复配型席夫碱缓蚀剂对碳钢在海水中缓蚀性能研究

设计了由邻氧乙酸苯甲醛-4-吡啶甲酰腙席夫碱80 mg/L,邻香草醛脱氢枞胺席夫碱6 mg/L,ZnSO4 50 mg/L,Tween-80 100 mg/L四元复配缓蚀剂,通过失重法、极化曲线法和电化学交流阻抗技术,研究了该复配缓蚀剂在模拟现实使用环境中的缓蚀性能。结果表明,该复配缓蚀剂的缓蚀率受海水盐度的影响不大,但该复配缓蚀剂的缓蚀性能受海水温度和海水流速的影响较大,当温度低于50℃和流速较低、缓蚀剂浓度为临界浓度时,缓蚀剂对碳钢有很好的抑制作用,而有锈试样和间浸实验发现高浓度的复配缓蚀剂可以抑制碳钢的腐蚀。     

环渤海地区港口建设中的环境工程地质问题

环渤海地区地壳稳定性较差,沿海地带软土地基、沙土液化等不良工程地质问题较多,存在崩塌、滑坡、侵蚀淤积等环境地质灾害。特别是由地下水开采引起的地下水位下降漏斗、地面沉降、海水入侵等灾害严重。本文章介绍了环渤海港口工程地质环境,并就原生地质环境、次生地质环境、人为地质环境对港口建设的影响进行论述。     

地质雷达在海岛调查中的应用

地质雷达探测技术正朝着探测精度更高、探测范围更广、解释更准确的方向发展,表现出前所未有的广阔发展前景,被广泛应用于工程、环境、灾害地质调查等领域,越来越受到人们的关注。随着海岛的开发与海岛基础设施的建设,海岛工程勘查与工程质量评估和地质灾害的影响与危害评估等工作越来越多。本文章结合地质雷达探测的优势,分析了海岛开发和地质调查中的研究内容,结合海岛上的滑坡监测、浅层断裂等地质灾害勘探实例,论述了地质雷达在海岛工程与地质调查中的应用。     

基于Moodle的变形监测技术网络课程开发及应用

为提高网络在线教学效果,适应疫情期间线上教学需求,本文基于Moodle开源在线教育平台构建了广泛适应的变形监测网络在线课程资源库。简述了Moodle在线课程建设的过程、方法及应注意的问题,重点讨论了试题库、案例库及线上线下交流模块的开发步骤。根据双一流建设与工程认证的OBE教学理念,对变形监测技术网络课程教学建设应遵循的基本原则、问题及毕业要求达成值评价方法进行了探讨。研究表明,网络在线课程的应用,促进了教学资源的共享和师生交流,降低了教师上课的劳动强度,提高了学生学习的积极性。通过合理制定课程目标,有效评价毕业要求的达成情况和持续改进教学手段,对提高变形监测技术课程教学效果有积极意义。     

某深埋特长隧洞线路比选方案研究

滇中引水工程香炉山隧洞为特长深埋隧洞,起点位于冲江河右岸石鼓镇,终点位于洱海边的长育村,此前已对该段进行东、中、西等多方向的较大范围线路比选[1]。通过已有地质资料进行线路对比,提出了8条比选线路,从各线路长度和形态,存在的主要工程地质问题,隧洞地质、施工条件等进行比较、分析、研究,最终选定中4线为推荐方案。论文简要介绍了隧洞线路选线方案、比选的思路和方法,以期为相关工程的规划设计提供参考。     

四川省蓬溪县安置点地质灾害危险性评估

通过对天福镇三关村安置点建设用地的地形地貌、地层岩性、地质构造与区域稳定性、水文地质条件等工程地质条件的分析,对场地进行了危险性现状评估、预测评估及综合评估,并提出了灾害防治建议。     

Selection of Less Biased Threshold Angles for SAM Classification Using the Real Value–Area Fractal Technique

The accuracy of classification of the Spectral Angle Mapping (SAM) is warranted by choosing the appropriate threshold angles, which are normally defined by the user. Trial‐and‐error and statistical methods are commonly applied to determine threshold angles. In this paper, we discuss a real value–area (RV–A) technique based on the established concentration–area (C–A) fractal model to determine less biased threshold angles for SAM classification of multispectral images. Short wave infrared (SWIR) bands of the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) images were used over and around the Sar Cheshmeh porphyry Cu deposit and Seridune porphyry Cu prospect. Reference spectra from the known hydrothermal alteration zones in each study area were chosen for producing respective rule images. Segmentation of each rule image resulted in a RV–A curve. Hydrothermal alteration mapping based on threshold values of each RV–A curve showed that the first break in each curve is practical for selection of optimum threshold angles. The hydrothermal alteration maps of the study areas were evaluated by field and laboratory studies including X–ray diffraction analysis, spectral analysis, and thin section study of rock samples. The accuracy of the SAM classification was evaluated by using an error matrix. Overall accuracies of 80.62% and 75.45% were acquired in the Sar Cheshmeh and Seridune areas, respectively. We also used different threshold angles obtained by some statistical techniques to evaluate the efficiency of the proposed RV–A technique. Threshold angles provided by statistical techniques could not enhance the hydrothermal alteration zones around the known deposits, as good as threshold angles obtained by the RV–A technique. Since no arbitrary parameter is defined by the user in the application of the RV‐A technique, its application prevents introduction of human bias to the selection of optimum threshold angle for SAM classification.     

