不同年龄杉木人工林土壤无机氮比较研究

在福建南平杉木林中心产区,选取11、21、28、40、88年生杉木人工林以及采伐迹地、杂木林为研究对象,研究不同年龄杉木林土壤无机氮的差异．结果表明：不同年龄杉木林土壤NH4^＋-N含量差异显著,以21年生的杉木人工林最高（11．91±0．43mg·kg^-1）,其他的为88年生的（8．33±0．38mg·kg^-1）〉28年生的（8．19±0．25mg·kg^-1）〉11年生的（5．65±0．17mg·kg^-1）〉40年生的（5．63±0．38mg·kg^-1）;NO3^--N含量较低（3．15～4．11mg·kg^-1）,且没有显著差异,这与杉木林所处的生长阶段、土壤理化性质有关．杉木林取代杂木林后,NH4^＋-N和NO3^--N含量都有所下降;采伐迹地土壤NH4^＋-N（19．74±1．44mg·kg^-1）和NO3^--N（18．05±0．72mg·kg^-1）含量远高于88年生的杉木林,分别是88年生的2．37和4．60倍．本地区无机氮含量较低,NH4^＋-N占无机氮的比例为60．0％～74．3％,NH4^＋-N为无机氮的主要形态．     

ENDOLITHIC LICHENS,RAPID BIOLOGICAL WEATHERING AND SCHMIDT HAMMER R‐VALUES ON RECENTLY EXPOSED ROCK SURFACES: STORBREEN GLACIER FORELAND,JOTUNHEIMEN, NORWAY

The endolithic lichen Lecidea auriculata is known to enhance rock surface weathering on the Little Ice Age moraines of the glacier Storbreen in Jotunheimen, central southern Norway. This study demonstrates the reduction in Schmidt hammer Rvalues that followed the rapid colonization by this lichen of pyroxene‐granulite boulders on terrain deglaciated over the last 88 years. In the absence of this lichen, the characteristic mean R‐value of boulder surfaces is 61.0 ± 0.3; where this lichen is present, R‐values are lower by at least 20 units on surfaces exposed for 30–40 years. A similar reduction in rock hardness on rock surfaces without a lichen cover requires about 10 ka. The rapid initial weakening of the rock surfaces is indicative of rates of biological weathering by endolithic lichens that may be two orders of magnitude (200–300 times) faster than rates of physico‐chemical weathering alone. If not avoided, the effects of this type of lichen are likely to negate the effectiveness of the Schmidt hammer and other methods for exposure‐age dating, including cosmogenic‐nuclide dating, in severe alpine and polar periglacial environments. The results also suggest a new method for dating rock surfaces exposed for <50 years.     

Feldspar multi-elevated-temperature post-IR IRSL dating of the Wulanmulun Paleolithic site and its implication

The Wulanmulun site found in 2010 is an important Paleolithic site in Ordos (China), from which lots of stone and bone artifacts and mammalian fossils have been recovered. It was previously dated by radiocarbon and optically stimulated luminescence (OSL) techniques on quartz. To further confirm the reliability of the chronology constructed based on OSL ages and test the applicability of the recently developed pIRIR procedure on sediments from northern China, twenty-four sediment samples (including eolian, lacustrine and fluvio-eolian sands) from the site were determined using the multi-elevated-temperature post-IR IRSL (MET-pIRIR or pIRIR) procedure on potassium feldspar. The results show that the studied samples have two MET-pIRIR D_e preheat plateaus (280–320 and 340–360 °C), and the bleaching rates of the luminescence signals are associated with sample ages and stimulation temperatures. All the pIRIR ages (7–155 ka) corrected for anomalous fading and residual dose obtained after solar bleaching for 15 h are larger than the corresponding quartz OSL ages (4–66 ka) previously determined, even for the young eolian samples (<10 ka). But the corrected IRSL(50 °C) ages (6–85 ka) are broadly consistent with the quartz ages. It appears that the IRSL(50 °C) ages are more reliable, although this contradicts the previously results obtained by other people. On the other hand, we also obtained an extended age plateau between the stimulation temperatures of 50 and 290 °C in the plot of age versus stimulation temperature (A-T plot) by subtracting different residual doses obtained after different bleaching times. The reliability of the plateau ages requires further investigation. For the sediment samples from this site, quartz should be more suitable for dating than K-feldspar, and the quartz OSL ages of 50–65 ka for its cultural layer should be reliable.     

