太湖水体氮、磷浓度演变趋势(1985-2015年)

分析了太湖水体氮、磷浓度1985-2015年的演变趋势.结果表明,近30年来,全太湖水体氮、磷指标总体呈先恶化、后好转的波动变化趋势.总氮（TN）浓度年均值在1.79～3.63 mg/L之间,30年平均值为2.62±0.03 mg/L,总磷（TP）浓度年均值在0.04～0.15 mg/L之间,30年平均值为0.086±0.001 mg/L,1996年全太湖TN （3.84 mg/L）和TP （0.15 mg/L）浓度年均值均达历史峰值.氮、磷逐月浓度变化情况显示,TN浓度呈明显季节性变化规律,最高值集中出现在3、4月,概率分别为67%和33%,最低值则分布在8、9、10、11月,概率分别为18%、41%、29%和12%,而TP浓度则没有明显的季节性变化规律.太湖各湖区水体氮、磷浓度变化空间异质性明显,西部水域和北部水域变化幅度大于东部水域、南部水域和湖心区.太湖水体氮、磷浓度的长期变化趋势显然和流域经济发展及各项环保管理措施的实施密切相关,同时也受到重大水情变化的影响.此外,在相对封闭的局部湖湾水体可以通过水利调度等综合治理措施短时期内改善氮、磷指标,但大太湖水质的改善任重而道远.     

Equilibrium thallium isotope fractionation and its constraint on Earth’s late veneer

Equilibrium isotope fractionation of thallium(Tl) includes the traditional mass-dependent isotope fractionation effect and the nuclear volume effect(NVE). The NVE dominates the overall isotope fractionation, especially at high temperatures. Heavy Tl isotopes tend to be enriched in oxidized Tl^3+-bearing species. Our NVE fractionation results of oxidizing Tl^+ to Tl^3+ can explain the positive enrichments observed in ferromanganese sediments. Experimental results indicate that there could be0.2–0.3 e-unit fractionation between sulfides and silicates at 1650 ℃. It is consistent with our calculation results,which are in the range of 0.17–0.38 e-unit. Importantly,Tl’s concentration in the bulk silicate Earth(BSE) can be used to constrain the amount of materials delivered to Earth during the late veneer accretion stage. Because the Tl concentration in BSE is very low and its Tl isotope composition is similar with that of chondrites, suggesting either no Tl isotope fractionation occurred during numerous evaporation events, or the Tl in current BSE was totally delivered by late veneer. If it is the latter, the Tl-contentbased estimation could challenge the magnitude of late veneer which had been constrained by the amount of highly siderophile elements in BSE. Our results show that the lateaccreted mass is at least five-times larger than the previously suggested magnitude, i.e., 0.5 wt% of current Earth’s mass. The slightly lighter 205 Tl composition of BSE relative to chondrites is probable a sign of occurrence of Tlbearing sulfides, which probably were removed from the mantle in the last accretion stage of the Earth.     

太湖水体的总磷分布及湖流对其影响的数值研究

用数值模拟的方法研究了太湖水体中ＴＰ分布特征及湖流对其影响,推导,建立了包括平流,水平扩散,沉降和底泥释放的浅水湖泊中污染物浓度分布计算的二维迎风有限元数值模式,并在给定若干点源条件下计算各种稳态流场下太湖水体中的ＴＰ分布。     

太湖流域南区湿地磷状况及其滞留能力

选取太湖流域南区29个典型湿地采样点进行土-水磷素状况调查,并采集杭州西湖茅家埠、湖州德清下渚湖、湖州长兴包漾河等泥样进行静态柱和稳流水槽模拟实验,研究区域湿地底泥含TP 0.169-1.200g/kg,Olsen-P 7.08-67.08mg/kg,最大吸附量为269.5-824.5mg/kg,NaOH+EDTA-P占底泥TP的52.O%±11.6%,且伴随其积累会提高Olsen-P含量,相应上覆水含TP 0.036-0.944mg/L,总颗粒态磷占TP含量的70.9%±13.2%,DRP相对较低,静态柱实验中的DRP初始阶段缓慢下降,之后快速下降并维持在稳定水平,稳流水槽实验的DRP动态表现出准U型曲线特征,经验证,底泥的磷素吸附能力在Langmuir吸附实验及室内模拟实验中表现一致.     

