实验研究岩石圈深部流体及相关科学问题

实验研究地球岩石圈深部流体和对地球深部流体的观测发现,水溶液在跨越临界态时有许多特殊性质。使用水热金刚石压钻在200～800MPa,300～700℃条件下,可观测到：NaCl-H2O溶液两相不混溶相区的结构和近临界态现象。测量高温高压下NaCl溶液的电导率,在近临界和跨越临界态时发现最大电导率值。在对大洋中脊热水观测中可发现大多数喷口是在2200m深。喷口正在近临界态条件下喷出含矿流体。这些临界态研究对于重新分析岩石圈的地球物理测量结果和对认识大陆岩石圈内流体性质有很大意义。     

极性分子型电流变液导电机理研究

极性分子型电流变液是一种新型的电流变材料.其介电颗粒上吸附极性分子,极性分子在颗粒间强局域电场作用下发生取向是产生巨电流变效应的关键.通过对Ca—Ti—O(CTO)体系极性分子型电流变液电流密度的测量发现,其导电行为遵从Poole-Frenkel效应的规律,这是极性分子型电流变液的重要特征之一.而500 ℃处理过的CTO粉体不含极性分子,所配制的电流变液无巨电流变效应,其电流密度随外电场强度近似地呈线性关系,显示出传统电流变液特性.     

LMWOA (low molecular weight organic acid) exudation by salt marsh plants: Natural variation and response to Cu contamination

This work aimed to evaluate, in vitro, the capability of roots of two salt marsh plants to release low molecular weight organic acids (LMWOAs) and to ascertain whether Cu contamination would stimulate or not organic acids exudation. The sea rush Juncus maritimus and the sea-club rush Scirpus maritimus, both from the lower Douro river estuary (NW Portugal), were used. Plants were collected seasonally, four times a year in 2004, during low tide. After sampling, plant roots were washed for removal of adherent particles and immersed for 2 h in a solution that matched salinity (3) and pH (7.5) of the pore water from the same location to obtain plant exudates. In one of the seasons, similar experiments were carried out but spiking the solution with different amounts of Cu in order to embrace the range between 0 and 1600 nM. In the final solutions as well as in sediment pore water LMWOAs were determined by high performance liquid chromatography. Plants were able to release, in a short period of time, relatively high amounts of LMWOAs (oxalate, citrate, malate, malonate, and succinate). In the sediment pore water oxalate, succinate and acetate were also detected. Therefore, plant roots probably contributed to the presence of some of these organic compounds in pore water. Exudation differed between the plant species and also showed some seasonally variation, particularly for S. maritimus. The release of oxalate by J. maritimus increased with Cu increase in the media. However, exudation of the other LMWOAs did not seem to be stimulated by Cu contamination in the media. This fact is compatible with the existence of alternative internal mechanisms for Cu detoxification, as denoted by the fact that in media contaminated with Cu both plant species accumulated relatively high amounts (29–83%) of the initially dissolved Cu. This study expands our knowledge on the contribution of globally dominant salt marsh plants to the release of LMWOAs into the environment.     

平湖油气田低渗透储层测井评价研究

平湖油气田P11储层开发是平湖油气田增储提产的重要目标,也是当前平湖油气田开发面临的难题之一。由于埋藏深,储层物性条件差,试油自然产能低下,储层流体性质复杂,气油比低,凝析油含量高,密度大,储层温度高,压力系数高,给测井解释和评价带来很大困难,对开发方案的实施提出了挑战。根据岩心分析资料,从成岩作用、沉积作用等方面对平湖组放鹤亭P11储层低渗原因进行了分析;对P11储层的测井响应特征进行了总结,对P11储层＂四性＂关系、孔隙度结构进行剖析,对储层孔隙度、渗透率、饱和度等参数进行了研究,得到一套适合P11储层测井解释评价的方法,为P11储层的开发提供参数依据和测井解释服务。     

Distribution and sources of organochlorine pesticides in water and sediments from Daliao River estuary of Liaodong Bay,Bohai Sea (China)

The levels of 19 kinds of organochlorine pesticides (OCPs) in the aqueous phase, suspended particulate matter (SPM), pore water and sediments from Daliao River estuary of Liaodong Bay (Bohai Sea) in northeast China were investigated to evaluate their potential pollution risks. The total OCPs concentrations in the aqueous phase, SPM, pore water and sediments were 3.7–30.1 ng l⁻¹, 4.6–52.6 ng l⁻¹, 157–830 ng l⁻¹ and 2.1–21.3 ng g⁻¹ dry weight, respectively. The concentrations of OCPs, in the Daliao River estuary, are in the mid-range, as compared to those reported in other estuaries worldwide. The distribution of HCHs and DDTs were different indicating different contamination sources. Lindane is the main type of HCH and continuing use in northeast China of ‘pure’ HCH (lindane) rather than technical HCH accounts for the source. The ratios of (DDE + DDD)/DDT in the samples indicate no recent inputs of these chemicals to the estuary.     

