A weighted-averaging regression and calibration model for inferring lakewater salinity from fossil diatom assemblages in saline lakes of the Vestfold Hills: a new tool for interpreting Holocene lake histories in Antarctica

The relationship between surface sediment diatom assemblages and measured limnological variables in thirty-three coastal Antarctic lakes from the Vestfold Hills was examined by constructing a diatom-water chemistry dataset. Previous analysis of this dataset by canonical correspondence analysis revealed that salinity accounted for a significant amount of the variation in the distribution of the diatom assemblages. Weighted-averaging regression and calibration of this diatom-salinity relationship was used to establish a transfer function for the reconstruction of past lakewater salinity from fossil diatom assemblages. Weighted-averaging regression and calibration with classical deshrinking provided the best model for salinity reconstructions and this was applied to the fossil diatom assemblages from one of the saline lakes in the Vestfold Hills in order to assess its potential for palaeosalinity and palaeoclimate reconstruction.     

A late Holocene record of land-use history,soil erosion,lake trophy and lake-level fluctuations at Bjäresjösjön (south Sweden)

Land-use history, soil erosion, lake trophy and lake-level fluctuations during the last 3000 years were reconstructed through a multidisciplinary palaeolimnological study (pollen, plant macrofossils, diatoms, physical and chemical analysis, magnetic measurements and radiometric methods) of a small eutrophic lake in southern Sweden (Bjäresjösjön, Scania). There are striking responses in diatom, chemical, sediment yield and magnetic records to land-use changes documented by pollen analysis or historical sources, and to lake-level changes identified from sedimentary changes. Our multidisciplinary approach assists interpretation of the processes controlling long-term changes and separation of the effects of different factors (land-use changes, lake-level fluctuations) on individual biostratigraphical records. Climate has controlled processes in the lake indirectly, through lake-level fluctuations, from the Late Bronze Age to the Viking Age (700 BC-AD 800). Since the Viking Age, land-use controlled most of the changes observed in the lake's development and soil erosion processes. Major changes in lake development occurred during the last 200 years, due to a drastic increase in soil erosion and water eutrophication during a period of agricultural modernization.     

Effect of low count sums on quantitative environmental reconstructions: an example using subfossil chironomids

The concentrations of chironomid remains in lake sediments are very variable and, therefore, chironomid stratigraphies often include samples with a low number of counts. Thus, the effect of low count sums on reconstructed temperatures is an important issue when applying chironomidtemperature inference models. Using an existing data set, we simulated low count sums by randomly picking subsets of head capsules from surfacesediment samples with a high number of specimens. Subsequently, a chironomidtemperature inference model was used to assess how the inferred temperatures are affected by low counts. The simulations indicate that the variability of inferred temperatures increases progressively with decreasing count sums. At counts below 50 specimens, a further reduction in count sum can cause a disproportionate increase in the variation of inferred temperatures, whereas at higher count sums the inferences are more stable. Furthermore, low count samples may consistently infer too low or too high temperatures and, therefore, produce a systematic error in a reconstruction. Smoothing reconstructed temperatures downcore is proposed as a possible way to compensate for the high variability due to low count sums. By combining adjacent samples in a stratigraphy, to produce samples of a more reliable size, it is possible to assess if low counts cause a systematic error in inferred temperatures.     

On the use of instar information in the analysis of subfossil chironomid data

Head capsules of chironomids of the genera Chironomus, Glyptotendipes and Microtendipes in two cores from Lough Neagh, Northern Ireland, were identified to instar. The proportions of 3rd and 4th instars did not stay constant throughout the lengths of the cores and it is possible there was differential preservation of the instars. Plotting diagrams using only one instar could give misleading information about the occurrence of a genus, while plotting total number of head capsules may result in individuals being counted twice. Counting the most numerous taxon at each level in the sediment avoids the latter problem while retaining maximum information about the fauna. Non-metric Multi-Dimensional Scaling ordination diagrams calculated using the different methods illustrate the similarity of plot obtained.     

