certified Reference Materials (GPt1-7)

Unlike the situation for other elements, few reference materials certified for the platinum-group elements are currently available. Therefore, the GPt1-7 series of PGE geochemical CRMs, prepared by the IGGE, represent an important addition and comprise a range of matrix types, including a soil, stream sediment, Mg-rich ultramafic rock, Fe-rich ultramafic rock, platinoid ore depleted in Cu, Ni and Fe, and a chromitite. The concentration of PGE in these samples ranges over 4-5 orders of magnitude and the samples were shown to have good homogeneity as assessed by a variance test. Analytical methods based on different principles were used in sample certification, including several fire assay and wet chemical procedures used for decomposition and preconcentration. Certified values for the elements Pt, Pd, Os, Ru, Ir, Rh and Au were determined by AAS, catalytic colourimetry (COL), catalytic polarography (POL), atomic emission spectrometry (AES), ICP-MS and NAA. Recently, the GPt1-7 samples were approved as national primary CRMs by the State Bureau of Technical Supervision of China.     

The importance of energetic particle precipitation on the chemical composition of the middle atmosphere

An assessment is made of the relative contribution of certain classes of energetic particle precipitation to the chemical composition of the middle atmosphere with emphasis placed on the production of odd nitrogen and odd hydrogen species and their subsequent role in the catalytic removal of ozone. Galactic cosmic radiation is an important source of odd nitrogen in the lower stratosphere but since the peak energy deposition occurs below the region where catalytic removal of O₃ is most effective, it is questionable whether this mechanism is important in the overall terrestrial ozone budget. The precipitation of energetic solar protons can periodically produce dramatic enhancement in upper stratospheric NO. The long residence time of NO in this region of the atmosphere, where catalytic interaction with O₃ is also most effective, mandates that this mechanism be included in future modelling of the global distribution of O₃. Throughout the mesosphere the precipitation of energetic electrons from the outer radiation belt (60°70°) can sporadically act as a major local source of odd hydrogen and odd nitrogen leading to observable O₃ depletion. Future satellite studies should be directed at simultaneously measuring the precipitation flux and the concomitant atmosphere modification, and these results should be employed to develop more sophisticated models of this important coupling.     

Combined use of spot samples and continuous integrated sampling in a study of storm runoff from a lowland catchment in the south of England

We have used two different sampling techniques to study the geochemical response of a small lowland rural catchment to episodic storm runoff. The first method involves traditional daily spot sampling and has been used to develop a standard end‐member mixing analysis (EMMA) of the relative contributions of ground water flow and surface runoff to the total stream flow. The second method utilizes a continuous sampling device, powered by an osmotic pump, to produce an integrated 24‐h sample of the stream flow. When combined with the EMMA results from the spot samples, analyses of the integrated samples reveal the presence of a third component that makes a significant contribution to the dissolved NO₃, Ca and K export from the catchment during the rising limb of the hydrographic profile of a storm event following a prolonged dry period. The storm occurred in the middle of the night, so that the response of the stream chemistry was not captured by the daily samples. We hypothesize that this third component is derived from the flushing of stored soil water that contains the geochemical signature of decaying vegetation. Copyright © 2011 John Wiley & Sons, Ltd.     

Formal subdivision of the Holocene Series/Epoch: a Discussion Paper by a Working Group of INTIMATE (Integration of ice‐core,marine and terrestrial records) and the Subcommission on Quaternary Stratigraphy (International Commission on Stratigraphy)

This discussion paper, by a Working Group of INTIMATE (Integration of ice‐core, marine and terrestrial records) and the Subcommision on Quaternary Stratigraphy (SQS) of the International Commission on Stratigraphy (ICS), considers the prospects for a formal subdivision of the Holocene Series/Epoch. Although previous attempts to subdivide the Holocene have proved inconclusive, recent developments in Quaternary stratigraphy, notably the definition of the Pleistocene–Holocene boundary and the emergence of formal subdivisions of the Pleistocene Series/Epoch, mean that it may be timely to revisit this matter. The Quaternary literature reveals a widespread but variable informal usage of a tripartite division of the Holocene (‘early’, ‘middle’ or ‘mid’, and ‘late’), and we argue that this de facto subdivision should now be formalized to ensure consistency in stratigraphic terminology. We propose an Early–Middle Holocene Boundary at 8200 a BP and a Middle–Late Holocene Boundary at 4200 a BP, each of which is linked to a Global Stratotype Section and Point (GSSP). Should the proposal find a broad measure of support from the Quaternary community, a submission will be made to the International Union of Geological Sciences (IUGS), via the SQS and the ICS, for formal ratification of this subdivision of the Holocene Series/Epoch. Copyright © 2012 John Wiley & Sons, Ltd.     

