使用PHSJ-3F实验室pH计测溶液的pH值

中国气象局在全国范围内布设酸雨观测站网,台站数量达89个(含大气本底站),茫崖站是担任酸雨观测业务的站网之一。为了各站点酸雨观测业务更加规范、观测质量日益提高,本文就如何减小误差、准确测量酸雨样品pH值,结合自己实际工作中测量流程和经验,总结了几个步骤和方法,供大家参考。     

Paleolimnological reconstructions of Rouyn-Noranda lakes within the zone of influence of the Horne Smelter,Québec,Canada

Diatoms were identified and enumerated from a surface sediment calibration set of 50 lakes in northwestern Québec. The relationship between species composition and environmental variables was examined using canonical correspondence analysis (CCA). Forward selection and Monte Carlo permutation tests in CCA indicated that diatom species distributions in the data set are most strongly correlated to lakewater pH. A strong (r ² _boot = 0.83) weighted averaging calibration model, that includes bootstrapped error estimates, was developed for inferring past lakewater pH. Using this model, temporal changes in pH were reconstructed for two kettle lakes, Lac de la Pépinière and Lac Perron. Based on limnological data, both the study lakes were expected to have recently acidified due to increased acidic precipitation and increases in anthropogenic metal loading. However, our long-term pH inference data indicate that these lakes were naturally acidic during pre-industrial times. Nonetheless, the rate of acidification, particularly in Lac de la Pépinière, has accelerated in the last ∼75 years. These long-term pH records developed for the dilute lakes in northwestern Québec suggest that the region has received increased atmospheric pollutants from the nearby Horne smelter in Rouyn-Noranda. The pH inference profiles are markedly different from many other paleolimnological studies in acid-sensitive regions of Canada that have become acidic primarily as a result of industrial activities. Electronic supplementary material The online version of this article (doi: ) contains supplementary material, which is available to authorized users.     

Partitioning of heavy metals on soil samples from column tests

In this study, column tests were used to determine the retention capability of three types of estuarine alluvia collected adjacent to landfill sites in South Wales. Selective sequential extraction (SSE) was used to study the retention mechanisms of heavy metals in the soil columns obtained from leaching experiments. Acid digestion was later used to check the validity of the SSE results. Breakthrough curves show good retention of heavy metal ions (Pb, Cu, and Zn) by all soils, where almost 99% of heavy metals were retained with the C_e/C_o values in the order of 10⁻³. The retention strength of these soils was observed to be constant up to five pore volumes (PV). This corresponds with the pH of the effluents and pore water of soil slices, which also show good buffering capacity against very acidic leachate up to 5PV. The heavy metal extraction profiles from SSE show very similar trends with the retention profiles from the leaching experiments, where heavy metals were retained mainly at the top part where the leachate entered the column. SSE indicates qualitatively that heavy metals precipitated with carbonates and amorphous materials (oxides/hydroxides) are higher than heavy metal retention via exchangeable mechanisms. The mass balance calculation gives range of deviation of 1–16% of the total soil extraction. The distribution of the heavy metals with various soil constituents are ranked in the following order: Carbonates>Amorphous oxides hydroxides>Organic matter>Exchangeable phases.     

一株海洋微藻的分离鉴定及其产油条件优化

自青岛近岸海水中分离到一株硅藻,经形态学和分子生物学鉴定,表明该藻与小头菱形藻(Nitzschia microcephala)最为相近,18SrDNA相似性99%以上。研究以f/2培养基为基础,对该藻的生长和油脂积累条件进行探析,表明其在pH=6~8时具有较高的生长速率,最大可达到0.01d-1,油脂含量随pH的升高而降低;添加SiO2-3可以抑制菱形藻的生长和油脂积累;高浓度的Fe3+能促进菱形藻的生长;在Zn2+浓度为1.74μmol/L的条件下,菱形藻能够较好地生长并且进行油脂的积累;其中pH、SiO2-3和Fe3+是影响该藻生长和油脂积累的主要因子。正交试验研究表明,该藻在f/2培养液中生长和油脂积累的最优条件为初始pH=9,SiO2-3和Fe3+添加浓度分别为0.07和100μmol/L。在该最优条件下,该藻的生物量和油脂积累可分别达到94.7mg/L和19.6%。     