Mass Spectrometry and reverse phase HPLC techniques for the identification of degraded fossil pigments in lake sediments and their application in palaeolimnology

Accurate identification of fossil pigments is essential if they are to be used as biomarker compounds in palaeolimnological studies. In recent years High Performance Liquid Chromatography (HPLC) has greatly enhanced the efficiency with which fossil pigments can be characterised and quantified. Using HPLC, undegraded pigments are typically identified through retention times, absorbance spectra and co-chromatography with authentic reference standards. However, lake sediments may also contain degraded pigments for which there are often no standards, and which may be difficult to identify using HPLC alone. In this study, we submitted HPLC fractions of fossil pigments and pigment derivatives collected from a meromictic lake in south west Tasmania, to a combination of Mass Spectrometry (MS) techniques including Electron Impact (EI) and static Liquid Secondary Ion MS (LSIMS) to identify their molecular ion characteristics and organic chemical composition. Mass Spectrometry permitted the detection of specific mass ions which were used to verify the identity of pigments and their derivatives. These included five carotenoids, chlorophyll a and derivatives, three previously described bacteriochlorophyll c derivatives with molecular weights of 770, 784, and 802, and two undescribed derivatives of bacteriochlorophyll c with molecular weights of 766 and 788. With these improved identifications we speculate on the pathways and modes of pigment degradation in the lake and asses the value of the degraded pigments as biomarkers. The use of MS permitted the identification of a greater number of signature pigments of algal and bacterial communities thus increasing the palaeolimnological value of the sediments. These methods are best applied in fossil pigment studies where there are a large number of unknown pigments and pigment degradation products, and where there are no authentic standards for co-chromatography. Practical suggestions for pigment MS are included in the discussion.     

The CASPIA project: diatoms,salt lakes,and environmental change

The Climate and Salinity (CASPIA) Project is concerned with diatoms as environmental indicators in inland waters and their use in reconstructing salinity and major ion composition from fossil diatom assemblages in lake sediments. By comparing saline lake diatom floras from around the world the project aims to establish a common, harmonised approach to sample collection, diatom identification and nomenclature, and to develop techniques for numerical analysis and data storage.This is the first in a series of papers published in this issue on the paleolimnology of arid regions. These papers were presented at the Sixth International Palaeolimnology Symposium held 19–21 April, 1993 at the Australian National University, Canberra, Australia. Dr A. R. Chivas served as guest editor for these papers.Palliser Triangle Global Change Project Contribution Number 19.     

近1200 a来黄河下游梁山泊沉积记录的环境变迁

利用梁山泊670 cm柱状岩芯沉积物,基于精确的AMS-~(14)C年代测定,通过高分辨率的粒度、磁化率、总有机碳、C/N比值等环境代用指标的综合分析,并结合历史文献记载,初步揭示了1200 a来黄河下游地区平原湖泊沉积特征及环境演化历史.结果表明,梁山泊环境演化大致分为5个阶段:790-940 AD期间,为低湖面的沼泽沉积环境,气候冷干;940-1215 AD期间,屡次受到黄河决溢洪水影响,湖盆扩张,湖泊水位上升,为梁山泊极盛期,气候暖湿;1215-1310 AD期间,黄河夺淮入黄海,湖区淤积严重,湖泊萎缩减小;1310-1470 AD期间,再次受到黄河决溢洪水影响,水位上升,面积扩张,但逊于极盛期;1470 AD至现代,黄河河道进一步南移,远离梁山泊,湖盆淤积抬高,梁山泊最终消失,直到1855AD,黄河第6次大改道北移,湖泊再次受到黄河洪水影响,由于前期受到泥沙淤积抬高,该地区仅作为黄河泥沙承载区.在气候变化大背景下,黄河改道决溢是梁山泊演化的主因.     

Holocene environmental change in the West African Sahel: sedimentological and mineral‐magnetic analyses of lake sediments from Jikariya Lake,northeastern Nigeria

Previous studies have demonstrated long‐term changes in effective moisture in sub‐Saharan Africa. Here, we reconstruct Holocene environments using a ～7 m lake‐sediment sequence recovered from the northeastern Nigerian Sahel and attempt to distinguish basin‐specific changes from regional climatic variations. The sequence was analysed for sedimentological properties, mineral magnetism and pollen, and dated by ¹³⁷Cs, ²¹⁰Pb excess and ¹⁴C. Extremely arid conditions of the terminal Pleistocene ended ca. 11 500 cal. BP (calendar years) when climate ameliorated and a lake developed until the occurrence of an arid event leading to lake desiccation at ～11 200 cal. BP. Following this, climate ameliorated and a water body re‐emerged. Very wet conditions predominated 11 200–5600 cal. BP, followed by drought between 5600 and 5500 cal. BP and a return to moderate humidity from 5500 to 4000 cal. BP. After 4000 cal. BP, a marked deterioration occurred, culminating in lake desiccation at ca. 800 cal. BP. After this time the climate remained generally dry and the re‐emerging lake was shallow. Comparison of these results with other well‐dated sequences in the region demonstrates the importance of basin‐specific influences on the palaeolimnological records in addition to regional climatic controls. Disentangling these different controls, as well as the reconstruction of Holocene climate, therefore requires a multiple‐basin approach. Copyright © 2008 John Wiley & Sons, Ltd.