海水中234Th的超低水平液闪谱仪测定

本文提出了利用超低水平液闪谱仪测定海水中234Th的方法.海水经氢氧化铁吸附共沉淀富集后,接着用阴离子交换和TBP/煤油萃取进行Th同位素的分离与纯化.对一系列测定条件进行了详细的研究,提出了测定海水中234Th的适宜程序,即在含有234Th和产额示踪剂230Th的纯化后的5mol/dm3HNO3溶液中加入TBP/煤油进行萃取,然后用0.1mol/dm3HNO3反萃取,后者是先用契伦柯夫计数法测量234Th(通过234mPa),后加入闪烁液Hisafe 3用α/β模式测量α放射体230Th.对于α和β放射体液闪谱仪的计数效率分别为100%和55.7%±2.7%.234Th的化学回收率和总探测效率分别为70%～80%和30%～45%.该法测定海水中的234Th快速、简便和高效.     

Estimation of Sea Ice Thickness from SARAL/AltiKa in Drifting Orbit Phase

Abstract

Intra and inter-annual variations in the sea ice thickness are highly sensitive indicators of climatic variations undergoing in the earth’s atmosphere and oceans. This paper describes the method of estimating sea ice thickness using radar waveforms data acquired by SARAL/Altika mission during its drifting orbit phase from July 2016 onwards yielding spatially dense data coverage. Based on statistical analysis of return echoes, classification of the surface has been carried out in three different types, viz. floe, lead and mixed. Time delay correction methods were suitably selected and implemented to make corrections in altimetric range measurements and thereby freeboard. By assuming hydrostatic equilibrium, freeboard data were converted into sea ice thickness. Results show that sea ice thickness varies from 4 to 5?m near ice shelves and 1 to 2.5?m in the marginal sea ice regions. Freeboard and sea ice thickness estimates were also validated using NASA’s Operation Ice Bridge (OIB) datasets. Freeboard measurements show very high correlation (0.97) having RMSE of 0.13. Overestimation of approximately 1–2?m observed in the sea ice thickness, which could be attributed to distance between AltiKa footprint and OIB locations. Moreover, sensitivity analysis shows that snow depth and snow density over sea ice play crucial role in the estimation of sea ice thickness.     

Diet of albacore Thunnus alalunga from the waters of Mauritius (western Indian Ocean) inferred from stomach contents and fatty acid analysis

The diet of albacore Thunnus alalunga from their spawning ground in the waters of Mauritius was investigated. The stomach contents of 249 albacore individuals, caught by industrial longliners and artisanal fishers, was analysed, and the dominant prey taxa were selected for lipid and fatty acid (FA) analysis. The FA profiles of prey were compared with those of liver tissue of spawning-capable and post-spawning female albacore, using multivariate analysis. Whereas stomach content analysis identified cephalopods and crustaceans as the dominant prey items in number, FA-profile analysis identified crustaceans and fishes as the most-frequently consumed prey of post-spawning female albacore. In contrast, the FA profiles of spawning-capable albacore and those of prey showed very low similarity. Analysis of the prey suggests that although cephalopods, crustaceans and fishes could all provide albacore with the required lipids and FAs, cephalopod prey seem to be less desirable owing to their lower energy content (i.e. low in total lipid, triacylglycerol, 16:0, 18:0 and 18:1ω9). Instead, the most beneficial food appeared to be locally available fishes, which are more energy-rich and have a higher docosahexaenoic acid/ eicosapentaenoic acid ratio. These results provide new information on the trophic ecology of albacore, promote our understanding of the importance of prey type for successful reproduction of albacore, and highlight the advantages of FA profiling to study diet.     

广西沿岸海平面变化的关联维数研究

采用相空间重构和关联维数方法，研究了广西沿岸月平均海平面变化的分形特征，结果表明，相空间重构的延迟时间τ为3△t，当关联维数趋于饱和时，石头埠，北海和龙尾的相空间维数为7，而涠洲岛为9，它们的关联维数平均值平均值分别为6.6507,6.5414,6.7059.     

碳水化合物的组合合成

碳水化合物的组合合成是一项新兴技术，该技术可以在短时间内合成大量用于进行生物活性筛选的寡糖及拟糖物。液相与固相合成技术可以极大地加快药物研究与开发进程。作者针对该技术在碳水化合物合成方面的研究进展情况进行讨论。     

Growth and reproduction of the bivalve Spisula subtruncata (da Costa) in Dutch coastal waters

The bivalve Spisula subtruncata is usually abundant in shallow coastal waters along the Dutch coast. However, its biomass has been decreasing since 1995. In order to assess whether reproductive failure may be the cause of the observed decline over the last decades, the energy investment in reproduction of a population of S. subtruncata from central Dutch coastal waters was studied. The population studied consisted of individuals of up to four years old. Shell length reached maximum values of around 32 mm and individual total body, somatic and gonadal ash-free dry mass reached maximum values of about 278 mg AFDM, 252 mg AFDM and 76 mg AFDM, respectively. A clear seasonal cycle in somatic and gonadal mass was observed. Somatic and gonadal mass indices increased in early spring and reached maximum values during summer, followed by a decrease to minimum values at the beginning of the following year. Spawning was in June–July and settlement of spat seems to have occurred in July–August. Mean oocyte diameter was 57.43 ± 0.03 μm, corresponding to a volume of 98972 μm³. These results suggested that reproductive failure was not the cause of the current population decline. Most likely, unsuccessful settlement of spat and/or severe predation during the first months of life were responsible for the observed patterns.     

新生相形成的模拟实验研究

通过模拟实验制备了硅酸盐类不溶性固体，从Ｘ射线衍射特征和红外光谱特征两方面看，制得的硅酸盐类与河口新生相成分，结构相似，表明铁水解成的β－ＦｅＯＯＨ胶体吸附Ｓｉ，Ａｌ，Ｍｇ，Ｋ等元素，经结构重组可形成硅酸盐矿物，这可能是河口体系新生相的形成原因。     

磁通门罗盘的原理

磁通门罗盘是一种新型罗盘。此罗盘的关键部件是探头,探头主要是由高导磁的软磁材料做成的磁环和线圈组成。当在初级线圈加上交变的激励信号时,即可得到与次级线圈在地磁场中相对应的磁方位角。本文介绍其原理,并对其进行了理论分析。