涂钨热解石墨管－石墨炉原子吸收法测定天然水中痕量钡

选择涂钨热解石墨管测钡，克服了钡的碳化物形成而提高了方法的灵敏度，采用钙做基体补偿不仅克服钙对测钡的影响，同时也对测钡起增敏作用，结合其它测定条件的优化实现了石墨炉原子吸收法测定天然水中的痕量钡。其线性范围在０～７０μｇ／Ｌ检出限３．３ｐｇ，特征质量为２．９ｐｇ／１％吸收，对５μｇ／ＬＢａ试液测定１１次，其ＲＳＤ为６．９％，加标回收率８９％～１２０％。方法经标样分析验证，结果与标准值相符。     

5－（4－羧基苯偶氮）－8－（对甲苯磺酰氨基）－喹啉与金显色反应研究及应用

以８－氨基喹啉为母体，合成了新试剂５－（４－羧基苯偶氮）－８－（对甲苯磺酰氨基）－喹啉（ＣＰＴＳＱ），研究了它与Ａｕ的显色反应，在ＣＴＭＡＢ存在下，于ｐＨ１０～１３的ＮａＯＨ介质中，ＣＰＴＳＱ与Ａｕ形成２：１紫蓝色络合物，最大吸收峰位于６１０ｎｍ，摩尔吸光系数１．０×ｌ０５Ｌ·ｍｏｌ－１·ｃｍ－１，Ａｕ含量在０～１．２ｍｇ／Ｌ内符合比尔定律。方法选择性好，灵敏度高，操作简便，已用于金矿石样品中Ａｕ的测定，结果满意。     

Preliminary seismic hazard maps of Slovenia

The preparation of the preliminary seismic hazard maps of the territory of Slovenia has been based on an expansion of the basic approach laid out by Cornell in 1968. Three seismic source models were prepared. Two of them are based mainly on the earthquake catalogue using the Poissonian probability model. A map of seismic energy release and a map of earthquake epicenter density are used to delineate seismic sources in these models. The geometry of the third model which is based on a rough estimate of seismotectonic setting is taken from the probabilistic seismic hazard analysis of a nuclear power plant in Slovenia. Published ground motion attenuation models based on strong motion records of recent strong earthquakes in Italy are used. Test maps for variable and uniform b-values are presented. The computer program, Seisrisk III, developed by the U.S. Geological Survey is used.     

Generating fracture networks using iterated function systems

In order to model flow and transport in fractured rocks it is important to know the geometry of the fracture network. A stochastic approach is commonly used to generate a synthetic fracture network from the statistics measured at a natural fracture network. The approach presented herein is able to incorporate the structures found in a natural fracture network into the synthetic fracture network. These synthetic fracture networks are the images generated by Iterated Function Systems (IFS) as introduced by Barnsley (1988). The conditions these IFS have to fulfil to determine images resembling fracture networks and the effects of their parameters on the images are discussed. It is possible to define the parameters of the IFS in order to generate some properties of a fracture network. The image of an IFS consists of many single points and has to be suitably processed for further use.     

Hazard mapping based on macroseismic data considering the influence of geological conditions

The object of this study is to consider directly the influence of regional geological conditions on the assessment of seismic hazard. It is assumed that macroseismic data at individual locations contain, in an average way, the influence of geological conditions.A Data Base referring to 199 historical (5) and instrumental (194, in the 1947–1993 period) events with macroseismic information in 1195 locations of Portugal was built. For any given seismic event, whenever macroseismic information was available at a location (town, village, etc.), an EMS-92 intensity value was estimated. To each one of those locations a geological unit, representing the most common type of soil, was assigned, based on the Geological Portuguese Map at a scale 1:500 000; the geological units were grouped into three categories: soft, intermediate and hard soils.The Data Base was used to determine the attenuation laws in terms of macroseismic intensity for the three different geological site conditions, using multiple linear regression analysis. The reasonability of the laws was tested by (i) checking residual distributions and (ii) comparing the map of isoseismals of important earthquakes with the isoseismals generated by the attenuation curves derived for each one of the three different soil classes, taking into consideration the soil class of each site. The main results of attenuation modeling are: high dispersion on macroseismic intensity data; all the models predict intensity values, for short hypocentral distances, lower than the ones observed; and for some important analyzed earthquakes and for the observed range of distances, the models confirm the expectancy that macroseismic intensity increases from hard to soft soil.The approach to obtain the hazard assessment at each location consisted in the use of the attenuation law specifically derived for the class of soil of that particular location. This method, which considers the influence of the regional geology, was illustrated with the mapping of hazard for the country for several return periods. Comparison with previous maps not taking into consideration the regional geological conditions emphasizes the importance of this new parameter. It can be concluded that (i) soil segmentation is clearly the cause for hazard increase in the region to the north of Lisbon, especially at sites with soft and intermediate soils as the ones in lower Tagus valley; the maximum increase on hazard is, in any case, less than one degree; (ii) when geological conditions are disregarded in the attenuation regression analysis, hazard pattern is similar to the one obtained for the case of hard soil everywhere.     