鮸状黄姑鱼胚胎和仔鱼发育的实验生态

本实验研究了温度、盐度、 ｐＨ对鮸状黄姑鱼胚胎发育和前期仔鱼存活的影响。结果表明,鮸状黄姑鱼受精卵孵化的温度范围为１５～３０℃,最适孵化温度为２５～３０℃;孵化盐度范围为１５～４５,最适孵化公度范围为１５～２５;ｐＨ值在５．００～８．９９范围内,受精卵孵化率没有显著的差异。鮸状黄姑鱼前期仔鱼存活的适合温度为１５～３０℃,最适温度为２５℃;适合盐度为１５～３５;适合ｐＨ值为５．９９～１０．０１。     

Transport and retention of Escherichia coli in a mixture of quartz,Al‐coated and Fe‐coated sands

Transport and retention of Escherichia coli through the mixture of quartz, Al‐coated and Fe‐coated sands was examined using column experiments to investigate the effect of geochemical heterogeneity on bacteria transport. The first set of the experiments was performed in quartz, Al‐coated and Fe‐coated sand mixtures (coated sand: 0, 5, 10, 25, 50, 100%) to examine the influence of positively‐charged sand grains on bacteria transport. The second experiments were carried out to observe the impact of pH (range 6·74–8·21) on bacteria transport in the mixture of quartz 50% and Fe‐coated sand 50%. The third experiments were conducted to analyse the effect of ionic strength (0, 50, 100, 200 mM) on bacteria transport in the mixture of quartz 50% and Al‐coated sand 50%. The first experiments show that bacterial mass recoveries were in the range of 3·6–43·4%, decreasing nonlinearly as the content of Al‐ and Fe‐coated sands increased. In the second experiments, the bacterial mass recoveries were in the range of 35·5–79·2%, increasing linearly as the solution pH increased. In the third experiments, the mass recovery was 3·4% at 0 mM. As the ionic strength increased to 50mM, the mass recovery decreased to 0%. When the ionic strength increased further to 100 and 200 mM, no bacterial mass was recovered as in the case of 50 mM. It indicates that in the mixed medium of quartz 50% and Al‐coated sand 50% both positive (increment of bacterial adhesion) and negative (decrement) effects of ionic strength may be counterbalanced, minimizing the impact of ionic strength on the bacterial adhesion. This study helps to understand the role of metal oxides and solution chemistry in the transport of bacteria in geochemically heterogeneous media Copyright © 2008 John Wiley & Sons, Ltd.     

Relationship between land cover and monsoon interannual variations in east Asia

Asian monsoon have multiple forms of variations such as seasonal variation, intra-seasonal variation, interannual variation, etc. The interannual variations have not only yearly variations but also variations among several years. In general, the yearly variations are described with winter temperature and summer precipitation, and the variations among several years are reflected by circulation of ENSO events. In this study, at first, we analyze the relationship between land cover and interannual monsoon variations represented by precipitation changes using Singular Value Decomposition method based on the time series precipitation data and 8km NOAA AVHRR NDVI data covering 1982 to 1993 in east Asia. Furthermore, after confirmation and reclassification of ENSO events which are recognized as the strong signal of several year monsoon variation, using the same time series NDVI data during 1982 to 1993 in east Asia, we make a Principle Component Analysis and analyzed the correlation of the 7th component eigenvectors and Southern Oscillation Index (SOI) that indicates the characteristic of ENSO events, and summed up the temporal-spatial distribution features of east Asian land cover’s inter-annual variations that are being driven by changes of ENSO events.     

