基于水淘选分级的长江口及邻近海域表层沉积物中磷的形态分布和迁移转化

磷是一种重要的生源要素,在河口、边缘海的初级生产中发挥重要作用,了解沉积物中磷的形态分布和迁移转化有助于深入了解该区域生态系统动力学。于2013年3月在长江口及邻近海域采集了表层沉积物样品,利用水淘选方法对沉积物进行了分级,并采用化学连续提取法分析了未分级和分级沉积物样品中的6种磷形态含量:可交换态磷、活性有机磷、铁结合态磷、自生磷灰石磷、碎屑磷和难分解有机磷,讨论了该区域沉积物中磷的形态分布、选择性输运过程和迁移转化。沉积物中总磷含量在14.0~18.4 μmol/g,其中碎屑磷是其主要成分,占54.5%,其次是有机磷和难分解有机磷,分别占到15.1%和13.1%。不同粒级沉积物中磷形态含量不同,可交换态磷、活性有机磷、铁结合态磷、自生磷灰石磷和难分解有机磷随粒级增加含量逐渐降低,而碎屑磷主要集中在粗粒级（大于32 μm）沉积物中。基于各粒级磷形态的质量分布,发现小于32 μm粒级的沉积物中各磷形态含量从长江口向浙闽沿岸逐渐增加,向外海方向逐渐减小,而大于32 μm沉积物的变化趋势与此相反,体现了不同形态磷的选择性输运。随粒径增大,总有机碳对有机磷比值（TOC/Or-P）先降低后升高,在大粒级沉积物中,TOC/Or-P比值较高主要是因为陆源有机碳贡献较高,而在小粒级沉积物中,主要是由于有机磷的迁移和转化更为活跃,体现了细颗粒物中有机磷相对有机碳的优先分解。本研究表明,从分级的角度可以对河口、边缘海的磷循环有一个更全面的认识。     

缢蛏(Sinonovacula constricta)生物扰动对养殖废水处理系统中沉积物磷赋存形态垂直分布的影响

为研究缢蛏(Sinonovacula constricta)生物扰动在养殖废水生态处理系统中对沉积物不同垂直分层的各种磷形态迁移转化的影响,于2016年5—7月在养殖废水处理池的贝藻处理区采集不同缢蛏养殖密度下的实验围隔箱内的底泥,测定不同垂直方向上的磷形态、微生物活性(FDA)以及碱性磷酸酶活性(APA)。结果表明,在底栖动物缢蛏生物扰动作用下,改变了沉积物内部的微环境,促进了微生物的生长,增大了沉积物中总微生物活性以及碱性磷酸酶活性。而沉积物中有机磷(OP)含量显著减少(P0.05);非磷灰石态无机磷(NAIP)、磷灰石态无机磷(AP)和无机磷(IP)含量显著增加(P0.05),这表明在缢蛏的生物扰动下OP可能转变成为AP、NAIP等无机磷成分;总磷含量呈降低趋势。本试验结果表明,缢蛏生物扰动下对于养殖废水生态处理系统沉积物垂直方向上的磷赋存形态具有显著的影响,且高密度组的生物扰动作用对沉积物中磷形态迁移转化的影响强于低密度组。     

南极半岛近岸海域生物化学要素分布特征及影响因素

基于中国第30次南极科学考察在南极半岛(60°~63°S)近岸海域获取的调查资料,分析了该海域生物化学要素中溶解有机碳(DOC)、总氮(TN)和总磷(TP)分布特征并讨论地形和水团对其的影响。结果表明:2014年夏季南极半岛近岸海域水体DOC浓度变化范围为40.5~78.1μmol/L,平均浓度为66.3μmol/L;TN浓度变化范围为4.2~29.5μmol/L,平均浓度为14.9μmol/L;TP浓度变化范围为0.8~2.9μmol/L,平均浓度为2.0μmol/L。表层DOC呈现研究海域西北部D1断面和东南部D5断面浓度较高,中部DOC浓度较低;表层TN与TP浓度高值区出现在研究海域西部D1断面北部以及南部,中部和东部浓度较低;DOC,TN和TP浓度的垂直分布与海底地形和水团交汇密切相关,水团运动受阻于地形致使生物化学要素在垂直方向再分布。DOC,TN和TP空间分布反映了南极半岛近岸海域生物化学要素复杂的流通,将为合理开发和利用南极资源及环境影响评价提供科学依据。     

