Re-Os geochronology of Cu and W-Mo deposits in the Balkhash metallogenic belt,Kazakhstan and its geological significance

<正>The Central Asian metallogenic domain(CAMD) is a multi-core metallogenic system controlled by boundary strike-slip fault systems.The Balkhash metallogenic belt in Kazakhstan,in which occur many large and super-large porphyritic Cu—Mo deposits and some quartz vein- and greisen-type W—Mo deposits,is a well-known porphyritic Cu—Mo metallogenic belt in the CAMD.In this paper 11 molybdenite samples from the western segment of the Balkhash metallogenic belt are selected for Re—Os compositional analyses and Re—Os isotopic dating.Molybdenites from the Borly porphyry Cu deposit and the three quartz vein-greisen W—Mo deposits—East Kounrad.Akshatau and Zhanet—all have relatively high Re contents(2712—2772μg/g for Borly and 2.267—31.50μg/g for the other three W—Mo deposits),and lower common Os contents(0.670—2.696 ng/g for Borly and 0.0051—0.056 ng/g for the other three).The molybdenites from the Borly porphyry Cu—Mo deposit and the East Kounrad,Zhanet,and Akshatau quartz vein- and greisen-type W—Mo deposits give average model Re—Os ages of 315.9 Ma,298.0 Ma,295.0 Ma,and 289.3 Ma respectively.Meanwhile,molybdenites from the East Kounrad,Zhanet,and Akshatau W—Mo deposits give a Re—Os isochron age of 297.9 Ma,with an MSWD value of 0.97.Re-Os dating of the molybdenites indicates that Cu—W—Mo metallogenesis in the western Balkhash metallogenic belt occurred during Late Carboniferous to Early Permian(315.9—289.3 Ma),while the porphyry Cu—Mo deposits formed at—316 Ma,and the quartz vein-greisen W—Mo deposits formed at ~298 Ma.The Re—Os model and isochron ages thus suggest that Late Carboniferous porphyry granitoid and pegmatite magmatism took place during the late Hercynian movement.Compared to the Junggar-East Tianshan porphyry Cu metallogenic belt in northwestern China,the formation of the Cu—Mo metallogenesis in the Balkhash metallogenic belt occurred between that of the Tuwu-Yandong in East Tianshan and the Baogutu porphyry Cu deposits in West Junggar. Collectively,the large-scale Late Carboniferous porphyry Cu—Mo metallogenesis in the Central Asian metallogenic domain is related to Hercynian tectono-magmatic activities.     

西秦岭大水金矿岩浆岩年代学、地球化学特征

西秦岭大水金矿床与其周围伴生的中酸性小岩体的成因关系,直接影响矿床成因的划分和深部资源的开发。中酸性岩浆岩的成因、源区性质及岩体规模对金矿成矿有重要影响。大水金矿岩浆岩地球化学研究结果显示:岩浆系列属于高钾钙碱性系列;岩体球粒陨石标准化稀土元素配分模式具有轻稀土元素富集、重稀土元素亏损、Eu正异常的特征;岩体洋中脊花岗岩标准化微量元素蛛网图显示其富集大离子亲石元素K、Rb、Ba、Th等,亏损高场强元素Nb、Ta、Hf、Zr、Sm、Y、Yb等,花岗岩的w(Sr)-w(Yb)分类属于高Sr、低Yb"C"型埃达克岩。LA-ICP-MS锆石U-Pb法测年获得大水金矿格尔括合岩体和竖井941岩脉的锆石U-Pb年龄分别为(215.8±1.3)、(202.9±1.5)Ma;成矿热液蚀变叠加在脉岩之上,成矿年龄应晚于202.9 Ma的脉岩年龄。Sr-Nd同位素组成具有高初始N(87Sr)/N(86Sr)值、低εNd的特点,模式年龄为1.29~1.47Ga。εSr(t)-εNd(t)图解表明岩浆源区为下地壳;εNd(t)-初始N(87Sr)/N(86Sr)图解暗示西秦岭存在统一的岩浆源区。因此,西秦岭大水金矿在成因上与高Sr、低Yb"C"型埃达克岩密切相关。     

