A Compilation of Silicon,Rare Earth Element and Twenty‐One other Trace Element Concentrations in the Natural River Water Reference Material SLRS‐5 (NRC‐CNRC)

The natural river water certified reference material SLRS‐5 (NRC‐CNRC) was routinely analysed in this study for major and trace elements by ten French laboratories. Most of the measurements were made using ICP‐MS. Because no certified values are assigned by NRC‐CNRC for silicon and 35 trace element concentrations (rare earth elements, Ag, B, Bi, Cs, Ga, Ge, Li, Nb, P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl, W, Y and Zr), or for isotopic ratios, we provide a compilation of the concentrations and related uncertainties obtained by the participating laboratories. Strontium isotopic ratios are also given.     

An Optimised 1,10‐Phenanthroline Method for the Determination of Ferrous and Ferric Oxides in Silicate Rocks,Soils and Minerals

A precise, accurate and rapid method for the sequential determination of FeO and Fe₂O₃ in rocks, soils and some non‐refractory minerals by 1,10‐phenanthroline spectrophotometry is described. Fe(II) and Fe(III) were leached from the sample (?200 mesh) using a mixture of NH₄HF₂ and H₂SO₄ at 40–80 °C for 10 min on a hot plate. Both Fe(II) and Fe(III) could be conveniently estimated sequentially from the same reaction mixture at the μg g^?1 to percentage level. The method is better than the existing wet chemical methods, including the commonly used Pratt's titrimetric redox method, for Fe(II) and Fe(III) determinations in rock and soil samples in terms of precision, accuracy and rapidity. The throughput of the method was very high; at least forty to fifty samples could be estimated easily in a day. The results obtained compare favourably with those obtained by Pratt's method, as well as for certified/recommended values of a set of eleven certified reference materials having FeO and Fe₂O₃ contents in the range 0.21–14.63% and 0.58–8.48%, respectively. The optimised 1,10 phenanthroline method was found to be accurate to within 0.21% m/m FeO and 0.30% m/m Fe₂O₃ compared with the literature values of the certified reference materials studied.     

Les orthomicaschistes,produits de la déformation cisaillante ductile synmétamorphe de granites avec transfert de matière : principaux caractères et exemples dans la chaîne varisque du Sud de la France

Résumé

Dans le segment varisque français, les associations d’orthogneiss et de micaschistes sont généralement interprétées comme correspondant originellement soit à des couples socle granitique -couverture pélitique, soit à des granités intrusifs dans un encaissant pélitique, soit encore à des séries détritiques ou volcano-détritiques. Certaines d’entre elles résultent en fait de la déformation cisaillante ductile hétérogène synmétamorphe d’anciens granités, associée à d’importants transferts de matière.

Cette interprétation se fonde essentiellement sur la reconnaissance dans des zones de cisaillement ductile de passages progressifs entre orthogneiss et micaschistes. Cette évolution, qui correspond à une séquence blastomylonitique ou sub-blastomylonitique, est caractérisée par une recristallisation complète, ou quasi-complète, dès le stade orthogneiss, accompagnée par une modification chimique marquée par une perte en Si, Ca et Na et une concentration corrélative en Al, Fe, Mg et Ti. Une telle évolution aboutit à des orthomicaschistes, roches entièrement recristallisées et à foliation bien définie, distincts des phyllonites et analogues aux « micaschistes rétrogrades ». Les associations métagranites - orthogneiss - orthomicaschistes reconnues occupent des surfaces allant de 50 à 500 km2 et l’épaisseur des nombreux niveaux d’orthomicaschistes va de quelques centimètres a plusieurs hectomètres.

En conséquence, dans les régions affectées par une intense déformation cisaillante ductile synmétamorphe, les transformations de granités peuvent être plus variées, plus importantes et plus généralisées qu’on ne l’admettait jusqu’ici.     

Migrations de charnières et vecteurs de déplacements sur des modèles analogiques de plis superposés

Résumé

La modélisation analogique d’une superposition de plissements dans une série sédimentaire stratifiée, représentée ici par un multicouche de paraffine et graisse, fait apparaître le rôle déterminant de la géométrie des plis initiaux. Les plis ouverts peuvent évoluer sous l’effet de la seconde compression :

- Si les directions des axes de ces plis sont parallèles à la seconde compression, on verra apparaître des plis superposés.

- Si les directions des axes sont obliques à celle-ci, on observera la réutilisation des plis qui seront alors réorientés grâce à la migration de leur charnière. En fin de déformation la ou les familles de plis présentes dans le modèle ne sont perpendiculaires ni à la première ni à la seconde direction de compression.     

