中更新世气候转型时期南海生态环境的南北差异

中更新世气候转型在南海浮游有孔虫、氧同位素和其它生物记录上主要反映在900 ka BP前后发生高频率变化,特别是指示表层水骤然降温。北部冬季表层水温从24~25℃降至17~28℃,而南部也从26~27℃降至23~24℃。总的降温趋势与开放西太平洋一致,直接反映了西太平洋暖池在900 ka BP之后MIS22期间有明显的减弱。表层水大幅度降温还发生在后继的MIS 20、18、16几大冰期,说明主要冰期旋回周期由41 ka转变为100 ka经历了长达400 ka的过渡时期,并且冬季风增强也在过渡时期的后半段最明显。南海南北生物组合和δ18O值的差异,突出了中更新世气候转型期边缘海区南北气候梯度反差和冬季风在冰期增强的讯号。结论是：生态环境系统反应总体表现与冰期旋回一致的同时,还包含了独特的地区性系统演变特征。但是,南海—西太平洋地区在0.9 Ma BP前后表层海水盐度因东亚冬季风和海平面下降的定量变化,以及这些变化对气候转型时期海—气耦合过程和生态环境系统的影响,尚缺乏足够的资料和证据。     

Effects of pulsed nutrient inputs on phytoplankton assemblage structure and blooms in an enclosed coastal area

The response of phytoplankton assemblage structure to terrestrial nutrient inputs was examined for the Gulf of Kalloni in the Northern Aegean Sea, a productive semi-enclosed coastal marine ecosystem. The study was focused on a typical annual cycle, and emphasis was placed on the comparative analysis between blooms developing after significant nutrient inputs from the watershed, and naturally occurring blooms. Baseline information was collected on a monthly basis from a network of stations located in the oligotrophic open sea and the interior and more productive part of the embayment. Intensive sampling was also carried out along a gradient in the vicinity of a river which was the most important source of freshwater and nutrient input for the Gulf. Phytoplankton assemblage structure was analyzed from 188 samples using diversity indices (Shannon and Average Taxonomic Distinctness), multivariate plotting methods (NMDS), multivariate statistics (PERMANOVA), and canonical correspondence analysis (CCA). Three characteristic assemblages were recognized: (1) an autumn assemblage developed under nutrient depleted conditions, having low diversity due to the dominance of two small diatoms, (2) a winter bloom of the potentially toxic species Pseudo-nitzschia calliantha occurring immediately after a nutrient peak and characterized by very low diversity, and (3) a naturally occurring early summer bloom of centric diatoms with relatively high diversity. The results of the study support the view that moderate nutrient inputs may have a beneficial effect on the functioning of coastal ecosystems, stimulating the taxonomic diversity through the growth of different taxonomic groups and taxa. On the other hand, a sudden pulse of high nutrient concentrations may greatly affect the natural succession of organisms, have a negative effect on the diversity through the dominance of a single species, and can increase the possibility of a harmful algal bloom development.     

南海 18°N 断面 上的体积和热盐输运

以2005—2008年4年中南海北部开放航次所获得的水文观测资料为基础,结合卫星高度计遥感资料,采用动力计算方法计算南海18°N断面的经向地转流,并与声学多普勒流速剖面仪(Acoustic Doppler Current Profilers,ADCP)走航观测资料进行对比,进而计算出通过南海18°N断面1000m以浅的各站位以及断面上总的经向地转体积、热、盐输运量。结果表明,2005—2008年南海北部开放航次期间18°N断面上的经向地转流呈相间带状分布,各站位经向地转流流速垂向分布和ADCP观测的大体一致。从卫星高度计获得的海面高度场可知,经向地转流流向的空间变化与海洋中尺度涡旋的活动密切相关。2005—2007年航次期间南海18°N断面上1000m以浅总的经向地转体积、热、盐输运均为南向输运,其3年的平均输运量分别为11.8Sv(1Sv=106m3.s 1)、0.38PW、418.8Gg.s 1;其年际间差别较大,经向地转体积、热、盐输运量均为2005年最大,2006年次之,2007年最小。2008年110°—117°E之间1000m以浅总的海水地转体积、热、盐输运量分别为7.3Sv、0.22PW、259.4Gg.s 1。     

Hydrodynamic and isotopic investigations for evaluating the mechanisms and amount of groundwater seepage through a rockslide dam

This study addresses the influence of landslide dams on surface water drainage and groundwater flow. In the study area of Scanno Lake and Sagittario River (Central Italy), a limestone rockslide‐avalanche formed a lake, which has an outlet that is occasionally active, showing infiltration into the rockslide dam. Several springs are present at the lake's base and are partly fed by seepage through the rockslide debris. Piezometric surveys, discharge measurements, pumping tests and chemical analyses are tools used to build a conceptual model of the groundwater flow and to evaluate the flow through the rockslide debris. Seasonal water isotopic signatures validate the assumed model, showing a mixing of infiltration recharge and groundwater seepage throughout the rockslide debris. Various recharge areas have been found for springs, pointing out those directly fed by the rockslide debris aquifer. Hypotheses about seasonal groundwater mixing between the regional carbonate aquifer and the rockslide debris aquifer are supported by isotope results. Seasonal changes in groundwater table level due to recharge and surface losses from seasonal outlet have been correlated with isotopic groundwater composition from the rockslide debris aquifer and the downstream springs; this relationship highlights the role of the rockslide dam body on the hydrodynamics of the studied area. Relationships between surface waters and groundwater in the area have been completely understood on the basis of water isotopic fingerprinting, finally obtaining a complete evaluation of groundwater renewable resources and its regimen. Copyright © 2010 John Wiley & Sons, Ltd.     

