三氟乙酰对癸基苯为中性载体的碳酸根离子选择电极的制备和应用

实验比较了多种膜组分的性能 ,制得了有较长使用寿命的三氟乙酰对癸基苯为载体的 PVC膜碳酸根离子电极。适当增大膜中载体的含量 ,采用亲脂性强的增塑剂并加入适量增水性溶剂 ,有利于延长电极的使用寿命和增强抗亲脂性阴离子干扰的能力。已利用此种膜电极 ,以控制 p H标准比较法测定了模拟血清和质控血清中的碳酸根 ,并以已知稀释—标准加入法测定了碳酸盐型卤水中的碳酸根     

Scaled chrysophytes and pH inference models: the effects of converting scale counts to cell counts and other species data transformations

Predictive pH models developed using scaled chrysophytes (Synurophyceae, Chrysophyceae) have thus far been based on the relative abundance of scales and not whole cells. This paper examines the effects of transforming scale to cell numbers on the predictive abilities of pH inference models, and the effects of logarithmic and square-root transformations of the species data on the predictive abilities of pH inference models.Very similar pH inference models were developed based on either the relative abundance of scales or cells. Thus, in this data-set, there appears to be no statistical advantage in transforming raw scale counts to cell counts prior to calculating the relative abundances. However, if one wishes to compare paleochrysophyte populations to actual long-term limnological chrysophyte collections, a scale-to-cell transformation would be desirable. Logarithmic and square-root transformations of the species data improve the pH inference models. These transformations increase the effective number of occurrences of chrysophyte taxa when compared to the untransformed scale and cell pH models. The logarithmic and square-root transformations improve the pH inference models because the dominant taxa, which are often pH generalists, are down-weighted in comparison to the more pH specialist, sub-dominant taxa. We suggest researchers use either a logarithmic or square-root transformation on chrysophyte scale data to improve quantitative reconstructions of lakewater pH and possibly other variables.     

Ferromanganese rock varnish in north Norway: A subglacial origin

A thin, dark brown rock varnish is described from ice-smoothed bedrock on the forefield of a glacier in North Norway. It occurs only in narrow strips (ca 100 mm or less wide) which run roughly parallel to the ice front and along the top edges of small treads of a series of bedrock steps. The varnish is hard, thin (< 10 μm) and consists of an iron/manganese deposit, greatly enriched in these elements compared with the composition of the underlying gabbroic bedrock. It is suggested that the varnish formation is due to localized changes in Eh/pH conditions in subglacial regelation ice and meltwater at the top of the bedrock steps. These changes may be due to CO₂ and/or O₂ degassing from water held at higher pressures under the ice than in cavities downstream where the ice is decoupled from the bedrock. Glacier retreat rates indicate that the varnish has remained exposed subaerially at the surface for about twenty years, and its restricted occurrence suggests that it is not of biological origin but rather is essentially authigenic. Possible subglacial origins for associated iron and silica precipitates are also suggested.     

On the physical essence of the b value for AE of rock tests and natural earthquakes in terms of fracture mechanics

The problem of physical essence of theb value forAE of rock tests and natural earthquakes has been a controversial topic during the past two decades. In the present paper the order and energy of each microfracturing of the microcrack system existing in a rock specimen is discussed from the viewpoint of fracture mechanics, then the whole series ofAE and subsequently the value ofb are determined. The order of microfracturing depends on the parametersKei/Kci whereKei is the effective stress intensity factor of thei-th microcrack andKci is the fracture toughness in the site of thei-th crack. The energy of eachAE can be expressed asηi ∫ loili Gids whereG is the energy release rate of microcarck,loi andli are the original and final crack lengths respectively andηi is the emanating efficiency for thei-th crack. If we assume that the distribution density function of microcrack lengthl isp(l)=Bl−v whereB andγ are constants, then the expressionb=3γ/2 can be deduced. Hence, we have come to the conclusion that the value ofb mirrors essentially the “crack-system-configuration” of the material, which means the distribution of the sizes, shapes and orientations of microcracks over space as well as the distribution of the other relevant physical parameters such as fracture toughness, friction coefficient, etc. Our conclusion is somewhat similar in character to Mogi’s. He concluded thet the heterogeneity of the material plays the most important role in determining the value ofb. The term heterogeneity of course covers the idea of “crack-system-configuration, but we think that our view has a little bit deeper insight to the problem than that of Mogi. This subject is supported by Chinese Joint Seismological Science Foundation.     

The Influence of NaBr/NaCl Ratio on the Br--Catalysed Production of Halogenated Radicals

The activation of Br^- and Cl^- to atomic Br and Cl in sea-spray aerosol was investigated in smog-chamber experiments. In the presence of O₃, hydrocarbons and NaCl aerosol alone no activation was observed. By adding Br^- to the aerosol, the chain reaction: Br + O₃ BrO, BrO + HO₂ HOBr, HOBr HOBr(aq), HOBr(aq) + H⁺ + Br^- Br₂ (6), HOBr(aq) + H⁺ + Cl^- BrCl (7) was verified. The step from reaction (6) to (7) is accompanied by a decrease of the Br^-/Cl^- ratio from 1/600 to less than 1/2000. In the absence of sulphate, the chain is initiated by the reaction of OH(aq) with Br^-. The pH value decreases to less than 2 during the first minutes of the experiment and later on to almost 1 (in the absence of NO_x or SO₂). This is caused by the formation of oxalic acid from alkanes and toluene. In stopped flow experiments, the reduction of Br₂ by oxalic acid was observed to occur through a two-step mechanism: HC₂O₄ ^- + Br₂ Br^- + BrC₂O₄H (k₂₂, k_-22), BrC₂O₄H Br^- + H⁺ + 2 CO₂ (23) with the following rate constants and ratios of rate constants, k ± 2: k₂₂k_-23 / k_-22 = (2.9 ± 0.3) · 10^-4 s^-1, k_-22 / k_-23 = 7000 ± ₃₀₀₀ ¹³⁰⁰⁰ M^-1, k₂₂ = 2 ±_-1 ⁴ M^-1 s^-1, and k_-23 > 0.1 s^-1, k_-22 > 600 M^-1 s^-1. Oxalic acid may be responsible for the inhibition of the chain reaction observed at the end of the experiments.     