Seismic hazard assessment in the Ionian Islands based on observed macroseismic intensities

Catalogues of actual observed intensities are constructed for three towns in the Ionian Islands. They are used for seismic hazard assessment and the results are compared with those obtained by standard approaches; that is, by statistics applied to the data computed from epicentral parameters. The results show that seismic hazard is better assessed using observed rather than computed data, but preparation of the local catalogue presents non-trivial difficulties.     

鄂西震旦系上统含磷岩系的划分与对比

上震旦统陡山沱组是鄂西地区最具工业价值的含磷地层。著名的磷矿有荆襄磷矿、宜昌磷矿、兴(山)神(农架)保(康)磷矿。迄今已有20多年的勘探史,但由于各矿区研究程度不一,又缺古生物依据,亦不能依靠同位素年龄来作划分对比,故在地层及磷矿层的划分、对比上认识不一。笔者结合磷矿特征及含磷岩系岩类组合、剖面结构特点、稀土元素特征等,将本区划分为4个磷矿分布区,将陡山沱组划分为3个岩性段、5个含磷层位。     

时间剖面上小断层的计算机自动检测

煤田地震勘探一直探寻着对小断层的自动检测方法，因受各种因素的影响，至今尚无良策。本文介绍了多元地震参数的模式识别方法，并通过模型及实测资料成功地检测到１０ｍ以下小断层。     

138铀矿床成矿地质及物化条件分析

１３８矿床是中生代火山－沉积改造型铀矿床。本文对矿床的铀源、矿区地层岩性、岩相古地理及古气候、构造和改造再生等地质条件，以及铀的吸附还原剂，岩石的有效孔隙度、化学成分、酸碱度、氧化还原电位等物理化学条件进行探讨。     

开发利用地理信息系统(GIS)综合分析地学信息进行矿产预测

众所周知,矿产资源预测是综合地学信息,进行优选靶区的有效手段之一。随着地学工作的深入和勘探技术的发展,已获取了大量的多源地学信息,如地质、地球物理、地球化学和遥感等资料。怎样从这众多的资料中提取有用信息进行综合分析,达到矿产资源预测的目的,一直是地学界探索的课题。过去,应用人工的方法来进行此项工作,不但费力、投资大,而且难以达到预期的效果,方法技术也不利于推广。如今,高速、高质量的计算机已趋于普及,使应用计算机技术高效地处理堆积如山的资料成为可能,尤其是近些年发展起来的地理信息系统(GIS),为综合处理地学资料的矿产资源预测的方法技术,开拓了广阔的前景。地理信息系统是一种计算机系统的应用软件,它集数据库管理和图像分析技术为一体,以空间数据迭加分析为重要特征。地学工作者进行矿产资源预测时,通常是从多源地学资料中提取有用信息,再应用专家知识,结合数学方法,如逻辑运算、贝叶斯(Bayes)规则等,建立预测模型,以模型的推理网格为线索,利用地理信息系统有效的空间分析手段,把各种证据图层综合迭加,最终产生以概率为指标的矿产资源预测图,高概率指示有利的矿产资源远景区,可作为勘探者和决策者进行勘查规划的依据。