Estimation of source water to cedar elm in a central Texas riparian ecosystem

A riparian ecosystem downstream of a small dam in central Texas was instrumented for sap flow, soil moisture content, and stream level from 2001. Stable isotopes in water (D and ¹⁸O) were analysed from rainfall, stream, lake, and cored sapwood cellulose from cedar elm (Ulmus crassifolia). The isotope signature of water source to cedar elm was identified by back calculation starting with the water isotopes in cellulose, and accounting for leaf‐water evaporation and biological fractionation during cellulose synthesis. The estimated mean isotope of the source water to cedar elm was enriched above rainfall in similarity to stream water during 2002. Flow paths that may have contributed to estimated variability from regional base flow and recharge water were identified using the variably saturated HYDRUS‐2D model. Copyright © 2004 John Wiley & Sons, Ltd.     

Application of AMD to the Determination of Cropprotection Agents in Drinking Water. Part III: Solid Phase Extraction and Affecting Factors Anwendung der AMD-Technik zur Bestimmung von Pflanzenbehandlungsmittel-Wirkstoffen im Trinkwasser. Teil III: Festphasenextraktion und ihre Einflußfaktoren

The more sensitive an analysis method the more care must be given to sample preparation. Solid phase extraction (SPE) onto RP 18 phases has established itself as a general purification and enrichment technique for trace components in aqueous samples. Various factors may thereby influence the recovery rate. For example, the ratio amount of sorbent and sample volume should be taken into account to avoid breakthrough of the investigated substance. Extracting phenylurea herbicides from drinking water, the ratio should be 1 g RP 18 sorbent per 1 L water sample. Concerning the flow rate for the fungicides procymidone, vinclozolin, and iprodione, the recovery rate decreases using higher flow rates than 3 or 6 mL/min. In the case of phenylurea herbicides, a flow rate of 10 or 14 mL/min showed best results. Even the coefficient of variation is below ± 5% at these flow rates. Furthermore, the company dependence should be considered because the recovery rate might differ by up to 40% using the nominally identical material. The same applies to the batch dependence of quality from the same company. The concentration of the eluate must also be monitored and carried out with great care to avoid decreasing the recovery rate. Considering these factors of influence, SPE is a very useful tool in sample preparation, particularly if an automated system is used.     

The δ18O in the Guliya shallow ice core during the prevailing summer monsoons and sea-air interactions

The correlations of the δ¹⁸O_max in the shallow ice core from the Guliya ice cap on the Tibetan Plateau with the global sea surface temperatures (SST) and height at the 500 hPa over the Northern Hemisphere were analyzed. The correlated regions on oceans that have a significant influence on the δ¹⁸O_max in the Guliya ice core are all located in ocean currents, or convergent regions of currents. They are the eastern Equatorial Pacific, the Northern Pacific Current, the Hot Pool in the eastern Indian Ocean, the Mozambique Current, the Northern Atlantic Current, the Canary Current and the Atlantic Equatorial Current. The δ¹⁸O_max in the Guliya ice core has negative correlations with the SST located in the lower latitudes, and positive correlations with the SST in the middle latitudes. The correlated areas at the 500 hPa that have a great impact on the δ¹⁸O_max are located in the subtropical highs over the mid-low-latitude oceans and the long-wave trough area over Balkhash Lake, where there are marked negative correlations between the heights in those areas and the δ¹⁸O_max. The influencing mechanism is displayed by the diversity of the vapor origins transported to the Guliya region. The strengths of the European ridge and the ridge over Baikal Lake have notable positive correlations with the δ¹⁸O_max. The two systems indirectly influence the vapor transportation towards the Guliya region by the adjustment of long-wave trough and ridge.     

Authigenic sericite record of a fossil geothermal system: the Offenburg trough,central Black Forest,Germany

A fossil geothermal area is hosted by the Carboniferous, Permian and Bunter sandstones of the Offenburg intramontane trough in the central Black Forest. The hydrothermal alteration is identified on the basis of newly formed sericites, which appear as pseudomorphs after feldspar and filling of pore spaces. According to K–Ar dating of sericite, serititization occurred about 145 Ma ago (Jurassic). On the basis of ¹⁸O analyses of sericite, sericite composition and vitrinite reflectance, the hydrothermal fluids had temperatures of 150–210 °C. Because their electrolyte content was low, these fluids are assumed to have derived from meteoric water. A second pulse of electrolyte-rich hydrothermal fluids resulted in quartz overgrowths. Fluid mobilization seems to be linked to the disintegration of Pangaea and to reactivated fault systems extending from the crystalline basement into the intramontane sediments.     

Variations of <Emphasis Type="Italic">δ</Emphasis><Superscript>18</Superscript>O in precipitation from the Muztagata Glacier,East Pamirs

Expeditions to Muztagata (in the eastern Pamirs) during the summer seasons of 2002 and 2003 collected precipitation samples and measured their oxygen isotopes. The δ ¹⁸O in precipitation displays a wide range, varying from −17.40‰ to +1.33‰ in June-September 2002 and from −22.31‰ to +4.59‰ in May-August 2003. The δ ¹⁸O in precipitation correlates with the initial temperature of precipitation during the observing periods. The positive correlation between δ ¹⁸O and temperature suggests that δ ¹⁸O can be used as an indicator of temperature in this region. The δ ¹⁸O values in fresh-snow samples collected from two snow events at different elevations on the Muztagata Glacier show a strong “altitude effect”, with a ratio of nearly −0.40% per 100 m from 5500 m to 7450 m.