Estimation of potential evapotranspiration over the Yellow River basin: reference crop evaporation or Shuttleworth–Wallace?

Potential evapotranspiration (PET) is a key input to hydrological models. Its estimation has often been via the Penman–Monteith (P–M) equation, most recently in the form of an estimate of reference evapotranspiration (RET) as recommended by FAO‐56. In this paper the Shuttleworth–Wallace (S–W) model is implemented to estimate PET directly in a form that recognizes vegetation diversity and temporal change without reference to experimental measurements and without calibration. The threshold values of vegetation parameters are drawn from the literature based on the International Geosphere–Biosphere Programme land cover classification. The spatial and temporal variation of the LAI of vegetation is derived from the composite NOAA‐AVHRR normalized difference vegetation index (NDVI) using a method based on the SiB2 model, and the Climate Research Unit database is used to provide the required meteorological data. All these data inputs are publicly and globally available. Consequently, the implementation of the S–W model developed in this study is applicable at the global scale, an essential requirement if it is to be applied in data‐poor or ungauged large basins. A comparison is made between the FAO‐56 method and the S–W model when applied to the Yellow River basin for the whole of the last century. The resulting estimates of RET and PET and their association with vegetation types and leaf area index (LAI) are examined over the whole basin both annual and monthly and at six specific points. The effect of NDVI on the PET estimate is further evaluated by replacing the monthly NDVI product with the 10‐day product. Multiple regression relationships between monthly PET, RET, LAI, and climatic variables are explored for categories of vegetation types. The estimated RET is a good climatic index that adequately reflects the temporal change and spatial distribution of climate over the basin, but the PET estimated using the S–W model not only reflects the changes in climate, but also the vegetation distribution and the development of vegetation in response to climate. Although good statistical relationships can be established between PET, RET and/or climatic variables, applying these relationships likely will result in large errors because of the strong non‐linearity and scatter between the PET and the LAI of vegetation. It is concluded that use of the implementation of the S–W model described in this study results in a physically sound estimate of PET that accounts for changing land surface conditions. Copyright © 2006 John Wiley & Sons, Ltd.     

Study of temperature and precipitation variations in Italy based on surface instrumental observations

In this paper we present a study concerning the climatic behaviour of two principal observables, temperature and precipitation as obtained from the measurements carried out at 50 Italian meteorological stations, since 1961. Analyses of WMO Climate Normals (CliNo) from 1961 to 1990 have been performed dividing the 50 Italian stations in three different classes: mountain (11 stations), continental (17) and coastal areas (21).The comparison of the CliNo 1961–1990 with the trend of temperature and precipitation for the period 1991–2000 showed a sharp significant increase of summer temperatures over Italy starting from 1980. This phenomenon was particularly evident for mountain stations, where a significant temperature increase has been recorded also during the autumn. Moreover, the analysis of precipitation data permitted to point out that, starting from 1980, mountain stations have been affected by a significant increase of precipitation events during autumn and winter, while for the rest of the Italian territory a reduction of precipitations has been recorded during early spring.     

Influence of Land Use/Cover Change on Storm Runoff— A Case Study of Xitiaoxi River Basin in Upstream of Taihu Lake Watershed

Land use/cover change (LUCC) is one of the main boundary conditions which influence many hydrologic processes. In view of the importance of Taihu Lake Watershed in China and the urgency of discovering the impacts of LUCC on storm runoff, two flood events under five land cover scenarios in the Xitiaoxi River Basin of the upstream of Taihu Lake watershed were simulated by distributed hydrologic modeling system HEC-HMS. The influences of each land cover on storm runoff were discussed. It was concluded that under the same rainstorm the ascending order of runoff coefficient and peak flow produced by the 5 different land covers were woodland, shrub, grassland, arable land, and built-up land; the descending order of swelling time were woodland, shrub, grassland, arable land, and built-up land. Scenario of built-up land was the first to reach peak flow, then arable land, grassland, shrub, and woodland. There were close relationships between the runoff coefficients produced by the 5 different land covers. The degrees of impacts on runoff coefficient of land cover change modes were sorted by descending: woodland to built-up land, shrub to built-up land, grassland to built-up land, arable land to built-up land, woodland to arable land, shrub to arable land, arable land to grassland, shrub to grassland, grassland to arable land, and woodland to shrub. Urbanization will contribute to flood disaster, while forestation will mitigate flood disaster.