基于三维荧光光谱-平行因子技术联用的浮游藻化学分类学技术研究

An in vivo three-dimensional fluorescence method for the determination of algae community structure was developed by parallel factor analysis(PARAFAC) and CHEMTAX. The PARAFAC model was applied to fluorescence excitation-emission matrix(EEM) of 60 algae species belonging to five divisions and 11 fluorescent components were identified according to the residual sum of squares and specificity of the composition profiles of fluorescent. By the 11 fluorescent components, the algae species at different growth stages were classified correctly at the division level using Bayesian discriminant analysis(BDA). Then the reference fluorescent component ratio matrix was constructed for CHEMTAX, and the EEM–PARAFAC–CHEMTAX method was developed to differentiate algae taxonomic groups. The correct discrimination ratios(CDRs) when the fluorometric method was used for single-species samples were 100% at the division level, except for Bacillariophyta with a CDR of 95.6%. The CDRs for the mixtures were above 94.0% for the dominant algae species and above 87.0% for the subdominant algae species. However, the CDRs of the subdominant algae species were too low to be unreliable when the relative abundance estimated was less than 15.0%. The fluorometric method was tested using the samples from the Jiaozhou Bay and the mesocosm experiments in the Xiaomai Island Bay in August 2007. The discrimination results of the dominant algae groups agreed with microscopy cell counts, as well as the subdominant algae groups of which the estimated relative abundance was above 15.0%. This technique would be of great aid when low-cost and rapid analysis is needed for samples in a large batch. The fluorometric technique has the ability to correctly identify dominant species with proper abundance both in vivo and in situ.     

电站坝基岩体评价及深层抗滑稳定性分析

某水电站位于雅鲁藏布江中游桑日至加查峡谷段出口处,坝型为混凝土重力坝,最大坝高116m,属高坝。混凝土重力坝主要是依靠坝体自身重量于基础之上产生的摩擦力及坝体与基础之间的凝聚力来抵抗水压力以满足稳定要求,对基础岩体要求较高。根据该水电站坝基工程实践,从坝基岩体质量评价方法、分级标准及深层抗滑稳定计算方法等方面进行一些有益探索,对类似工程坝基岩体质量评价及深层抗滑稳定计算具有指导意义。     

结构面中粘土矿物及含水率变化对边坡稳定性影响的试验研究

以南京某边坡结构面中的滑带土为研究对象,定量分析不同的滑带土颗粒级配情况下,岩质边坡结构面中粘土矿物含量及含水率的变化对边坡稳定性影响机制及变化规律.随着粘土矿物的增加,安全系数值整体上呈现减小的趋势,安全系数在45％～55％之间时达到最低;随含水率的增加,安全系数值也呈下降的趋势.采用了粒子群算法对试验成果作以解析,结果显示,随着粘土矿物含量的增加,安全系数的变化为非线性,但始终表现出较好的相关性,其相关系数由小变大;安全系数值与含水率呈现出一种负相关的线性关系,且保持较高的相关性,相关系数在0.90以上,较符合一般的自然规律.     

雅鲁藏布江结合带东段仁布-曲松地层分区上三叠统朗杰学(岩)群层序及构造样式再认识

雅鲁藏布江结合带东段夹在南、北两条蛇绿混杂岩带之间的一套活动类型的上三叠统朗杰学(岩)群,许多地质工作者对其地层层序、沉积特征、变形变质、物质来源以及形成的构造环境进行过研究。作者在前人工作成果的基础上,综合对比了已往区调工作获得的实际资料,以(构造)岩石地层为基础,结合沉积古生物特征、变形特征以及区域大地构造背景,对该岩(群)作了进一步的研究。初步认为:朗杰学(岩)群地层层序自老至新为宋热(岩)组、江雄(岩)组和姐德秀(岩)组(章村岩组);郎杰学(岩)群的构造样式为一"Ω"型两翼不对称的复式背斜构造。     

Selection of Less Biased Threshold Angles for SAM Classification Using the Real Value–Area Fractal Technique

