Two contrasted P–T–time paths of coronitic metanorites of the French Massif Central: are reaction textures reliable guides to metamorphic histories?

Metanorites from two eclogitized metagabbros of the Hercynian French Massif Central preserve coronitic textures of hornblende, garnet, quartz and/or kyanite produced at the expense of the primary magmatic assemblage orthopyroxene and plagioclase. Using a petrogenetic grid in the CFMASH system, two possible P–T evolutions for the origin of the coronas are evaluated. The sequence of reactions involving the formation of Hbl (–Ky) ± Grt and Qtz coronitic assemblages is consistent with an isobaric cooling at high pressure (c. 1–2 GPa) under hydrated conditions. However, this P–T path, inferred by using only petrographical observations, is inconsistent with the geochronological constraints: emplacement of the gabbro at 490 Ma and high‐pressure metamorphism at 410 Ma. In order to reconcile petrographical observations with geochronological constraints, we propose a discontinuous two‐stage evolution involving a change in water activity with time. (1) Emplacement and cooling of the norite at low pressure under anhydrous conditions, at 490 Ma. (2) During the Hercynian orogeny, the norite experienced an increase in pressure and temperature under fluid‐present conditions. Adding water to the system implies a dramatic change in the petrogenetic grid topology, restricting the orthopyroxene–plagioclase assemblage only to high temperatures. Therefore, the breakdown of the unstable magmatic assemblage, through apparent retrograde reactions, occurred along the prograde P–T path which never crossed the equilibrium boundaries of these reactions.     

Laser Ablation ICP-MS Developments and Trends for 2003

This annual review of laser-ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS) covers the year 2003. Significant advances were made in understanding laser-sample interactions. In particular, research defined the distribution of particle sizes produced by the interplay of laser wavelength, laser pulse width and the gas environment of ablation. A link between particle sizes and elemental and isotopic fractionation at both the ablation site and in the ICP was established. Experimental 15 7 nm and femtosecond laser systems were tested with promising results. The number of applications of LA-ICP-MS in geology and environmental Earth science continued to grow with particular interest in element concentration and isotope ratio profiling of materials, linking composition to time scales. In situ isotopic ratio measurements were increasingly made using multicollector magnetic sector ICP-MS instruments. Other applications of wide interest included bulk sampling of rocks and ores prepared as lithium borate glasses; low level analysis of platinum-group elements, rhenium and gold in sulfides, metal and silicates; in situ uranium-lead zircon geochronology; and melt and fluid inclusion analysis.     

Investigation into the effect of fault properties on wave transmission

The estimation of wave transmission across the fractured rock masses is of great importance for rock engineers to assess the stability of rock slopes in open pit mines. Presence of fault, as a major discontinuity, in the jointed rock mass can significantly impact on the peak particle velocity and transmission of blast waves, particularly where a fault contains a thick infilling with weak mechanical properties. This paper aims to study the effect of fault properties on transmission of blasting waves using the distinct element method. First, a validation study was carried out on the wave transmission across a single joint and different rock mediums through undertaking a comparative study against analytical models. Then, the transmission of blast wave across a fault with thick infilling in the Golgohar iron mine, Iran, was numerically studied, and the results were compared with the field measurements. The blast wave was numerically simulated using a hybrid finite element and finite difference code which then the outcome was used as the input for the distinct element method analysis. The measured uplift of hanging wall, as a result of wave transmission across the fault, in the numerical model agrees well with the recorded field measurement. Finally, the validated numerical model was used to study the effect of fault properties on wave transmission. It was found that the fault inclination angle is the most effective parameter on the peak particle velocity and uplift. Copyright © 2017 John Wiley & Sons, Ltd.     