内蒙古扎鲁特旗地区中侏罗统塔木兰沟组的厘定

扎鲁特旗地区发育的一套中性火山岩,前人曾将其置于二叠纪“大石寨组”、“青凤山组”,缺少古生物资料和测年数据.本次1：25万区域地质调查,在原1：20万划分的“大石寨组”、“青凤山组”的安山岩中采集了同位素测年样品,采用全岩激光⁴⁰Ar/³⁹Ar法测年,对火山岩样品进行了年代学研究,结果表明火山岩年龄为（172.7±2.0）~（165.2±1.3）Ma.鉴于这套火山岩地层岩石组合特征清楚,时代依据充分,在区域上具有一定的延展性和可填图性,故将这套火山岩地层重新厘定为中侏罗统塔木兰沟组.     

Conceptual modelling to assess how the interplay of hydrological connectivity,catchment storage and tracer dynamics controls nonstationary water age estimates

Although catchment storage is an intrinsic control on the rainfall–runoff response of streams, direct measurement remains a major challenge. Coupled models that integrate long‐term hydrometric and isotope tracer data are useful tools that can provide insights into the dynamics of catchment storage and the volumes of water involved. In this study, we use a tracer‐aided hydrological model to characterize catchment storage as a dynamic control on system function related to streamflow generation, which also allows direct estimation of the nonstationarity of water ages. We show that in a wet Scottish upland catchment dominated by runoff generation from riparian peats (histosols) with high water storage, nonstationarity in water age distributions is only clearly detectable during more extreme wet and dry periods. This is explained by the frequency and longevity of hydrological connectivity and the associated relative importance of flow paths contributing younger or older waters to the stream. Generally, these saturated riparian soils represent large mixing zones that buffer the time variance of water age and integrate catchment‐scale partial mixing processes. Although storage simulations depend on model performance, which is influenced by input variability and the degree of isotopic damping in the stream, a longer‐term storage analysis of this model indicates a system that is only sensitive to more extreme hydroclimatic variability. Copyright © 2014 John Wiley & Sons, Ltd.     

地下水测年方法及其在地震监测中的应用展望

对地下水动力学特征的观测与研究,是地震前兆监测的重要方法之一。地下水动力学研究中,利用地下水测年方法,可以对地下水的补给、径流特征及更新能力作出定性和定量的分析。本文介绍了近年来国际上常用的地下水测年方法,总结了前人在该领域的主要研究进展,重点分析了地下水更新能力与地震前兆信息的关系、地下水运动规律与地震构造活动的关系以及地下水浅层补给与异常干扰排除的方法等。已有的研究成果表明,地下水年龄的测定与分析方法对于了解监测点映震能力、评价构造活动与地震活动程度,以及在观测资料异常变化的现场核实等方面,可以发挥重要作用。     

2014年云南鲁甸M_S6.5地震人员死亡年龄分布特征

通过收集到鲁甸地震分县(区)地震人员死亡统计表,对死亡人员的年龄、性别、死亡原因、死亡地点等情况进行分类分析,得到鲁甸地震人员死亡类型和死亡人员年龄总体分布特征。并分别对因房屋倒塌、因崩塌滑坡、因抢救无效致死人员年龄分布特征,性别—年龄分布特征等地震人员死亡年龄分布特征进行总结分析。同时与国内同类研究相比,鲁甸地震造成的人员死亡具备地震人员死亡的普遍特征,同时具有山区、经济欠发达地区地震人员死亡的特性。     

特提斯喜马拉雅带东段列麦白云母花岗岩年代学及成因

列麦白云母花岗岩位于特提斯喜马拉雅东段,侵位于雅拉香波穹窿边部早古生代浅变质岩中。为揭示其形成时代及成因,本文对其开展LA-ICP-MS锆石U-Pb年代学、Hf同位素及岩石地球化学研究。结果表明列麦白云母花岗岩具有高SiO_2(71.08%～71.49%)、Al_2O_3(15.55%～15.72%)和K_2O(4.32%～4.57%),高的A/CNK比值(1.17～1.21),低的CaO/Na_2O比值(0.22～0.28),属于高钾钙碱性过铝质花岗岩;富集Rb、Th和Hf,亏损Ba、Nb、Sr和Ti,稀土元素呈轻稀土(LREE)富集,重稀土(HREE)相对亏损的向右倾斜的配分模式(LREE/HREE=16.57～17.91),具有弱负Eu异常(δEu=0.78～0.79)。与二云母花岗岩比较,列麦白云母花岗岩具有较高的Rb含量(204.1×10~(-6)～293.8×10~(-6))、较低的Sr(134.6×10~(-6))及显著的重稀土分馏效应。锆石新生边年龄为48.5±1.1 Ma(MSWD=2.1),代表其结晶年龄,该年龄为目前报道的最早年龄,其初始Hf同位素组成ε_(Hf)(t)=-6.4～-2.3,显示物源为壳源性质,二阶段模式年龄介于731～839 Ma之间,表明成岩物质形成于新元古代;核部继承锆石年龄变化在135.7～3339.2 Ma之间,表明其源岩为早白垩世沉积岩,是在印度与欧亚大陆主碰撞阶段,陆-陆碰撞导致地壳缩短加压升温,引起早白垩世沉积岩部分熔融而形成的。     

