红柳沟北镁铁-超镁铁质岩体矿物学特征及矿石成因分析

红柳沟北镁铁-超镁铁质岩体位于柴达木陆块北部的欧龙布鲁克微陆块东北缘,呈岩墙状,出露面积约0.1km~2,由方辉橄榄岩、橄榄二辉岩、含长单辉橄榄岩、橄榄辉长苏长岩、暗色橄榄辉长岩、苏长岩、辉长岩等组成,各岩相带在空间上呈渐变过渡关系。电子探针分析结果显示,岩体的主要造岩矿物为贵橄榄石、古铜辉石、普通辉石和斜长石,并且各矿物的结晶温度为1 307~1 122℃。岩体钛铁矿化明显,主要金属矿物为钛铁矿、钛磁铁矿和磁铁矿。利用橄榄石Fo最高值反演出原生岩浆MgO含量为8.49%,FeO含量为10.03%,TiO_2含量为1.63%,为普通玄武质岩浆。通过综合研究各矿物形成的温度和氧逸度条件,认为岩浆从橄榄石结晶到普通辉石结晶,其氧逸度是缓慢升高的,并且氧逸度是控制红柳沟北岩体Ti-Fe氧化物结晶的主要因素。     

广西都结氧化锑矿可选性试验研究

都结锑矿的矿石矿物几乎均为黄锑矿 ,分布粒度微细 ,属难选的氧化矿石。经研究发现黄锑矿颗粒含3%的铁并具有弱磁性 ,采用分级强磁选与化学选矿相结合的试验流程 ,获得锑精矿品位 39.2 9% ,总回收率 >95 %的分选效果     

Was the Panzhihua Large Fe-Ti Oxide Deposit,SW China,Formed by Silicate Immiscibility?

The Panzhihua mafic intrusion, which hosts a world-class Fe-Ti-V ore deposit, is in the western Emeishan region, SW China. The formation age(～260 Ma), and Sr and Nd isotopes indicate that the Panzhihua intrusion is part of the Emeishan large igneous province and has little crustal contamination. To assess ore genesis of the Panzhihua Fe-Ti-V ore deposit, two different models have been provided to explain the formation, namely silicate immiscibility and normal fractional crystallization. Silicate...     

春季黄、渤海沉积物中CH4和N2O的垂向分布特征研究

本研究分别利用顶空平衡法与qPCR技术测定了2018年春季黄、渤海5个典型站位柱状沉积物中甲烷(CH₄)和氧化亚氮(N₂O)浓度及产甲烷菌与硫酸盐还原菌功能基因拷贝数,并分析了其与间隙水中相关环境因子的关系。沉积物上方水文条件的差异以及其中复杂的碳氮生物地球化学过程使得CH₄和N₂O浓度呈现出明显的空间和垂直变化。结果显示,沉积物中CH₄浓度为0.23~0.92 μmol·kg^-1,N₂O浓度为18.90~104.96 nmol·kg^-1。总体来说,渤海沉积物中CH₄和N₂O平均浓度高于黄海。垂向分布上,CH₄浓度均随深度增加逐渐升高, $\text{SO}_{4}^{2-}$浓度随深度增加逐渐降低,并与CH₄浓度呈镜像关系,产甲烷菌与硫酸盐还原菌的丰度也遵循着同样规律,这表明沉积物中产甲烷作用受$\text{SO}_{4}^{2-}$浓度的抑制。 mcrA基因拷贝数平均值为渤海低于黄海。除3500-7站外,沉积物中mcrA基因拷贝数随深度增加而升高。各站位mcrA 基因丰度与CH₄浓度均无显著相关性,且mcrA丰度与$\text{SO}_{4}^{2-}$浓度之间也未检测到显著相关性。dsrB基因拷贝数远高于mcrA基因拷贝数,且两者相差至少两个数量级。 dsrB基因拷贝数随深度逐渐增加,直至10 cm左右,随后至沉积物底部逐渐减少。各站位dsrB基因拷贝数与CH₄浓度剖面略有镜像关系,但均未检测到显著负相关性。以上结果均表明沉积物中存在着同时消耗沉积物中$\text{SO}_{4}^{2-}$与CH₄的其他作用。N₂O浓度随深度增加先降低,在深度30 cm以下逐渐升高。间隙水中$\text{NO}_{3}^{-}$和$\text{NO}_{2}^{-}$浓度均随深度减小,同时$\text{NH}_{4}^{+}$浓度与其呈相反趋势。沉积物中N₂O与$\text{NO}_{2}^{-}$及$\text{NO}_{3}^{-}$浓度均呈正相关,且前者相关性较高,说明反硝化作用是沉积物中N₂O产生的主要过程。这些结果为进一步了解近岸陆架海域沉积物中CH₄和N₂O的来源、分布及碳氮生物地球化学循环提供了参考资料。     