小秦岭地区太华群锆石U-Pb年龄及华北克拉通南缘地壳演化

以小秦岭地区太华群二长片麻岩为研究对象,分析其地球化学、锆石U-Pb年龄和Hf同位素特征。地球化学分析显示其原岩为高钾钙碱性花岗质岩石,稀土元素总含量较高(229×10-6),轻、重稀土元素分馏明显(w(La)N/w(Yb)N=45.39),有明显的Eu负异常(0.43)。原始地幔标准化微量元素蛛网图显示其富集Rb、Ba、Th、U等大离子亲石元素和亏损Nb、Ta、Sr、P、Ti等高场强元素。锆石U-Pb定年结果显示,其原岩的形成时代为古元古代早期(2.47Ga)。锆石Hf同位素分析结果显示:初始N(176 Hf)/N(177 Hf)值变化范围很小,为0.281 284~0.281 328,εHf(t)值均为正值(0.93~5.18);二阶段Hf模式年龄为2.70~2.89Ga,新生地壳(现代岛弧火山)Hf模式年龄为2.54~2.73Ga,接近于锆石结晶年龄(2.47Ga),指示华北克拉通南缘在这一时期有明显的新生地壳生长。华北克拉通南缘在新太古代早期(2.7~2.9Ga)、新太古代晚期—古元古代早期(2.2~2.5Ga)和古元古代中期(1.8~2.1Ga)有3期重要的构造热事件。新太古代早期及晚期有明显的新生地壳生长(εHf(t)0),新太古代晚期—古元古代早期和古元古代中期的岩浆活动有明显的新生地壳生长,同时还伴随有古老地壳物质的再循环和改造(εHf(t)0或εHf(t)0)。     

东秦岭华县西沟钼矿床Re-Os同位素年龄及其地质意义

东秦岭华县西沟钼矿床位于华北陆块南缘老牛山岩体与华山岩体所夹持的EW向长廊中,产出于太古界太华群黑云斜长片麻岩地层内。该矿床已经被确定为中型矿床。西沟钼矿区内构造发育,岩浆活动强烈,展布的多条长石-石英脉、碳酸盐脉型钼矿体主要受近EW向剪切带控制,矿石类型以石英脉型、长石-石英脉型、方解石-石英脉型及蚀变岩型为主。应用Re-Os同位素地质年代学方法测得西沟钼矿床的成矿模式年龄为(206.7±2.8)~(214.7±2.8)Ma,等时线年龄为(212.4±2.8)Ma,属于印支晚期;辉钼矿Re质量分数为(306.6~401.0)×10-6,暗示成矿物质主要来源于上地幔。区域成矿条件对比发现,西沟钼矿床与黄龙铺钼矿床在成矿时代、成因类型等方面具有一致性,矿床类型划归为长石-石英脉、碳酸盐脉型。依据化探异常及初步勘查结果,预测西沟地区深部可能存在有隐伏岩体,具有寻找大型钼矿床的潜力。     

中龄和老龄杉木人工林细根序级形态和呼吸特征

以福建省南平市王台镇溪后村安曹下19年生和91年生杉木人工林为研究对象,对其1~5级细根的形态及呼吸特征进行了比较研究。结果表明:2个林分细根直径、根长、组织密度随序级升高逐渐增大,比根长及比根呼吸随序级升高则减小;2个林分细根仅在4级根之间和5级根之间的直径以及5级根之间的比根呼吸具有显著差异(P0.05)。方差分析表明林龄仅对细根直径有极显著影响(P0.01),对根长、比根长、组织密度及比根呼吸的影响均不显著;林龄和序级的交互作用对细根直径,比根长及比根呼吸有显著影响(P0.05,P0.01),对根长和组织密度的影响不显著;序级对两个林分细根直径、根长、比根长、组织密度及比根呼吸的影响均达到极显著水平(P0.01)。回归分析表明2个林分细根直径、根长、比根长、组织密度及比根呼吸与序级之间具有三次函数,指数函数,或者幂函数关系。     

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冀北承德盆地九龙山组凝灰岩夹层LA-ICP-MS锆石U-Pb定年及其地质意义

冀北承德盆地中生代侏罗纪地层序列较齐全,但作为关键层位之一的九龙山组一直缺乏高精度年代学的约束。笔者首次对九龙山组凝灰岩夹层进行了LA-ICP-MS锆石U-Pb高精度定年,获得凝灰岩中岩浆锆石206Pb/238U加权平均年龄164.1±1.3 Ma。综合研究及对比表明,九龙山组的时限为158~164Ma,属中侏罗世晚期至晚侏罗世早期,对应于国际地层表的牛津期至卡洛维期,其沉积时间相对短暂。在此基础上,更新了研究区侏罗系年代地层柱状图,该认识对于深入研究燕山地区中生代侏罗纪地层格架及构造岩浆演化过程具有重要意义。     

Metallogenic and Metamorphic Age of the Hongtoushan Copper–Zinc Massive Sulfide Deposit,Liaoning Province,China

The Hongtoushan copper–zinc deposit is the only large Archean volcanogenic massive sulfide (VMS) deposit in China. This paper presents new information on the timing of metallogenesis and metamorphism of the deposit, including new cathodoluminescence (CL) images, and Th U^?1 and LA–ICP–MS U–Pb dating on zircons of the biotite–plagioclase gneiss and plagioclase–amphibole gneiss that host the deposit. The CL images and Th U^?1 ratios indicate that the zircons within the gneiss are of metamorphic origin. LA–ICP–MS dating of the plagioclase–amphibole gneiss yielded the upper intercept ages of 2549 Ma, and the biotite–plagioclase gneiss yielded the upper intercept ages of 2552 Ma and 2550 Ma correspondingly, indicating that the mineralization of the deposit occurred at around 2550 Ma. The rims of zircons within these host rocks yielded younger U–Pb ages at 2529, 2520 and 2515 Ma, identical to the age of felsic intrusive rocks in the study area. This suggests that the Hongtoushan VMS deposit underwent initial metamorphism and deformation at around 2520 Ma by the intrusion of granite magmas.     