太行山南段铜矿成矿时代厘定及成矿意义

太行山南段井陉-内丘一带是河北省重要的铜矿远景区,区内成矿条件优越。已有研究资料多将该区铜矿类型、成矿条件等与山西中条山铜矿富集区进行类比。由于缺少对铜的成矿时代的精确限定,致使无法对区内铜矿床的形成过程及成因进行较为准确的分析,制约着区域铜矿成因类型对比及找矿勘查工作部署。本文以区内桃园铜矿床及酸枣坪、虎寨口、鹿峪和方垴等四个铜矿化点为研究对象,采用Rb-Sr法测试分析了上述铜矿床及矿化点的矿石硫化物。测试结果显示,桃园铜矿不同硫化物对Rb-Sr等时线年龄在1829.6~1840Ma之间,酸枣坪铜矿点的形成时代为1830.7±5.2Ma,虎寨口铜矿点的形成时代为1844.3±5.9Ma。上述三个铜矿床(点)矿石硫化物Rb-Sr等时线年龄测试结果表明,在古元古代晚期区内有一次较为强烈的铜矿成矿作用,成矿时限在1830~1844Ma之间。而方垴和鹿峪两个铜矿化点矿石硫化物测年结果与上述三个铜矿床(点)形成时间有较大差异,Rb-Sr等时线测年结果分别为1402±23Ma和1376±37Ma,说明在中元古代长城纪末期区内仍有一次铜矿化作用发生。结合华北地台构造演化过程,太行山南段古元古代晚期第一次铜矿化与山西中条山胡-篦型铜矿形成时代接近,铜矿床的形成与吕梁运动关系密切。由于太行山南段铜矿(点)分布区地处陆内构造环境的晋豫裂陷带,而山西中条山铜矿富集区处于秦岭-大别活动带的北缘的"秦岭古洋"壳向华北地台俯冲环境,构造环境差异可能导致两区在铜矿形成潜力及规模上存在一定差异。与区内第一次铜矿化作用相比,发生在中元古代长城纪末期的第二期铜矿化在成矿规模及强度上均较弱,其成矿动力学机制有待进一步分析确定。     

Dating the giant Zhuxi W–Cu deposit (Taqian–Fuchun Ore Belt) in South China using molybdenite Re–Os and muscovite Ar–Ar system

The recently discovered Zhuxi W–Cu ore deposit is located within the Taqian–Fuchun Ore Belt in the southeastern edge of the Yangtze Block, South China. Its inferred tungsten resources, based on new exploration data, are more than 280 Mt by 2016. At least three paragenetic stages of skarn formation and ore deposition have been recognized: prograde skarn stage; retrograde stage; and hydrothermal sulfide stage. Secondly, greisenization, marmorization and hornfels formation are also observed. Scheelite and chalcopyrite are the dominant metal minerals in the Zhuxi deposit and their formation was associated with the emplacement of granite stocks and porphyry dykes intruded into the surrounding Carboniferous carbonate sediments (Huanglong and Chuanshan formations) and the Neoproterozoic slate and phyllites. The scheelite was mostly precipitated during the retrograde stage, whereas the chalcopyrite was widely precipitated during the hydrothermal sulfide stage. A muscovite ⁴⁰Ar/³⁹Ar plateau age of about 150 Ma is interpreted as the time of tungsten mineralization and molybdenite Re–Os model ages ranging from 145.9 ± 2.0 Ma to 148.7 ± 2.2 Ma (for the subsequent hydrothermal sulfide stage of activity) as the time of the copper mineralization. Our new molybdenite Re–Os and muscovite ⁴⁰Ar/³⁹Ar dating results, along with previous zircon U–Pb age data, indicate that the hydrothermal activity from the retrograde stage to the last hydrothermal sulfide stage lasted up to 5 Myr, from 150.6 ± 1.5 to 145.9 ± 1 Ma, and is approximately coeval or slightly later than the emplacement of the associated granite porphyry and biotite granite. The new ages reported here confirm that the Zhuxi tungsten deposit represents one of the Mesozoic magmatic–hydrothermal mineralization events that took place in South China in a setting of lithospheric extension during the Late Jurassic (160–150 Ma). It is suggested that mantle material played a role in producing the Zhuxi W–Cu mineralization and associated magmatism.