滆湖磷迁移过程的研究(一)——磷迁移模型的建立

通过滆湖磷的来源途径(入湖河道、湖区径流、湖面沉降、养殖技饵、底泥释放)和湖体各要素(水体、浮游植物、大型水生植物、鱼类等)中磷迁移过程调查资料的分析,建立了描述磷在上述各要素中迁移过程的数学模型.经实测资料验证,模型的计算值与实测值的平均相对误差在9.9%-18.6%.基本反映了磷的迁移过程及动态变化规律,对该湖磷浓度预测及磷资源合理利用具有重要的意义.     

铜绿微囊藻和蛋白核小球藻对不同形态有机磷的利用及其生长

本研究探索了铜绿微囊藻(Microcystis aeruginosa)和蛋白核小球藻(Chlorella pyrenoidosa)在单藻批式培养条件下对三种不同形态的可溶性有机磷化合物:1-磷酸-葡萄糖,环磷酸腺苷(c-AMP)和三磷酸腺苷(ATP)的利用及其生长.结果表明铜绿微囊藻和蛋白核小球藻能够利用这三种有机磷源进行生长.铜绿微囊藻对三种不同形态有机磷源的利用效率由高到低依次是:1-磷酸-葡萄糖,ATP和c-AMP,尤其是对磷酸单酯类磷源——1-磷酸-葡萄糖有极高的利用效率,在该磷源培养条件下微囊藻最大藻浓度能达到正磷酸盐培养条件下的最大藻浓度.小球藻对1-磷酸-葡萄糖和ATP的利用率略高于c-AMP.总体上铜绿微囊藻对这三种有机磷源的利用能力要高于小球藻.碱性磷酸酶与藻利用有机磷的能力有重要的关系,藻对有机磷的利用能力随着胞内酶活的增加而增强.随着富营养化程度的加剧,水体中可溶性有机磷在总磷中的比例也不断升高,铜绿微囊藻对可溶性有机磷的较强利用能力,可能促使其成为富营养化水体中优势种的原因之一.     

乌江磷浓度与通量变化及来源解析

磷(P)是长江流域备受关注的污染物。乌江是长江八大支流之一,位于三峡水库近库尾江段。武隆断面是乌江入长江控制断面。对1998—2019时期武隆断面径流量、悬浮泥沙浓度(SS)与输沙量、磷浓度与通量(包括总磷(TP)、溶解态磷(DP)和颗粒态磷(PP))年际变化及季节特征进行研究,并基于河流基流分割原理对磷的来源进行了解析。结果表明,(1)1998—2019年,乌江武隆断面径流量在一定幅度内上下波动,而悬浮泥沙浓度和输沙量下降剧烈。(2)22年来,乌江TP和DP浓度与通量总体上呈先升高后下降的趋势,2009—2013年为磷污染峰值期,TP和DP浓度与通量远高于其它时期。(3)2007年是一个重要的时间节点,该节点前,TP的赋存形态以颗粒态为主,颗粒态磷在总磷中的占比均值为65%;该节点后,TP的赋存形态转变为以溶解态为主,颗粒态磷占比均值下降为16%,相应地,溶解态磷占比由35%上升为84%。水沙条件改变是磷形态发生显著变化的主要驱动力,磷污染程度亦是磷形态变化的重要影响因素。(4)磷通量在年内的季节分布发生了显著变化,丰水期磷通量减少,枯水期磷通量增加。(5)1998—2012、2009—2013和2014—2019年3个时期点源负荷占比分别为23.5%、36.8%和62.1%,呈增加趋势。(6)建议制定适宜的总磷控制目标,结合目前所存在的磷污染风险点,进一步强化监管,侧重源头治理。     

