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61.
A method was developed for the determination of organic halogens in water samples with the aim of minimizing matrix effects and simplifying the sample preparation technique commonly used. The method is based on the adsorption of organic halogens in modified hydrophilic divinylbenzene polymer columns and their elution with methanol. The adsorbent used enables rapid adsorption and desorption due to comparatively high operating flow rates and minimized solvent amounts. Furthermore, no additional reconcentration steps are needed. The methanol extract obtained is combusted with a standard EOX (extractable organic halogen) analyzer and the concentration of organically bound halogens is determined by microcoulometric analysis. The matrix effects are considerably reduced compared to the standard procedure (EN 1485) commonly used. A detection limit of 13 μg/L was established. 相似文献
62.
Migration characteristics of dense non-aqueous phase liquids (DNAPLs) in the subsurface can be expressed as a water–DNAPL two-phase system based on mainly the k–S–p relations, which describe the relations among relative permeability (k), degree of water saturation (S), and capillary pressure head (p). The aims of this research are to develop an experimental system with new type of probes, such as the electrical conductivity probe for measuring the degree of water saturation and the hydrophilic and hydrophobic tensiometer for measuring the pore water and DNAPL pressures, and also to estimate the results obtained from the developed experimental system. From these tests, the excellent k–S–p relations were obtained and the efficiency and validity of this developed experimental system have been confirmed in terms of the concept of the scaling coefficient calculated by interfacial tensions. 相似文献
63.
Predictions from dynamic modelling of the lithospheric deformation are presented for Northern Europe, where several basins underwent inversion during the Late Cretaceous and Early Cenozoic and contemporary uplift and erosion of sediments occurred. In order to analyse the evolution of the continental lithosphere, the equations for the deformation of a continuum are solved numerically under thin sheet assumption for the lithosphere. The most important stress sources are assumed to be the Late Cretaceous Alpine tectonics; localized rheological heterogeneities can also affect local deformation and stress patterns. Present-day observations available in the studied region and coming from seismic structural interpretations and stress measurements have been used to constrain the model. Our modelling results show that lateral variation in lithospheric strength below the basin systems in Central Europe strongly controls the regional deformation and the stress regime. Furthermore, we have demonstrated that the geometry of the boundary between Baltica and Avalonia, together with different rheological characteristics of the two plates, had a crucial role on local crustal deformation and faulting regime resulting in the Baltica–Avalonia transition zone from the S–N Alpine convergence. 相似文献
64.
Philippe Machetel 《Comptes Rendus Geoscience》2003,335(1):91-97
The numerical models of mantle convection agree to depict avalanches behaviour according to the level of endothermicity of the spinel → perovskite phase change. Their potential effects on the global thermal and dynamical states of the mantle have been computed thanks to a numerical code, which takes into account both the 400-km exothermic and the 660-km endothermic phase changes. The cycle followed by the avalanches is: local layering, destabilization of the 660-km thermal layer, travelling and spreading on the core, and reappearing of the local layering. Therefore, mantle convection is characterized by quiet periods of partial layering embedded in catastrophic events. During the avalanche, the amplitude of the surface velocity is multiplied by two, which would imply an enhanced plate tectonic and ridge activities. The global thermal effects of the avalanche are compatible with a high mantle temperature and an acceleration of Earth's rotation during the Cretaceous. They also offer a coherent explanation to locate the origin of mantle plumes both within the CMB and just below the transition zone. 相似文献
65.
The impact of accelerometry on CHAMP orbit determination 总被引:6,自引:0,他引:6
The contribution of the STAR accelerometer to the CHAMP orbit precision is evaluated and quantified by means of the following
results: orbital fit to the satellite laser ranging (SLR) observations, GPS reduced-dynamic vs SLR dynamic orbit comparisons,
and comparison of the measured to the modeled non-gravitational accelerations (atmospheric drag in particular). In each of
the four test periods in 2001, five CHAMP arcs of 2 days' length were analyzed. The mean RMS-of-fit of the SLR observations
of the orbits computed with STAR data or the non-gravitational force model were 11 and 24 cm, respectively. If the accelerometer
calibration parameters are not known at least at the few percent level, the SLR orbit fit deteriorates. This was tested by
applying a 10% error to the along-track scale factor of the accelerometer, which increased the SLR RMS-of-fit on average to
17 cm. Reference orbits were computed employing the reduced-dynamic technique with GPS tracking data. This technique yields
the most accurate orbit positions thanks to the estimation of a large number of empirical accelerations, which compensate
for dynamic modeling errors. Comparison of the SLR orbits, computed with STAR data or the non-gravitational force model, to
the GPS-based orbits showed that the SLR orbits employing accelerometer observations are twice as accurate. Finally, comparison
of measured to modeled accelerations showed that the level of geomagnetic activity is highly correlated with the atmospheric
drag model error, and that the largest errors occur around the geomagnetic poles.