Annual dissolved fluxes from Central Nepal rivers: budget of chemical erosion in the Himalayas

Annual dissolved element fluxes of Himalayan rivers from Central Nepal are calculated using published river discharge and a new set chemical data of rivers, including monsoon sampling. These are used to study the control on chemical erosion of carbonate and silicate over the whole basin. Chemical erosion of carbonate is mainly controlled by the river runoff but it can be limited by the availability of carbonate in limestone-free basin. Chemical erosion of silicate is well correlated to the runoff. However differences between High Himalayan and Lesser Himalayan basins suggest that physical erosion may also play an important control on silicate weathering. To cite this article: C. France-Lanord et al., C. R. Geoscience 335 (2003).     

Restoring capability of bilinear hysteretic seismic isolation systems

The restoring capability (or re‐centering capability) is identified by the current design codes as a fundamental feature of seismic isolation systems. In this paper, the restoring capability of bilinear hysteretic or frictional seismic isolation systems is investigated in some detail. Certain energy considerations are examined first in order to provide insight into and reveal governing parameters on individual aspects of the problem. The restoring capability is then investigated through an extensive parametric study of smooth bilinear single‐degree‐of‐freedom hysteretic systems, with parameters covering a range of typical seismic isolation systems, subjected to a large group of recorded earthquakes. The results of the parametric analyses are processed statistically and regression analysis relations are derived that show the dependence of the residual displacement after the earthquake and the cumulative build up of displacements after a series of successive earthquakes on the governing parameters. Based on the analysis results, the features of the bilinear system that ensure sufficient restoring capability are identified. Copyright © 2007 John Wiley & Sons, Ltd.     

A new scenario for the last magmatic eruption of La Soufrière of Guadeloupe (Lesser Antilles) in 1530 A.D. Evidence from stratigraphy radiocarbon dating and magmatic evolution of erupted products

La Soufrière of Guadeloupe is a dangerous volcano characterized over the last decade by moderate seismic and fumarolic unrest. In the last 15,000 years it has experienced phreatic and magmatic eruptions and unusually numerous flank collapse events sometimes associated with a magmatic eruption. We propose a new age of 1530 A.D. and a new eruptive scenario for the last magmatic eruption on the basis of a novel statistical analysis of radiocarbon age dates, and new field and geochemical data. This eruption is the only magmatic eruption likely to have occurred in Guadeloupe during the last 1400 years. The eruption mainly involved an andesitic magma which, in the first phase of the eruption, partially mixed with a slightly more differentiated magma stored in a small and shallow magma chamber. Ascent of magma to the surface generated a partial collapse of the hydrothermally altered edifice that increased the magma discharge and led to a sub-plinian phase with scoria fallout and column-collapse pyroclastic flows followed by near-vent pyroclastic scoria fountains. The eruption ended with growth of a lava dome. Our revised interpretation of the last magmatic eruption of La Soufrière constitutes the most likely key to a future magmatic eruption scenario for this volcano which displays strong evidence of unrest since 1992.     

Reconstruction and analysis of sub-plinian tephra dispersal during the 1530 A.D. Soufrière (Guadeloupe) eruption: Implications for scenario definition and hazards assessment

The last magmatic eruption of Soufrière of Guadeloupe dated at 1530 A.D. (Soufrière eruption) is characterized by an onset with a partial flank-collapse and emplacement of a debris-avalanche that was followed by a sub-plinian VEI 2–3 explosive short-lived eruption (Phase-1) with a column that reached a height between 9 and 12 km producing about 3.9 × 10⁶ m³ DRE (16.3 × 10⁶ m³ bulk) of juvenile products. The column recurrently collapsed generating scoriaceous pyroclastic flows in radiating valleys up to a distance of 5–6 km with a maximum interpolated bulk deposit volume of 11.7 × 10⁶ m³ (5 × 10⁶ m³ DRE). We have used HAZMAP, a numerical simple first-order model of tephra dispersal [Macedonio, G., Costa, A., Longo, A., 2005. A computer model for volcanic ash fallout and assessment of subsequent hazard. Comput. Geosci. 31, 837–845] to reconstruct to a first approximation the potential dispersal of tephra and associated tephra mass loadings generated by the sub-plinian Phase 1 of the 1530 A.D. eruption. We have tested our model on a deterministic average dry season wind profile that best-fits the available data as well as on a set of randomly selected wind profiles over a 5 year interval that allows the elaboration of probabilistic maps for the exceedance of specific tephra mass load thresholds. Results show that in the hypothesis of a future 1530 A.D. scenario, populated areas to a distance of 3–4 km west–southwest of the vent could be subjected to a static load pressure between 2 and 10 kPa in case of wet tephra, susceptible to cause variable degrees of roof damage. Our results provide volcanological input parameters for scenario and event-tree definition, for assessing volcanic risks and evaluating their impact in case of a future sub-plinian eruption which could affect up to 70 000 people in southern Basse-Terre island and the region. They also provide a framework to aid decision-making concerning land management and development. A sub-plinian eruption is the most likely magmatic scenario in case of a future eruption of this volcano which has shown, since 1992, increasing signs of low-energy seismic, thermal, and acid degassing unrest without significant deformation.     

