Screening the current soil drainage class map of Flanders (Belgium) for its predictive quality

The predictive quality of the current drainage class map of Flanders was evaluated using data from two monitoring networks: one with good spatial coverage but poor temporal coverage and another with better temporal but poor spatial coverage. We combine both networks to obtain 1678 point predictions for mean highest water (MHW) and mean lowest water (MLW) tables by applying time series modelling and total least squares regression. The resulting MHW and MLW point data set was used to evaluate the currency of the existing map and to identify regional differences. The quality of the current map is moderate, and large differences occur between regions. Especially the Campine region shows large and systematic differences, whereas the southeastern hills and chalk–loam region is relatively accurate. If more weight is given to errors in the wetter drainage classes, about 50% of the area of Flanders would benefit from remapping. Copyright © 2011 John Wiley & Sons, Ltd.     

Multifractal behaviour of long‐term karstic discharge fluctuations

Karstic watersheds are highly complex hydrogeological systems that are characterized by a multiscale behaviour corresponding to the different pathways of water in these systems. The main issue of karstic spring discharge fluctuations consists in the presence and the identification of characteristic time scales in the discharge time series. To identify and characterize these dynamics, we acquired, for many years at the outlet of two karstic watersheds in South of France, discharge data at 3‐mn, 30‐mn and daily sampling rate. These hydrological records constitute to our knowledge the longest uninterrupted discharge time series available at these sampling rates. The analysis of the hydrological records at different levels of detail leads to a natural scale analysis of these time series in a multifractal framework. From a universal class of multifractal models based on cascade multiplicative processes, the time series first highlights two cut‐off scales around 1 and 16 h that correspond to distinct responses of the aquifer drainage system. Then we provide estimates of the multifractal parameters α and C₁ and the moment of divergence q_D corresponding to the behaviour of karstic systems. These results constitute the first estimates of the multifractal characteristics of karstic spingflows based on 10 years of high‐resolution discharge time series and should lead to several improvements in rainfall‐karstic springflow simulation models. Copyright © 2012 John Wiley & Sons, Ltd.     

Pulse generation models for daily intermittent streamflows / Modèles de génération d’impulsions pour des débits journaliers intermittents

Abstract

Abstract Generating pulses and then converting them into flow are two main steps of daily streamflow generation. Three pulse generation models have been proposed on the basis of Markov chains for the purpose of generating daily intermittent streamflow time series in this study. The first one is based on two two-state Markov chains, whereas the second uses a three-state Markov chain. The third model uses harmonic analysis and fits Fourier series to the three-state Markov chain. Results for a daily intermittent streamflow data series show a good performance of the proposed models.     

Discrete wavelet‐based trend identification in hydrologic time series

Trend identification is a substantial issue in hydrologic series analysis, but it is also a difficult task in practice due to the confusing concept of trend and disadvantages of methods. In this article, an improved definition of trend was given as follows: ‘a trend is the deterministic component in the analysed data and corresponds to the biggest temporal scale on the condition of giving the concerned temporal scale’. It emphasizes the intrinsic and deterministic properties of trend, can clearly distinguish trend from periodicities and points out the prerequisite of the concerned temporal scale only by giving which the trend has its specific meaning. Correspondingly, the discrete wavelet‐based method for trend identification was improved. Differing from those methods used presently, the improved method is to identify trend by comparing the energy difference between hydrologic data and noise, and it can simultaneously separate periodicities and noise. Furthermore, the improved method can quantitatively estimate the statistical significance of the identified trend by using proper confidence interval. Analyses of both synthetic and observed series indicated the identical power of the improved method as the Mann–Kendall test in assessing the statistical significance of the trend in hydrologic data, and by using the former, the identified trend can adaptively reflect the nonlinear and nonstationary variability of hydrologic data. Besides, the results also showed the influences of three key factors (wavelet choice, decomposition level choice and noise content) on discrete wavelet‐based trend identification; hence, they should be carefully considered in practice. Copyright © 2012 John Wiley & Sons, Ltd.     

黑钨矿类质同象系列的红外光谱研究

本文是对黑钨矿类质同象系列研究的一个组成部分。测试结果表明在中红外区及远红外区的某些吸收谱带,其频率和强度的变化与黑钨矿中两端员组份FeWO_4和MnWO_4的相对含量有良好的线性相关关系。文中给出了频率变化的相关方程和相关图,并讨论了频率位移和强度变化的内部机制。     

The application of uranium series disequilibrium concepts to sediment yield determination

The determination of uranium series disequilibria in fluvial environments is proposed as a method of calculating catchment mass balances. The technique is based on two main principles. Firstly, ²³⁴U is more mobile than ²³⁸U, especially during the early stages of weathering. Secondly, uranium is far more mobile than either thorium or protactinium. Consequently, teaching during weathering results in the loss of the uranium found in the fresh rock, leaving the two immobile daughters behind. The ratio of uranium carried by sediment to that dissolved, U_S/U_W can, therefore, be determined from river water and sediment isotopic activity ratios. Fluxes of uranium can then be calculated from average concentrations in the water and the associated sediment, from which a sediment yield can be inferred. The Witham catchment in Lincolnshire has been used to test the proposed method. A U_S/U_W ratio of between 5 and 7 is determined and a sediment yield of 2.51 ± 2.12 tonnes yr^?1 km^?2 is proposed. Although some problems concerning environmental chemistry have arisen, the validity of the approach is confirmed by the close correspondence between the results obtained and those inferred by earlier workers using more conventional methods.     

中国主要含镍岩体特征及其成因

中国目前已发现7条岩带中18个岩体赋存有工业铜镍矿床。这些含镍岩体的岩石组合有三大类,其中以超基性岩中矿床居多,苏长岩与科马提岩中较少。中国含镍岩浆系列属于科马提岩系列而非拉斑玄武岩系列,含矿岩浆来自上地幔的部分熔融,源区具有U、Th值高而Cr低的特点,深大断裂发育的大陆边缘是镍矿床发育最理想的场所。     

自然金—银类质同象系列矿物晶胞参数变化规律及其表述方程

本文提出了自然金-银类质同象系列矿物的晶胞参数与金、银原子数百分比成二次函数关系,推导出了表示二者之间函数关系的方程式。利用该方程式,可以用金原子数百分比计算出晶胞参数,反之亦然。并且从金、银二者的电负性出发,对a值的变化作了解释。     

胶东金矿成矿系列硫同位素研究

胶东金矿的早晚两期成矿系列中，岩浆成因或在岩浆期即有天然水和表生矿质加入的矿床，δ＾３４Ｓ值均有自早而晚依次降低的规律。为重熔岩浆分异成矿理论和成矿系列的建立提供了重要证据。焦家式和某些晚期矿床，在形成矿液后有表生硫加入，扰乱了这一规律性。胶东群中的硫同位素没有达到均匀化，副变质岩偏重，而斜长角闪岩偏轻，接近陨石硫值，是近似原始岩浆的产物。