Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.     

Gold Occurrence and Ore Genesis,Yata Micro—Disseminated Gold Deposit,Guizhou,Southwest China

The mode of occurrence of gold in the Yata micro-disseminated gold deposit is ap-proached through chemical phase studies coupled with ore-dressing monitoring and micro-beam analysis.The results showed that gold occurred for the most part as ultra-microscopic particles adsorbed on the surfaces or fracture planes of pyrite and other sulphides.The proportions of gold of different occurrences were estimated solutions containing nanometer-sized gold particles were prepared following the hydrolysis-reduction procedure and the adsorption of nanometer-sized gold on ordinary sulphides and rocks was experimentally determined.It is evident that sulphides are good adsorbents of gold and this is consistent with geological observations.     

软基上高速铁路路桥过渡段的技术措施研究

通过对高速铁路路基与桥梁过渡段动力特性分析，指出结构物沉降差是导致轨面不平顺的主要因素。分析了沉降差产生的原因，提出了软基上路桥过渡段的结构设计方案，并对其施工方法及质量检测标准进行了探索。     

Structure sismique du socle paléozoı̈que du bassin des Doukkala,Môle côtier,Maroc occidental. Indication en faveur de l'existence d'une phase éo-varisqueSeismic structure of the Doukkala basin,Palaeozoic basement,western Morocco: a hint for an Eovariscan fold-and-thrust belt

Seismic profiles and well data from the Doukkala basin unravel the structure of the Palaeozoic basement and suggest that this coastal zone of western Morocco was affected by a compressive phase during the Frasnian. This resulted in the formation of upright, plurikilometric folds associated with reverse faults (North Doukkala), and of asymmetrical folds associated with mostly west verging ramps (South Doukkala). Folding involved all pre-Upper Frasnian formations and caused partial or total hiatus of Upper Frasnian–Strunian strata. This event can be correlated with the orogenic phase reported from more internal domains of the Morocco Hercynian belt, where it is referred to as the ‘Bretonne’ or ‘Eovariscan’ phase. To cite this article: H. Echarfaoui et al., C. R. Geoscience 334 (2002) 13–20     

Simulation of artificial random field considering the temporal-spatial variation

Introduction For the seismic design of special structures such as nuclear power station, marine platform, long-span bridge and dam, generally the time-history response analysis of the structure under seismic excitation is imperative, which was coded in most seismic design codes. The earthquake records suitable for the seismic situation and site condition are necessary to be used as the seismic input in the dynamic analysis of structures. As a result of the limited observational condition of st…     

Screening model for volatile pollutants in dual porosity soils

This paper develops mass fraction models for transport and fate of agricultural pollutants in structured two-region soils. Mass fraction index models, based on a semi-infinite domain solution, are derived that describe leaching at depth, vapor losses through soil surface, absorption, and degradation in the dynamic- and stagnant-water soil regions. The models predict that leaching is the result of the combined effect of the upward vapor-phase transport relative to downward advection, residence time relative to half-life, dispersion, and lateral diffusive mass transfer. Simulations show that leached fraction of volatile compounds does not always decrease monotonically with increased residence time relative to the pollutant half-life, as a result of complex interactions among the different physical and biochemical processes. The results show that leaching, volatilization, and degradation losses can be affected significantly by lateral diffusive mass transfer into immobile-water regions and advection relative to dispersion (i.e. Peclet number) in the mobile-water regions. It is shown that solute diffusion into the immobile phase and subsequent biochemical decay reduces leaching and vapor losses through soil surface. Potential use of the modified leaching index for the screening of selected pesticides is illustrated for different soil textures and infiltration rates. The analysis may be useful to the management of pesticides and the design of landfills.     

Melting of β-quartz up to 2.0 GPa and thermodynamic optimization of the silica liquidus up to 6.0 GPa

Melting relations of β-quartz were experimentally determined at 1.0 GPa (1900±20 °C), 1.5 GPa (2033±20 °C), and 2.0 GPa (2145±20 °C) using a new high-pressure assembly in a piston–cylinder apparatus and substantial differences were found with data previously reported. The new melting data of β-quartz were combined and optimized with all available thermodynamic, volumetric, and phase equilibria data for β-cristobalite, β-quartz and coesite to produce a P–T liquidus diagram for silica valid up to 6.0 GPa. Using the new optimized thermodynamic parameters, the invariant point β-cristobalite+β-quartz+liquid and β-quartz+coesite+liquid were determined to lie at 1687±17 °C and 0.457 GPa, and 2425±25 °C and 5.00 GPa, respectively.     

新疆北部降水的气候分布特片及其对ENSO的响应

分析研究了新疆北部地区近50年（1951-2000年）全年各月降水的气候分布特征和各季降水的年际变化规律，重点揭示了北疆多雨季节（4-7月）及其各月降水量对赤道东太平洋的海温SST和南方涛动指数SOI的显著响应关系，并用前期SST和SOI作为预报因子，建立了北疆地区雨季水量的预报方程。该方程可用于北疆地区雨季降水量的长期预报。     

天山西部中山带积雪变化趋势与气温和降水的关系——以巩乃斯河谷为例

根据位于巩乃斯河谷的天山积雪雪崩研究站近30年来的年最大雪深、月平均气温、月降水量观测记录，用平均差值法、最小二乘法、自回归滑动平均法检验了天山西部中山带积雪、冷季降水、冷季平均气温的变化趋势，结果表明，天山西部中山带积雪呈增加趋势，近30年来年平均增加1.43%，与青藏高原、南极大陆及格陵兰冰盖表面积雪积累增加相一致。天山西部中山带冷季气温和降水的变化趋势也是增加的，其中冷季降水平年平均增加0．12％，而冷季气温升高了0．8℃，积雪与冷季气温之间存在着弱的负相关关系，而与冷季降水呈显著的正相关关系。积雪的增加主要是因为气候变暖引起的冷季降水的增加对积雪增加的贡献大于由于冷季气温升高而造成积雪减少的贡献的结果。