BOOK REVIEWS

Book Reviewed in this article: Unfairly Structured Cities . Blair Badcock Religion and Rural Revolt . Janos M. Bak and Gerhard Benecke The Industrial Geography of Canada . Anthony Blackbourn and Robert G. Putnam The Cuban-American Experience, Culture, Images, and Perspectives. Thomas D. Boswell and James R. Curtis Quaternary Paleoclimatology . R. S. Bradley Development and Crisis in Brazil, 1930–1983 . Luiz Bresser Pereiras Centres of Origin in Biogeography . John C. Briggs Analytical Urban Geography . Martin Cadwallader Geomorphology . Richard J. Chorley , Stanley A. Schumm, and David E. Sugden South Africa: The Impact of Past Geographies . A. J. Christopher The Geography of Underdevelopment. A Critical Survey . D. K. Forbes Health Care in Developing Countries . Wilbert M. Gesler Place to Grow Old: The Meaning of Environment in Old Age . Stephen M. Golant The Emerging Marine Economy of the Pacific . Chennat Gopalakrishnan An Introduction to Agricultural Geography . David B. Grigg The Soviet Union: A Geographical Study . G. Melvyn Howe Geographical Aspects of Health: Essays in Honour of Andrew Learmonth . N. D. Mc Glashan and J. R. Blunden Physical Geography: A Landscape Appreciation . Tom L. Mc Knight Mountain Experience. The Psychology and Sociology of Adventure. Richard G. Mitchell Jr . Systematic and Regional Biogeography. Stanley A. Morain The Economic Transformation of American Cities. T. J. Noyelle and T. M. Stanback , Jr . Normal Accidents: Living With High-Risk Technologies. Charles Perrow Vanishing Farmland: A Legal Solution for the States. Sarah E. Redfield Applied Methods of Regional Analysis: The Spatial Dimensions of Development Policy. Dennis A. Rondinelli Urbanization in Romania. A Geography of Social and Economic Change Since Independence. Per Ronnas Statistical Techniques in Geographical Analysis. Gareth Shaw and Dennis Wheeler The Granite Garden: Urban Nature and Human Design. Anne Whiston Spirn Political Geography: Recent Advances and Future Directions. Peter Taylor and John House Geographia y Medio Ambiente. Manuel Valenzuela -Rubío Nãgara and Commandery: Origins of the Southeast Asian Urban Traditions. Paul Wheatley The Common Fisheries Policy of the European Community. Mark Wise Geography and Gender. Women and Geography Study Group of the IBG Technological Hazards. D. J. Zeigler , J. H. Johnson , S. D. Brunn     

Effects of eruption history and cooling rate on lava dome growth

To better understand the factors controlling the shapes of lava domes, laboratory simulations, measurements from active and prehistoric flows and dimensional analysis were used to explore how effusion history and cooling rate affect the final geometry of a dome. Fifty experiments were conducted in which a fixed volume of polyethylene glycol wax was injected into a tank of cold sucrose solution, either as one continuous event or as a series of shorter pulses separated by repose periods. When the wax cooling rates exceeded a critical minimum value, the dome aspect ratios (height/diameter) increased steadily with erupted volume over the course of a single experiment and the rate at which height increased with volume depended linearly on the time-averaged effusion rate. Thus the average effusion rate could be estimated from observations of how the dome shape changed with time. Our experimental results and dimensional analyses were compared with several groups of natural lava flows: the recently emplaced Mount St Helens and Soufrière domes, which had been carefully monitored while active; three sets of prehistoric rhyolite domes that varied in eruptive style and shape; and two sets of Holocene domes with similar shapes, but different compositions. Geometric measurements suggest that dome morphology can be directly correlated with effusion rate for domes of similar composition from the same locality, and that shape alone can be related to a dimensionless number comparing effusion rate and cooling rate. Extrapolation to the venusian pancake domes suggests that they formed from relatively viscous lavas extruded either episodically or at average effusion rates low enough to allow solidified surface crust to exert a dominating influence on the final morphology.