Geochronology and fluid inclusion study of the Yinjiagou porphyry–skarn Mo–Cu–pyrite deposit in the East Qinling orogenic belt,China

The Yinjiagou Mo–Cu–pyrite deposit of Henan Province is located in the Huaxiong block on the southern margin of the North China craton. It differs from other Mo deposits in the East Qingling area because of its large pyrite resource and complex associated elements. The deposit’s mineralization process can be divided into skarn, sulfide, and supergene episodes with five stages, marking formation of magnetite in the skarn episode, quartz–molybdenite, quartz–calcite–pyrite–chalcopyrite–bornite–sphalerite, and calcite–galena–sphalerite in the sulfide episode, and chalcedony–limonite in the supergene episode. Re–Os and ⁴⁰Ar–³⁹Ar dating indicates that both the skarn-type and porphyry-type orebodies of the Yinjiagou deposit formed approximately 143 Ma ago during the Early Cretaceous. Four types of fluid inclusions (FIs) have been distinguished in quartz phenocryst, various quartz veins, and calcite vein. Based on petrographic observations and microthermometric criteria the FIs include liquid-rich, gas-rich, H₂O–CO₂, and daughter mineral-bearing inclusions. The homogenization temperature of FIs in quartz phenocrysts of K-feldspar granite porphyry ranges from 341 °C to >550 °C, and the salinity is 0.4–44.0 wt% NaCl eqv. The homogenization temperature of FIs in quartz–molybdenite veins is 382–416 °C, and the salinity is 3.6–40.8 wt% NaCl eqv. The homogenization temperature of FIs in quartz–calcite–pyrite–chalcopyrite–bornite–sphalerite ranges from 318 °C to 436 °C, and the salinity is 5.6–42.4 wt% NaCl eqv. The homogenization temperature of FIs in quartz–molybdenite stockworks is in a range of 321–411 °C, and the salinity is 6.3–16.4 wt% NaCl eqv. The homogenization temperature of FIs in quartz–sericite–pyrite is in a range of 326–419 °C, and the salinity is 4.7–49.4 wt% NaCl eqv. The ore-forming fluids of the Yinjiagou deposit are mainly high-temperature, high-salinity fluids, generally with affinities to an H₂O–NaCl–KCl ± CO₂ system. The δ¹⁸O_H2O values of ore-forming hydrothermal fluids are 4.0–8.6‰, and the δD_V-SMOW values are between −64‰ and −52‰, indicating that the ore-forming fluids were primarily magmatic. The δ³⁴S_V-CDT values of sulfides range between −0.2‰ and 6.3‰ with a mean of 1.6‰, sharing similar features with deeply sourced sulfur, implying that the sulfur mainly came from the lower crust composed of poorly differentiated igneous materials, but part of the heavy sulfur came from the Guandaokou Group dolostone. The ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb, and ²⁰⁸Pb/²⁰⁴Pb values of sulfides are in the range of 17.331–18.043, 15.444–15.575, and 37.783–38.236, respectively, which is generally consistent with the Pb isotopic signature of the Yinjiagou intrusion, suggesting that the Pb chiefly originated from the felsic–intermediate intrusive rocks in the mine area, with a small amount of lead from strata. The Yinjiagou deposit is a porphyry–skarn deposit formed during the Mesozoic transition of a tectonic regime that is EW-trending to NNE-trending, and the multiepisode boiling of ore-forming fluids was the primary mechanism for mineral deposition.     

大兴安岭地区嫩北农场一带晚古生代火山岩地层的厘定

大兴安岭嫩北农场一带出露一套以中酸性火山熔岩为主的晚古生代地层.前人对这套地层划分、时代归属存有很大分歧.原因是:一方面区域上火山岩出露厚度大、露头不连续、区域植被茂盛,顶底多为断层接触或被第四系所覆盖;另一方面由于存在于火山岩地层中的化石较少或缺少精确的同位素年代学数据.本文在新近研究成果的基础上,依据地层岩石组合对比及锆石U-Pb年代学资料,将这套晚古生代地层进行了重新厘定为大石寨组.