低渗透储层的微观特征对其宏观性质的影响规律——以榆树林油田扶杨油层为例

利用岩心物性分析、压汞曲线和镜下分析等资料,研究榆树林油田东16区块扶杨油层的宏、微观特征及二者关系.结果表明:研究区扶杨油层岩性为岩屑长石砂岩,普遍具有碎裂特征,主要孔隙成因类型包括微裂缝、粒间孔、粒内孔和晶间孔,微裂缝对孔隙度的贡献不大,但对渗透率的影响不容忽视.孔隙度主要受孔喉发育程度影响,孔喉半径越大,孔隙度越高.渗透率受反映连通程度的特征结构参数影响较大,二者呈正相关关系,且孔隙度越大,特征结构系数对渗透率的影响越大.退汞效率受特征结构参数影响较大,储层为中孔时,退汞效率随特征结构参数的增大而增大;储层为低孔或特低孔时,退汞效率随特征结构参数的增大而减小.该研究结果对改造低渗储层、提高采收率具有指导意义.     

固体地球观向流体地球观的概念更新

长时间内人们把地球看成为一个固体星球,忽视流体在地球动力学中非常重要的作用.在本文中我们将列举一系列的资料来证明它.此流体由H\|A\|C\|O\|N\|S组成.H (氢, 卤素和热), A (碱金属, 例如 Na, K等.), C (碳), O (氧), N (氮), S (硫族).此流体从深部外地核H, H2流向上进入地幔演化为H\|HACONS, 向上到上地幔演化为A\|HACONS, 向上进入地壳后演化为O\|HACONS. 此流体可以使固体地幔,地壳发生弱化,变软,熔融和排气,结果造成地球动力学及大地构造运动和众多自然灾害.     

沟谷型沙漠泥流堆积体起动过程中的孔压变化特性

以黄河上游宁蒙段典型风水复合侵蚀流域为研究区域,重点针对堆积体堵塞沟道极端条件下的沟谷型沙漠泥流,从堆积体起动成灾的环节入手,开展直槽概化模型试验,并采用基于有效应力原理的流固耦合模型,概化模拟上游暴雨洪水入渗条件下堆积体内孔隙水压力变化特性及其起动过程,从微观角度揭示其成灾机理。结果表明：堆积体起动过程中孔隙水压力与时间呈指数为0.5的幂函数关系;流固耦合作用下堆积体内经历了应力场→体积应变→孔隙率→孔隙水压力→渗流场→塑性应变→屈服破坏的复杂非线性变化过程。     

利用SEM照片获取土的孔隙结构参数

以土工实验和计算机图像处理技术为基础, 探讨利用SEM照片获取土的孔隙结构参数的方法, 并以重塑粘性土为例进行实证分析.为获取孔隙结构参数, 首先分3个步骤对土样的SEM照片进行图像处理: 即照片格式转换、颗粒边际线探测和颜色充填; 然后针对黑白二元图像测算孔隙结构参数.从设计制备的重塑粘性土的三轴试验样品中, 选择了12个不同水分状态和密度状态的样品, 经风干和烘干后, 进行SEM测试, 每个样品拍摄了3个尺度的SEM照片, 放大倍数依次为500倍、1000倍、2000倍.之后, 对所获得的SEM照片进行了图像处理分析, 计算了相应的平面孔隙比和平面孔隙率.数据分析表明: SEM照片测算的孔隙参数与通常三相图计算的孔隙参数有关联, 测算数据可以反映土的孔隙结构特征; 样品的不同脱水方式对SEM照片测算的孔隙参数有影响, 与三相图法计算数据相比, 风干土样测算的数据略有偏大, 烘干土样测算的数据偏小; 同一土样不同比例尺的SEM照片测算出的孔隙参数有所不同, 邻近三相图法计算结果上下波动; 利用SEM照片提取土的结构信息是可行的, 对SEM照片进行图像处理分析是获取土的孔隙结构参数的有效办法.