东天山香山铜镍硫化物-钛铁氧化物矿床成因

新疆东天山地区是中国重要的Cu-Ni-Au-Mo-Fe矿集区,目前,该地区唯一的一个铜镍硫化物-钛铁氧化物复合型矿床产自香山岩体中。通过对香山岩体的岩石地球化学和同位素地球化学研究,表明香山岩体是同源岩浆不同演化阶段的产物;硫化物熔离主要受控于岩浆自身分离结晶作用,同化混染和外来硫的加入对硫化物熔离具有一定促进作用。岩浆高度演化、残余岩浆中Ti、Fe元素富集、岩浆体系高氧逸度、富含流体相和挥发分使钛铁氧化物逐步结晶,并在合适的容矿空间富集成矿。     

Synthesis of todorokite by refluxing process and its primary characteristics

Todorokite is one of the common manganese ox-ides in manganese ore deposits, weathering product of manganese-bearing rocks, soils and sediments. It is also an important component in the abundant marine manganese nodules. Since todorokite was firstly found in Japanese Todoroki mine in 1934, its properties and origination have appeared to be very interesting to many researchers[1—3]. It has a stable structure similar to porous molecular sieves, constructed of triple MnO6 octahedral chains. Th…     

Composition and assemblage characteristics of magnetic minerals in layer S<Subscript>5-1</Subscript> of Xifeng and Duanjiapo sections

Relatively strongly magnetic fine components (< 30μm, XS-4J and DS-4J) which are most environmentally sensitive were separated from layer S_5-1 in the Xifeng and Duanjiapo loess sections and analyzed by MPV-3 for their morphometric characteristics and reflectance, SEM-ESD for their element contents and XRD for their mineral phases, respectively. The results showed that minerals in both samples are dominated by detrial Fe-Ti oxides of aeolian origin. In sample XS-4J the reflectance and iron contents of magnetic minerals are usually high. In addition to magnetite (Fe₃O₄), maghemite (γFe₂O₃) and hematite (Fe₂O₃), some Fe-high oxide (72.25 wt%–86.67 wt%), ilmenite (FeTiO₃), and magnetite-ulvöspinel [Fe(FeCr)O₄, Fe (FeNi)O₄] were also detected. In sample DS-4J obvious negative linear correlations were found between Ti and Fe, and the contents of Mn, Si, Al and Ca are usually high and the minerals are dominated by magnetite (maghemite), goethite (FeOOH) and limonite (containing Si and OH). In addition, the signs of corrosion of magnetic minerals and newly crystallized magnetite (maghemite) were recognized. Differences in the composition and assemblage characteristics of magnetite minerals between XS and DS reflect significant differences in source rocks and preserving conditions.     

Use of microelectrodes for electrochemical measurement of nitric oxide in natural seawater

In this paper, the application of a homemade Nation and Co(Salen) modified platinum microelectrode and an ISO-NOPMC microsensor (World Precision Instruments, USA ) to measure nitric oxide in natural seawater is reported. These two microelectrodes are suitable for the measurement. In natural seawater, the sensitivity and stability of the ISO-NOPMC microsensor are higher than that of the homemade Nation and Co(Salen) modified platinum microelectrode.     

原子吸收分光光度法快速测定铬铁矿中钙、镁、锰

通过在标液中加入相应的Sr来消除离子干扰,采用原子吸收分光光度法快速测定CaO、MgO、MnO的含量,方法经国家标准物质验证,其RSD<2%(n=6)。其结果与标准值相符。方法达到了准确、简便、快速、实用性强。     

Temperature-dependent photoabsorption cross-sections of cyanoacetylene and diacetylene in the mid- and vacuum-UV: Application to Titan's atmosphere

Cyanoacetylene (HC₃N) and diacetylene (C₄H₂) play an important role in the photochemistry of Titan's atmosphere, in part because of their strong absorption between 110 and 180 nm. Accurate photoabsorption cross-sections at temperatures representative of Titan's atmosphere are required to interprete Cassini observations and to calculate photolysis rates used in photochemical models. Using synchrotron radiation as a tunable vacuum ultraviolet (VUV) light source, we have measured absolute photoabsorption cross-sections of C₄H₂ and HC₃N with a spectral resolution of 0.05 nm in the region between 80 and 225 nm and at different temperatures between 173 and 295 K. The measured cross-sections are used to model transmission spectra of Titan atmosphere in the VUV.