Petroleum retention in the Mandal Formation,Central Graben,Norway

Upper Jurassic organic matter-rich, marine shales of the Mandal Formation have charged major petroleum accumulations in the North Sea Central Graben including the giant Ekofisk field which straddles the graben axis. Recent exploration of marginal basin positions such as the Mandal High area or the Søgne Basin has been less successful, raising the question as to whether charging is an issue, possibly related to high thermal stability of the source organic matter or delayed expulsion from source to carrier.The Mandal Formation is in part a very prolific source rock containing mainly Type II organic matter with <12 wt.-% TOC and HI < 645 mg HC/g TOC but Type III-influenced organofacies are also present. The formation is therefore to varying degrees heterogeneous. Here we show, using geochemical mass balance modelling, that the petroleum expulsion efficiency of the Mandal Formation is relatively low as compared to the Upper Jurassic Draupne Formation, the major source rock in the Viking Graben system. Using maturity series of different initial source quality from structurally distinct regions and encompassing depositional environments from proximal to distal facies, we have examined the relationship between free hydrocarbon retention and organic matter structure. The aromaticity of the original and matured petroleum precursors in the Mandal source rock plays a major role in its gas retention capacity as cross-linked monoaromatic rings act on the outer surface of kerogen as sorptive sites. However, oil retention is a function of both kerogen and involatile bitumen compositions. Slight variations in total petroleum retention capacities within the same kerogen yields suggest that texture of organic matter (e.g. organic porosity) could play a role as well.     

Diplophos rebainsi Krefft & Parin, 1972, an addition to the mesopelagic fish fauna of New Zealand (note)

Plankton samples taken in the south‐western Pacific Ocean and the Tasman Sea have provided, for the first time in these waters, a series of individuals of the gonostomatid Diplophos rebainsi. Observations are presented on some of the prejuvenile and adult features and on the seasonal distribution of prejuveniles off New Zealand.     

近15 a来三门湾海域氮、磷营养盐分布与富营养化状况的变化分析

以1997年8月中旬和2011年10月中旬对三门湾附近海域开展的海域水质现状调查为依据,分析了近15 a间该海域水体环境氮、磷营养盐的分布现状及变化特征。结果表明:近15 a来,三门湾海域的无机氮和活性磷酸盐含量均成倍增长,水体营养程度由轻度富营养化逐步上升为重度富营养化;从营养结构来看,活性磷酸盐仍为限制性富营养化因子;大量的海水养殖是导致该海域营养盐大幅提高的直接原因。因此,为控制三门湾的富营养化现象进一步加剧,建议适度控制海水养殖规模,调整海水养殖结构,加强对三门湾沿岸排污控制,以获得养殖经济效益和生态环境效益的协调、可持续发展。     

磷锑钼蓝光度法测定红土镍矿中磷量

试样经烘干处理后,利用硫酸和氢氟酸溶矿,硝酸提取,加氨水以氢氧化铁为载体沉淀磷酸盐,分离镍、铬、钴、铜等干扰离子,制备成硝酸溶液。中和后,以钼酸铵—酒石酸锑钾为显色剂,以抗坏血酸为还原剂,显色,在700nm处测量吸光度,利用计算机拟合标准曲线计算磷含量。此方法精密度与加标回收率均能满足质量要求。     

Tracking eutrophication in Taihu Lake using the diatom record: potential and problems

Taihu Lake is the third largest freshwater lake in China and has been experiencing eutrophication problems for several decades. Diatoms in short sediment cores from three bays in northern Taihu Lake were studied in addition to 1-year of seasonal phytoplankton samples in order to evaluate the rate and magnitude of nutrient enrichment. The dominant species found in the phytoplankton samples appeared in high percentages in the surface sediment samples, suggesting that the latter faithfully record the modern diatom flora. The diatom preservation status varied among the three cores, while in all cores the preservation deteriorated with sediment depth. Due to the superior diatom preservation in the core from Mashan Bay, the fossil diatom record of this core and an established diatom total phosphorus (TP) transfer function were used to reconstruct the nutrient history of Taihu Lake. Diatom assemblages changed from Aulacoseira-dominated to other eutrophic planktonic species, such as Stephanodiscus minutulus, Cyclostephanos tholiformis, Cyclotella atomus, C. meneghiniana and S. hantzschii in ca. 1980. Diatom-inferred TP concentrations exhibited little change prior to 1980, with values around 50 μg/l. However, after 1980 TP concentrations increased significantly and remained in excess of 100 μg/l, reflecting eutrophication of Taihu Lake. Comparison with TP measurements in the water column from 1988 to 2004, as well as the analogue analysis among fossil and modern samples, demonstrates that the diatom-TP inference model can reliably hindcast past TP concentrations. Therefore, the baseline TP value of about 50 μg/l, can be used as a restoration target for Taihu Lake. However, due to the complexity of this very large, shallow aquatic ecosystem, caution should be exercised when employing the diatom record to track eutrophication. Further studies on the mechanism of diatom distribution, evolution and preservation are recommended for Taihu Lake.