Controlling Factors,Accumulation Model and Target Zone Prediction of the Coal‐bed Methane in the Huanghebei Coalfield,North China

The Huanghebei Coalfield, one of the coal production bases in North China, was considered as a coalfield without coal‐bed methane (CBM) during past decades. In recent years, however, CBM has been discovered in coal‐bearing successions. In order to understand the CBM geological characteristics and accumulation process in this area, fifteen coal samples were collected and analyzed with respect to coal maceral and reflectance. The result shows that the gas distribution is uneven and the content varies in different areas even for the same coal bed. The storage of CBM is affected by geological factors such as burial depth, geological structures, and magmatic intrusion, among which the former two are more important in the formation of CBM. Deep burial of coal beds with the presence of cap‐rock mudstone can seal CBM. The CBM is also accumulated and preserved at the place where normal faults are distributed. Magmatic intrusion causes contact metamorphism and controls the CBM formation by heating the coal‐bearing successions. The obtained data indicate the geological conditions in northeastern Zhaoguan Mine are preferable for CBM formation and conservation; recent exploration estimates the CBM geological reserves up to 282.16 Mm³ and average of reserve abundance at 0.1662 × 10⁸ m³ km^?2. The Changqing Mine is a potential prospect in terms of CBM exploration since its geological conditions (structures and burial depth) are similar to the Zhaoguan Mine and its cap rock is even better.     

Calcium,Na, K and Mg Concentrations in Seawater by Inductively Coupled Plasma‐Atomic Emission Spectrometry: Applications to IAPSO Seawater Reference Material,Hydrothermal Fluids and Synthetic Seawater Solutions

We report a measurement procedure to determine simultaneously the major cation concentrations (Na, Ca, K and Mg) of seawater‐derived solutions by inductively coupled plasma‐atomic emission spectrometry. The best results were obtained when the IAPSO (‘standard’) seawater reference material was diluted by thirty times with Milli‐Q^® water. We obtained an average reference value r_K (the ratio of the mass fraction of potassium to that of chlorine, i.e., (g kg^?1)/(g kg^?1)) for IAPSO seawater of 0.0205 ± 0.0006 (2.9% RSD), not significantly different from 0.0206 ± 0.0005 (2.4% RSD) for seawater composition reported in the literature. The measured Na, Ca and Mg concentrations correspond to r_Na, r_Ca and r_Mg values of 0.5406 ± 0.0026 (0.5% RSD), 0.02192 ± 0.00048 (2.2% RSD) and 0.06830 ± 0.00047 (0.7% RSD), respectively, in line with previous values measured by wet‐chemistry and atomic absorption spectrophotometry or wet‐chemical titration. Our measurement procedure was used successfully on synthetic seawater solutions and high‐temperature hydrothermal fluids.     

Sulfur Concentration in Geochemical Reference Materials by Solution Inductively Coupled Plasma‐Mass Spectrometry

With implications for the origin of ore deposits, redox state of the atmosphere, and effects of volcanic outgassing, understanding the sulfur cycle is vital to our investigation of Earth processes. However, the paucity of sulfur concentration measurements in silicate rocks and the lack of well‐calibrated reference materials with concentrations relevant to the rocks of interest have hindered such investigations. To aid in this endeavour, this study details a new method to determine sulfur concentration via high mass resolution solution inductively coupled plasma‐mass spectrometry (ICP‐MS). The method is based on an aqua regia leach, involving relatively rapid sample preparation and analysis, and uses small test portion masses (< 50 mg). We utilised two independently prepared standard solutions to calibrate the analyses, resulting in 4% accuracy, and applied the method to eight geochemical reference materials. Measurements were reproducible to within ~ 10%. Sulfur concentrations and isotopes of six reference materials were measured additionally by elemental analyser‐combustion‐isotope ratio mass spectrometry to independently evaluate the accuracy of the ICP‐MS method. Reference materials that yielded reproducible measurements identical to published values from other laboratories (JGb‐1, JGb‐2 and MAG‐1) are considered useful materials for the measurement of sulfur. Reference materials that varied between studies but were reproducible for a given test portion perhaps suffer from sample heterogeneity and are not recommended as sulfur reference materials.