中型医院CT室实施QA,QC原则的初探

本文介绍了采用中国推广普及型ＣＴ，根据世界卫生组织提出的ＱＡ、ＱＣ体系的原则，制定中型医院ＣＴ室“ＣＴ室组织行为规范”，“ＣＴ扫描技术规范”；“ＣＴ诊断技术规范”。     

Development of an apparatus to measure groundwater qualities in situ and to sample groundwater using boreholes

 To accurately measure the pH, Eh, EC and temperature of groundwater retrieved from boreholes, a deep groundwater sampling apparatus was developed which provided sensory measurements both in situ and in a flow-through cell at ground level. Under a pressure of 1×10⁶ Pa the in situ accuracy of the apparatus sensor was within the following limits: pH ±0.2, temperature ±0.1°C, Eh ±10 mV, and EC ±2.4%. The measuring and sampling of deep groundwater from a borehole of more than 1000 m in depth was performed continuously for 30 days. Values of pH were the same for the in situ sensor, the flow-through cell sensor and the laboratory measurements of the sampled water. At the beginning of the sampling period, Eh values of the in situ sensor indicated deep groundwater conditions. The apparatus is particularly useful for Eh measurement. Chemical composition and stable isotope ratios indicated that the groundwater sampled from more than 1000 m depth was a connate water with a chemical composition slightly different from seawater of the present time, and the groundwater retrieved from 800 m depth was a meteoric water. Natural radioactive elements are thought to be the origin of the tritium in the groundwater retrieved from the 1000 m depth. Received: 6 August 1996 / Accepted: 22 October 1996     

Invertebrate community response to experimental lime (Ca(OH)2) treatment of an eutrophic pond

Calcium hydroxide (Ca(OH)₂), or hydrated lime, has recently been reintroduced in western Canada as a treatment to reduce macrophytes and algae in eutrophic waters. We examined the effects and recovery of aquatic invertebrates of the Ca(OH)₂ treatment (250 mg L^–1) of one half of a divided eutrophic pond compared to the untreated half. Nine weeks following treatment, total invertebrates on the untreated side were present at 1917 ± 555 individuals m^–2, and on the treated side at 822 ± 186 individuals m^–2. Notably, Chironomidae represented 13% of invertebrates on the untreated half, but dominated numerically with 72% on the treated half of the pond. The remaining five most abundant taxa in the untreated side were 88%–99% less abundant in the treated half of the pond. Diversity and evenness were twice as high for the untreated half as for the treated half of the pond. Because macrophytes were also extirpated with the Ca(OH)₂ treatment, macrophyteassociated taxa were absent or at low numbers in the treated half. The death of organisms on the treated side of the pond may have been caused (directly or indirectly) by the pH shock associated with Ca(OH)₂ treatments. Slow recolonization by most invertebrates during the year of treatment was probably due to the lack of heterogeneous macrophyte habitat. Follow-up sampling 3 years later indicated that the pond completely regained the abundance and biological diversity of flora and fauna.     

Large gaps in voluntary sustainability commitments covering the global cocoa trade

The production and trade of agricultural commodities, such as cocoa, have important impacts on farmer livelihoods and the environment, prompting a growing number of companies to adopt public commitments to address sustainability issues in their value chains. Though trading companies, who handle the procurement and export of these commodities, are key actors in corporate sustainability efforts, cross-country data on their identity, market share, and adoption of sustainability commitments is lacking. Here, we address this gap for the cocoa sector by compiling detailed shipping data from eight countries responsible for 80% of global cocoa exports, developing a typology of trader types, and assessing their adoption of sustainability commitments. We find that cocoa trading is a highly concentrated market: seven transnational companies handled 62% of the global cocoa trade, with even larger shares in individual cocoa producing countries. The remaining 38% of exports were handled by domestic trading companies and farmer cooperatives. Overall, the adoption of public sustainability commitments is low. We estimated that just over one quarter (26%) of cocoa is traded under some form of sustainability commitment, with gaps arising from their exclusion of indirect sourcing, low adoption rates by domestic traders, and commitment blind spots, notably on forest degradation and farmer incomes. Low rates of traceability and transparency pose a further barrier to the broadscale implementation and monitoring of these commitments: one-quarter of traders report being able to trace at least some of their cocoa back to farmer cooperatives and only half of them openly disclose the identity of their suppliers. We discuss the opportunities and limitations of voluntary sustainability commitments in a highly concentrated market and argue that, to realize visions of sustainable trade, the gaps in commitment coverage must be closed by extending current efforts to smaller traders and indirect suppliers. However, companies must support, coordinate and align with government efforts so that voluntary initiatives are ultimately rendered more transparent and accountable.