Assessment of flow paths and confluences for saltwater intrusion in a deltaic river network

Saltwater intrusion is a serious issue in estuarine deltas all over the world due to rapid urban sprawl and water shortage. Therefore, detecting the major flow paths or locations at risk of saltwater intrusion in estuarine ecosystems is important for mitigating saltwater intrusion. In this paper, we introduce a centrality index, the betweenness centrality (BC), to address this problem. Using the BC as the weighted attribute of the river network, we identify the critical confluences for saltwater intrusion and detect the preferential flow paths for saltwater intrusion through the least‐cost‐path algorithm from a graph theory approach. Moreover, we analyse the responses of the BC values of confluences calculated in the river network to salinity. Our results show that the major flow paths and critical confluences for saltwater intrusion in a deltaic river network can be represented by the least cost paths and the BC values of confluences, respectively. In addition, a significant positive correlation between the BC values of confluences and salinity is determined in the Pearl River Delta. Changes in the salinity can produce significant variation in the BC values of confluences. Therefore, freshwater can be diverted into these major flow paths and critical confluences to improve river network management under saltwater intrusion. Copyright © 2015 John Wiley & Sons, Ltd.     

A smoothed particle hydrodynamics modelling of soil–water mixing and resulting changes in average strength

Soil–water interaction is a pivotal process in many underwater geohazards such as underwater landslides where soil sediments gradually evolve into turbidity currents after interactions with ambient water. Due to the large deformations, multiphase interactions and phase changes this involves, investigations from numerical modelling of the transition process have been limited so far. This study explores a simple numerical replication of such soil–water mixing with respect to changes in average strength using smoothed particle hydrodynamics (SPH). A uniform viscoplastic model is used for both the solid-like and fluid-like SPH particles. The proposed numerical solution scheme is verified by single-phase dam break tests and multiphase simple shear tests. SPH combinations of solid-like and fluid-like particles can replicate the clay–water mixture as long as the liquidity index of the solid-like particles is larger than unity. The proposed numerical scheme is shown to capture key features of an underwater landslide such as hydroplaning, water entrainment and wave generation and thus shows promise as a tool to simulate the whole process of subaquatic geohazards involving solid–fluid transition during mass transport.     

From soil aggregates to riverine flocs: a laboratory experiment assessing the respective effects of soil type and flow shear stress on particles characteristics

Particles eroded from hillslopes and exported to rivers are recognized to be composite particles of high internal complexity. Their architecture and composition are known to influence their transport behaviour within the water column relative to discrete particles. To‐date, hillslope erosion studies consider aggregates to be stable once they are detached from the soil matrix. However, lowland rivers and estuaries studies often suggest that particle structure and dynamics are controlled by flocculation within the water column. In order to improve the understanding of particle dynamics along the continuum from hillslopes to the lowland river environment, soil particle behaviour was tested under controlled laboratory conditions. Seven flume erosion and deposition experiments, designed to simulate a natural erosive event, and five shear cell experiments were performed using three contrasting materials: two of them were poorly developed and as such can not be considered as soils, whilst the third one was a calcareous brown soil. These experiments revealed that soil aggregates were prone to disaggregation within the water column and that flocculation may affect their size distribution during transport. Large differences in effective particle size were found between soil types during the rising limb of the bed shear stress sequence. Indeed, at the maximum applied bed shear stress, the aggregated particles median diameter was found to be three times larger for the well‐developed soil than for the two others. Differences were smaller in the falling limb, suggesting that soil aggregates underwent structural changes. However, characterization of particles strength parameters showed that these changes did not fully turn soil aggregates into flocs, but rather into hybrid soil aggregate–floc particles. Copyright © 2013 John Wiley & Sons, Ltd.     

Changes in dissolved organic matter (DOM) amount and composition along nested headwater stream locations during baseflow and stormflow

Amount and composition of dissolved organic matter (DOM) were evaluated for multiple, nested stream locations in a forested watershed to investigate the role of hydrologic flow paths, wetlands and drainage scale. Sampling was performed over a 4‐year period (2008–2011) for five locations with drainage areas of 0.62, 3.5, 4.5, 12 and 79 ha. Hydrologic flow paths were characterized using an end‐member mixing model. DOM composition was determined using a suite of spectrofluorometric indices and a site‐specific parallel factor analysis model. Dissolved organic carbon (DOC), humic‐like DOM and fluorescence index were most sensitive to changes with drainage scale, whereas dissolved organic nitrogen, specific UV absorbance, Sr and protein‐like DOM were least sensitive. DOM concentrations and humic‐like DOM constituents were highest during both baseflow and stormflow for a 3.5‐ha catchment with a wetland near the catchment outlet. Whereas storm‐event concentrations of DOC and humic DOM constituents declined, the mass exports of DOC increased with increasing catchment scale. A pronounced dilution in storm‐event DOC concentration was observed at peak stream discharge for the 12‐ha drainage location, which was not as apparent at the 79‐ha scale, suggesting key differences in supply and transport of DOM. Our observations indicate that hydrologic flow paths, especially during storms, and the location and extent of wetlands in the catchment are key determinants of DOM concentration and composition. This study furthers our understanding of changes in DOM with drainage scale and the controls on DOM in headwater, forested catchments. Copyright © 2014 John Wiley & Sons, Ltd.     