Received: 7 May 2002 / Accepted: 18 November 2002
Correspondence to: S. Bruinsma
Acknowledgments. The TIGCM results were obtained from the CEDAR database. This study was supported by the Centre National d'Etudes Spatiales
(CNES). The referees are thanked for their helpful remarks and suggestions. 相似文献
66.
Geoid determination using adapted reference field, seismic Moho depths and variable density contrast 总被引:4,自引:0,他引:4
The traditional remove-restore technique for geoid computation suffers from two main drawbacks. The first is the assumption
of an isostatic hypothesis to compute the compensation masses. The second is the double consideration of the effect of the
topographic–isostatic masses within the data window through removing the reference field and the terrain reduction process.
To overcome the first disadvantage, the seismic Moho depths, representing, more or less, the actual compensating masses, have
been used with variable density anomalies computed by employing the topographic–isostatic mass balance principle. In order
to avoid the double consideration of the effect of the topographic–isostatic masses within the data window, the effect of
these masses for the used fixed data window, in terms of potential coefficients, has been subtracted from the reference field,
yielding an adapted reference field. This adapted reference field has been used for the remove–restore technique. The necessary
harmonic analysis of the topographic–isostatic potential using seismic Moho depths with variable density anomalies is given.
A wide comparison among geoids computed by the adapted reference field with both the Airy–Heiskanen isostatic model and seismic
Moho depths with variable density anomaly and a geoid computed by the traditional remove–restore technique is made. The results
show that using seismic Moho depths with variable density anomaly along with the adapted reference field gives the best relative
geoid accuracy compared to the GPS/levelling geoid.
Received: 3 October 2001 / Accepted: 20 September 2002
Correspondence to: H.A. Abd-Elmotaal 相似文献
67.
结合传输型对地观测小卫星一体化设计的特点,介绍了一种用于对地观测小卫星系统的锁相接收机的-构成及原理,并对系统的相位噪声性能进行了详尽的分析,提出了对其相位噪声进行技术控制的方法。通过文中的分析与研究,消除了由于对地观测小卫星相位噪声所引起的系统误码率的恶化,提高了系统的可靠性,为下一步对地观测小卫星的发展与应用打下了良好的技术基础。 相似文献
68.
GPS载波相位三差观测方程的改化 总被引:3,自引:0,他引:3
本文根据相关测量平差原理推导出改化GPS载波相位三差观测方程的算法,使改化后的协因数呈分块对角体。这种改化算法不但顾及观测值的相关性,而且节省大量的存储单元。使采用严密平差法平差三差观测值成为一种最简单的数据处理方法之一。 相似文献
69.
榴辉岩中铁铝榴石的测定方法研究 总被引:3,自引:1,他引:3
对国内主要矿区铁铝石榴子石纯矿物中铁的价态规律进行了研究。证明其所含Fe均以Fe^2+为主,其质量分数在83-94,并将Fe^2+这特征性成分用于某地榴辉岩中铁铝榴石的间接测定,获得结果与焙烧磁化-磁选法一致且精度好,较磁化法简便,快速。 相似文献
70.
We have examined the effects of the spinel-garnet phase transition on subsidence of extensional sedimentary basins. For a constant positive Clapeyron slope ( dP/dT ), the phase boundary moves downwards in the syn-rift and upwards in the post-rift phase. For a non-linear Clapeyron curve ( dP/dT > 0 above 900°C and dP/dT < 0 below 900°C), theory predicts for the reaction of the spinel-garnet phase transition, the direction of phase boundary movement is dependent on the stretching factor, the position of the Clapeyron curve and the lithospheric thickness. A smaller syn-rift and larger post-rift subsidence are predicted for a deeper phase boundary and a thicker lithosphere. The model with a non-linear Clapeyron curve is applied to the subsidence histories of a young extensional basin (Gulf of Lion) and an old continental margin (eastern Canada). The observed syn-rift uplift and the larger post-rift subsidence can be reasonably explained by this model, where the optimum depth of the phase boundary for eastern Canada (˜90 km) is consistent with the estimate from seismic observations and is larger than that for the Gulf of Lion (˜ 50 km). The depth of the spinel-garnet phase boundary is sensitive to the composition of mantle rocks and increases with the extraction of basaltic components from the lithosphere, compatible with our result that the phase boundary is deeper for an older and thicker lithosphere. Thus the surface movement associated with the rifting for these areas may reflect the chemical evolution of the continental lithosphere. 相似文献