The accuracy of classification of the Spectral Angle Mapping (SAM) is warranted by choosing the appropriate threshold angles, which are normally defined by the user. Trial‐and‐error and statistical methods are commonly applied to determine threshold angles. In this paper, we discuss a real value–area (RV–A) technique based on the established concentration–area (C–A) fractal model to determine less biased threshold angles for SAM classification of multispectral images. Short wave infrared (SWIR) bands of the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) images were used over and around the Sar Cheshmeh porphyry Cu deposit and Seridune porphyry Cu prospect. Reference spectra from the known hydrothermal alteration zones in each study area were chosen for producing respective rule images. Segmentation of each rule image resulted in a RV–A curve. Hydrothermal alteration mapping based on threshold values of each RV–A curve showed that the first break in each curve is practical for selection of optimum threshold angles. The hydrothermal alteration maps of the study areas were evaluated by field and laboratory studies including X–ray diffraction analysis, spectral analysis, and thin section study of rock samples. The accuracy of the SAM classification was evaluated by using an error matrix. Overall accuracies of 80.62% and 75.45% were acquired in the Sar Cheshmeh and Seridune areas, respectively. We also used different threshold angles obtained by some statistical techniques to evaluate the efficiency of the proposed RV–A technique. Threshold angles provided by statistical techniques could not enhance the hydrothermal alteration zones around the known deposits, as good as threshold angles obtained by the RV–A technique. Since no arbitrary parameter is defined by the user in the application of the RV‐A technique, its application prevents introduction of human bias to the selection of optimum threshold angle for SAM classification.     

Controlling Factors,Accumulation Model and Target Zone Prediction of the Coal‐bed Methane in the Huanghebei Coalfield,North China

The Huanghebei Coalfield, one of the coal production bases in North China, was considered as a coalfield without coal‐bed methane (CBM) during past decades. In recent years, however, CBM has been discovered in coal‐bearing successions. In order to understand the CBM geological characteristics and accumulation process in this area, fifteen coal samples were collected and analyzed with respect to coal maceral and reflectance. The result shows that the gas distribution is uneven and the content varies in different areas even for the same coal bed. The storage of CBM is affected by geological factors such as burial depth, geological structures, and magmatic intrusion, among which the former two are more important in the formation of CBM. Deep burial of coal beds with the presence of cap‐rock mudstone can seal CBM. The CBM is also accumulated and preserved at the place where normal faults are distributed. Magmatic intrusion causes contact metamorphism and controls the CBM formation by heating the coal‐bearing successions. The obtained data indicate the geological conditions in northeastern Zhaoguan Mine are preferable for CBM formation and conservation; recent exploration estimates the CBM geological reserves up to 282.16 Mm³ and average of reserve abundance at 0.1662 × 10⁸ m³ km^?2. The Changqing Mine is a potential prospect in terms of CBM exploration since its geological conditions (structures and burial depth) are similar to the Zhaoguan Mine and its cap rock is even better.     

Calcium,Na, K and Mg Concentrations in Seawater by Inductively Coupled Plasma‐Atomic Emission Spectrometry: Applications to IAPSO Seawater Reference Material,Hydrothermal Fluids and Synthetic Seawater Solutions

We report a measurement procedure to determine simultaneously the major cation concentrations (Na, Ca, K and Mg) of seawater‐derived solutions by inductively coupled plasma‐atomic emission spectrometry. The best results were obtained when the IAPSO (‘standard’) seawater reference material was diluted by thirty times with Milli‐Q^® water. We obtained an average reference value r_K (the ratio of the mass fraction of potassium to that of chlorine, i.e., (g kg^?1)/(g kg^?1)) for IAPSO seawater of 0.0205 ± 0.0006 (2.9% RSD), not significantly different from 0.0206 ± 0.0005 (2.4% RSD) for seawater composition reported in the literature. The measured Na, Ca and Mg concentrations correspond to r_Na, r_Ca and r_Mg values of 0.5406 ± 0.0026 (0.5% RSD), 0.02192 ± 0.00048 (2.2% RSD) and 0.06830 ± 0.00047 (0.7% RSD), respectively, in line with previous values measured by wet‐chemistry and atomic absorption spectrophotometry or wet‐chemical titration. Our measurement procedure was used successfully on synthetic seawater solutions and high‐temperature hydrothermal fluids.     