Modelling the flow of self‐compacting concrete

A Lagrangian particle‐based method, smooth particle hydrodynamics (SPH), is used in this paper to model the flow of self‐compacting concretes (SCC) with or without short steel fibres. An incompressible SPH method is presented to simulate the flow of such non‐Newtonian fluids whose behaviour is described by a Bingham‐type model, in which the kink in the shear stress vs shear strain rate diagram is first appropriately smoothed out. The viscosity of the SCC is predicted from the measured viscosity of the paste using micromechanical models in which the second phase aggregates are treated as rigid spheres and the short steel fibres as slender rigid bodies. The basic equations solved in the SPH are the incompressible mass conservation and Navier–Stokes equations. The solution procedure uses prediction–correction fractional steps with the temporal velocity field integrated forward in time without enforcing incompressibility in the prediction step. The resulting temporal velocity field is then implicitly projected on to a divergence‐free space to satisfy incompressibility through a pressure Poisson equation derived from an approximate pressure projection. The results of the numerical simulation are benchmarked against actual slump tests carried out in the laboratory. The numerical results are in excellent agreement with test results, thus demonstrating the capability of SPH and a proper rheological model to predict SCC flow and mould‐filling behaviour. Copyright © 2010 John Wiley & Sons, Ltd.     

阿根廷米纳毕戈塔地区水系沉积物采样粒度试验研究

中国地质调查局与阿根廷地质矿产调查局合作在阿根廷西北部米纳毕戈塔地区进行1︰25万水系沉积物测量,该区属于干旱-半干旱高寒山区,为突出找矿效果,消除或减少风积物干扰,需要确定适合于该区的水系沉积物采样粒度。为此,在该区选择一个有已知矿床的1︰5万图幅进行采样粒度试验,分别选择10~60目、-60目、60~80目、-80目4个粒度级进行粒度试验;根据我国区域地球化学勘查规范,每个粒度分析39种元素。结果表明,大部分元素在4种粒度水系沉积物中的分布形态基本一致,都能够较好地反映出区内已知矿床,说明采用的采样方法可以有效地避免风成砂干扰;金、银、铜、锡等成矿元素在4种粒度中的分布略有差异,10~60目的金、铜和锡异常对已知矿体的反应更清晰准确。因此,本区水系沉积物地球化学测量的最佳采样粒度是10~60目。根据本次试验结果,中-阿地调局在本区联合开展1︰25万水系沉积物地球化学测量时采用了10~60目水系沉积物作为采样介质,取得了很好的效果。这是本区第一次进行水系沉积粒度试验,对本区将来的地球化学调查和研究具有指导意义。     

横向振动格栅紊流紊动特性试验

建立了一套大尺度格栅紊流试验系统,格栅进行有别于传统垂向模式的横向振动,采用粒子图像测速技术(Particle Image Velocimetry,PIV)测量流速。对瞬时流速的检验表明,该系统产生的紊流场具有较强的随机性和统计规律性。均方根流速在格栅片附近变化较大,在两片格栅中间处趋于稳定,纵向均方根流速明显大于垂向均方根流速,二者比值在1.5~2.0之间,接近天然明渠紊流。雷诺应力在距格栅越近处波动越大,随着距格栅距离的增加而减小,至两片格栅中间处雷诺应力基本为0。时间和长度积分尺度在格栅片处最小,随着距格栅距离的增加而线性增加,至两片格栅中间处达到最大值。流速能谱呈现Kolmogorov理论的-5/3次方规律。本系统生成的紊流场的统计规律与传统的垂向振动格栅紊流较为一致,但纵向和垂向的紊动强度更接近实际,为后续紊流中泥沙和污染物等运动机理的研究奠定了基础。