地貌发育阶段的定量研究

文章提出用临界侵蚀积分值作为划分流域发育阶段的定量指标,是对经典理论的发展,主要表现在:1)将地貌发育阶段纳入开放系统的概念之中;2)避免高程积分法在划分发育阶段上的不确定性;3)建立地貌发育阶段与流域物质迁移之间的定量关系;4)区分自然侵蚀和加速侵蚀。用文中的临界侵蚀方程对黄土高原丘陵沟壑区分析计算,得到临界侵蚀积分值为0.30和0.70,即当侵蚀积分值小于0.30寸,流域处于侵蚀早期;当侵蚀积分值大于0.30,小于0.70时,流域处于侵蚀中期;当侵蚀积分值大于0.70时,流域处于侵蚀晚期。对于纯自然侵蚀过程,与临界侵蚀积分值相对应的年代及侵蚀模数为7万年前,7008t/km~2·a和距今7.2万年以后,7008t/km~2·a。目前黄土高原丘陵沟壑区加速侵蚀所占比例为30％。     

基于模糊聚类的新疆典型高寒草原土壤pH值空间制图

准确、高效地掌握草原土壤属性的空间分布能够为草地资源境管理提供基础信息和参考依据。相比于传统土壤调查方法,基于模糊逻辑的土壤—环境推理能够提高野外采样效率和预测制图精度,被广泛应用于数字土壤制图。但由于土壤自身的空间变异性及其与环境条件间的非线性,现有推理模型的稳定性较低,尚未在高寒草原区进行应用。选择新疆巴音布鲁克典型亚高山草原地区约4 km^2区域为研究区,以高程、坡度、坡向、沿剖面曲率、沿等高线曲率、地形湿度指数6个地形因子为土壤环境因子,采用模糊C均值聚类(Fuzzy C-means Clustering,FCM)方法对环境因子聚类,得到9个环境因子组合,并在隶属度值高的环境因子组合中心共设置18个典型点。运用土壤—环境推理方法模拟研究区表层土壤pH值空间分布,其变化范围在7.170~8.186之间。选取35个独立样本进行精度检验(均匀采样点16个,横截面采样点9个,垂直带采样点10个),模拟结果与实测值基本吻合,且基于模糊聚类和土壤—环境推理方法的模拟精度高于普通克里格法和反距离权重法。通过基于模糊逻辑和土壤—环境推理的数字土壤制图方法在小尺度区域的运用验证,结果表明基于典型点的采样方案能够快速、有效地对区域土壤属性进行空间模拟,该方法对于类似小尺度的研究区同样有效。     

夏季烟台—威海北部近海溶解氧浓度垂向分布的最小值

基于2020年夏季的大面航次观测数据,分析了烟台—威海北部海洋牧场及邻近海域海水溶解氧浓度垂向分布最小值（氧最小值层）的空间分布特征,并探讨了影响因素。从6月至8月,海水溶解氧浓度不断减小,垂向结构亦存在显著变化。海水溶解氧浓度垂向分布的最小值主要集中于7月的近岸海域,最小值大致从外海向近岸方向减小,其距离海底高度及与底层溶解氧浓度之差的绝对值均于双岛湾邻近海域为最大。海水溶解氧浓度垂向分布的最小值位于最强密度层结以下。但是海水溶解氧浓度垂向分布最小值的强度向北减小,而密度层结向北增大,两者的空间分布基本相反,说明密度层结抑制垂向湍流扩散可极大减少深层海水溶解氧的来源,是海水溶解氧浓度垂向分布最小值形成的必要条件,但不是主导因素。在海水溶解氧浓度垂向分布的最小值层,表观耗氧量存在垂向分布的最大值,大部分站点的pH存在垂向分布的最小值,说明局地增强、持续的生物地球化学耗氧是控制海水溶解氧浓度垂向分布最小值形成和空间分布的一个重要过程。研究结果表明氧最小值层是夏季烟台—威海北部近岸海水溶解氧垂向结构的典型特征之一。