Sulfur Concentration in Geochemical Reference Materials by Solution Inductively Coupled Plasma‐Mass Spectrometry

With implications for the origin of ore deposits, redox state of the atmosphere, and effects of volcanic outgassing, understanding the sulfur cycle is vital to our investigation of Earth processes. However, the paucity of sulfur concentration measurements in silicate rocks and the lack of well‐calibrated reference materials with concentrations relevant to the rocks of interest have hindered such investigations. To aid in this endeavour, this study details a new method to determine sulfur concentration via high mass resolution solution inductively coupled plasma‐mass spectrometry (ICP‐MS). The method is based on an aqua regia leach, involving relatively rapid sample preparation and analysis, and uses small test portion masses (< 50 mg). We utilised two independently prepared standard solutions to calibrate the analyses, resulting in 4% accuracy, and applied the method to eight geochemical reference materials. Measurements were reproducible to within ~ 10%. Sulfur concentrations and isotopes of six reference materials were measured additionally by elemental analyser‐combustion‐isotope ratio mass spectrometry to independently evaluate the accuracy of the ICP‐MS method. Reference materials that yielded reproducible measurements identical to published values from other laboratories (JGb‐1, JGb‐2 and MAG‐1) are considered useful materials for the measurement of sulfur. Reference materials that varied between studies but were reproducible for a given test portion perhaps suffer from sample heterogeneity and are not recommended as sulfur reference materials.     

Precise and Accurate In Situ Determination of Lead Isotope Ratios in NIST,USGS, MPI‐DING and CGSG Glass Reference Materials using Femtosecond Laser Ablation MC‐ICP‐MS

Lead isotope ratio data were obtained with good precision and accuracy using a 266 nm femtosecond laser ablation (fLA) system connected to a multi‐collector ICP‐MS (MC‐ICP‐MS) and through careful control of analytical procedures. The mass fractionation coefficient induced by 266 nm femtosecond laser ablation was approximately 28% lower than that by 193 nm excimer laser ablation (eLA) with helium carrier gas. The exponential law correction method for Tl normalisation with optimum adjusted Tl ratio was utilised to obtain Pb isotopic data with good precision and accuracy. The Pb isotopic ratios of the glass reference materials NIST SRM 610, 612, 614; USGS BHVO‐2G, BCR‐2G, GSD‐1G, BIR‐1G; and MPI‐DING GOR132‐G, KL2‐G, T1‐G, StHs60/80‐G, ATHO‐G and ML3B‐G were determined using fLA‐MC‐ICP‐MS. The measured Pb isotopic ratios were in good agreement with the reference or published values within 2s measurement uncertainties. We also present the first high‐precision Pb isotopic data for GSE‐1G, GSC‐1G, GSA‐1G and CGSG‐1, CGSG‐2, CGSG‐4 and CGSG‐5 glass reference materials obtained using the femtosecond laser ablation MC‐ICP‐MS analysis technique.     

黔西地区构造变形特征及其煤层气地质意义

黔西地区处于特提斯与滨太平洋两个构造域的交接地带,多期性质不同的构造作用形成了现今错综复杂的构造变形特征。根据构造变形的差异,可划分为织金-纳雍NE向构造变形区、水城-紫云NW向构造变形区和黔西南复杂构造变形区。在野外地质的基础上,结合微观变形特征和矿物流体包裹体测试分析,认为黔西地区构造变形属于上地壳低温-中低温环境下的脆性-脆韧性变形;由于黔西地区基底构造相对稳定,成煤期后断块内部变形较弱,煤储层形成了一定程度的构造裂隙,有助于渗透率的提高,煤层气勘探开发前景良好。