华南热带水库丰水期浮游植物群落对氮、磷、铁加富的响应——以广东大沙河水库为例

富营养化是水生态系统主要的环境问题,自然条件下多种营养盐以组合形式进入水体,明确浮游植物群落对多种营养盐加富的响应对富营养化防治有重要意义。本研究以一座华南热带水库(大沙河水库)为例,分析了2021年枯水期(1—3月)和丰水期前期(4—6月)氮(N)、磷(P)、铁(Fe)和叶绿素a(Chl.a)浓度的变化趋势,并通过原位添加实验,解析浮游植物丰度和多样性对N、P、Fe加富的响应。结果表明:与1—3月相比,4—6月期间水体总磷浓度(TP)明显升高,总铁浓度(TFe)呈增加趋势但月度间波动较大,总氮浓度(TN)在4月最低,之后缓慢增加,期间Chl.a浓度从3月的5 μg/L快速增加到5月的29 μg/L。原位实验结果表明:浮游植物群落以蓝藻、绿藻和硅藻为主要组成,所有营养盐添加组浮游植物丰度均有增加,但只有NP同时添加时(NP和FeNP两组)生物量(以Chl.a表征)有显著升高;营养盐添加组细胞丰度的响应在门类和种类间差异明显,实验组组间群落结构和优势种类差异显著,所有处理组的群落多样性均明显高于对照组。N和P添加及其与Fe的联合添加(N、P、NP、FeN、FeP和FeNP)均导致蓝藻丰度升高,绿藻仅在NP添加组(FeNP组和NP组)显著升高且两组没有显著差异,硅藻仅在N和P单独添加组(N和P)显著升高。上述结果说明浮游植物生物量受N、P营养盐的共同影响而非单因子作用,N、P和Fe添加均影响群落结构和多样性,对水库富营养化的管理尤其是蓝藻水华防治应综合考虑3种营养盐的共同作用。     

The composition of nutrient fluxes from contrasting UK river basins

Accurate estimates of N and P loads were obtained for four contrasting UK river basins over a complete annual cycle. The fractionation of these loads into dissolved and particulate, and inorganic and organic components allowed a detailed examination of the nutrient load composition and of the factors influencing both the relative and absolute magnitude of these components. The particulate phosphorus (TPP) loads account for 26–75% of the annual total phosphorus (TP) transport and are predominantly inorganic. The inorganic (PIP) and organic (POP) fractions of the TPP loads represent 20–47% and 6–28% of the annual TP transport, respectively. In contrast, the particulate nitrogen loads (TPN) represent 8% or less of the annual total nitrogen (TN) loads and are predominately organic. For dissolved P transport, the dissolved inorganic fraction (DIP) is more important, representing 15–70% of the TP loads, whereas the dissolved organic fraction (DOP) represents only 3–9% of the TP loads. The TN loads are dominated by the dissolved component and more particularly the total oxidized fraction (TON), which is composed of nitrate and nitrite and represents 76–82% of the annual TN transport. The remaining dissolved N species, ammonium (NH₄-N) and organic N (DON) account for 0·3–1·2% and 13–16% of the annual TN transport, respectively. The TPN and TPP fluxes closely reflect the suspended sediment dynamics of the study basins, which are in turn controlled by basin size and morphology. The dissolved inorganic nutrient fluxes are influenced by point source inputs to the study basins, especially for P, although the TON flux is primarily influenced by diffuse source contributions and the hydrological connectivity between the river and its catchment area. The dissolved organic fractions are closely related to the dissolved organic carbon (DOC) dynamics, which are in turn influenced by land use and basin size. The magnitude of the NH₄-N fraction was dependent on the proximity of the monitoring station to point source discharges, because of rapid nitrification within the water column. However, during storm events, desorption from suspended sediment may be temporarily important. Both the magnitude and relative contribution of the different nutrient fractions exhibit significant seasonal variability in response to the hydrological regime, sediment mobilization, the degree of dilution of point source inputs and biological processes. © 1998 John Wiley & Sons, Ltd.     

乌梁素海沉积物中全磷的分布特征

开展了浅水草型湖泊乌梁素海沉积物中TP(全磷)的分布特征研究。结果表明,乌梁素海表层沉积物中TP含量在0.37~0.99 g/kg之间变化,平均值为0.75 g/kg;水平分布上,TP含量呈现从湖区四周向湖心递减的变化趋势,大部分湖区已具有生态毒性效应,并对湖区底栖生物群落和生态环境构成了较大威胁;垂向上,尽管沉积物中TP含量有所波动,但0~10 cm的表层沉积物中TP含量均随深度增加而递减,揭示了近年来人类活动的加剧对乌梁素海沉积物中磷累积的重大影响;实验得出了粉砂、粘土粒级>极细砂粒级>细砂粒级>中砂以上粒级的TP含量序列,各粒级对TP的吸附贡献率由吸附能力和质量百分比共同控制;磷的沉积对乌梁素海富营养化进程有深远影响。