Static compression of α-Fe<Subscript>2</Subscript>O<Subscript>3</Subscript>: linear incompressibility of lattice parameters and high-pressure transformations

The high-pressure behavior of ntent/n06g7j5b3x8tf9p4/xxlarge945.gif" alt="agr" align="BASELINE" BORDER="0">-Fe₂O₃ has been studied under static compression up to 60 GPa, using a laser-heated diamond anvil cell. Synchrotron-based angular-dispersive X-ray diffraction shows that the sample remains in the corundum structure up to 50 GPa, but with the appearance of coexisting diffraction lines from a high-pressure phase at pressures above 45 GPa. A least-squares fit of low-pressure phase data to an Eulerian finite-strain equation of state yields linear incompressibilities of K _{a 0}=749.5 (&plusmn; 18.4) GPa and K _{c 0}= 455.7 (&plusmn; 21.4) GPa, differing by a factor of 1.6 along the two directions. The enhanced compressibility of the c axis may lead to breaking of vertex- or edge-sharing bonds between octahedra, inducing the high-pressure phase transformation at 50 GPa. Analysis of linear compressibilities suggests that the high-pressure phase above 50 GPa is of the Rh₂O₃ (II) structure. Continuous laser heating reveals a new structural phase transformation of ntent/n06g7j5b3x8tf9p4/xxlarge945.gif" alt="agr" align="BASELINE" BORDER="0">-Fe₂O₃ at 22 GPa, to an orthorhombic structure with a=7.305(3) &Aring;, b=7.850(3) &Aring;, and c=12.877(14) &Aring;, different from the Rh₂O₃ (II) structure.     

中国煤层气勘探开发技术研究进展

我国煤层气勘探开发工作走过了十多年的探索历程,大致可以分为三个阶段：技术引进阶段、勘探评价阶段、开发试验及探索研究阶段。目前,制约煤层气商业开发的瓶颈技术问题在于寻找煤层气富集高渗区、提高煤层气产能的开发工艺技术。本文将着重介绍我国在煤层气勘探开发技术方面的研究进展,主要包括煤层气资源评价和区块优选评价技术、钻井技术、完井工艺技术、压裂工艺技术、注CO2增产技术、煤层气地球物理探测技术、煤层气井抽放技术、煤层气生产和评价技术等等。同时,提出了今后我国煤层气勘探开发技术存在的问题和发展趋势。     

IMPACTS OF TRANSPORTATION CHANGES ON THE WOODWORKING INDUSTRY OF MEXICO'S PURÉPECHA REGION

ABSTRACT. The PurÉpecha region of Michoacán State, in west‐central Mexico, has a strong tradition of craft production, especially wooden items. Transportation improvements in the region since the mid‐twentieth century have led to a higher level of integration of the regional economy, yet access to the broader Mexican market remains limited. Towns throughout the region have experienced substantial changes in the types of crafts produced, the extent of their local and external markets, and the location of craft production. Transportation improvements have, in part, led to agglomeration economies and a resultant contraction in the number of different types and an increase in the volume of the crafts produced. Market changes have led to the proliferation of craft storefronts in towns with higher levels of accessibility. Conversely, remote towns still rely heavily on distributors and have not been able to expand their markets. As a result, the region has seen the development of a two‐tiered system whereby towns with increased accessibility have viable craft industries and towns with limited accessibility struggle with stagnant craft industries.     

The cultural context of forest degradation in adjacent Purépechan communities, Michoacán, Mexico

Recent changes in the cultural and forest landscapes of the Meseta Purépecha in Michoacán, Mexico as a result of forest degradation underscore the complexity of forest change processes in the tropical highlands of Latin America. Differences in community perception and forest structure and composition between the furniture-making and lumber-producing towns of Pichátaro and Sevina, Purépechan indigenous communities located amidst pine forests on Michoacán's volcanic plateau illustrate the dynamics of this process. We base our comparisons on interviews and field measures of forest structure. Our results show dramatic changes in the forests and cultural landscapes of both communities during the past decade. Following high regional timber exports during the early 1990s, Sevina shifted from a self-sufficient to a timber importation community. By comparison, communal forests and individual parcels in Pichátaro continue to provide wood for approximately 300 wood shops. Field data and forest stand maps confirm the perception of forest degradation in both communities. While Pichátaro has maintained a larger and more diverse forest base to date, stand structure data indicate selective harvesting has led to a shift in dominance toward the less economically desirable pine species and oak. Deforestation and degradation of Sevina and Pichátaro's community forests are symptomatic of both the Meseta Purépecha and Mexico in general. Current forest conditions in both communities justify local, regional, and national concerns regarding declining biodiversity and sustainable economies.     

Quasi-Wavelet Model of Von Kármán Spectrum of Turbulent Velocity Fluctuations

The von Kármán spectra of turbulent temperature andvelocity fluctuations have been widely used in the literature on turbulenceand electromagnetic, seismic, and acoustic wave propagation in random media.In this paper we provide a phenomenological motivation for the vonKármán velocity spectrum in terms of the quasi-wavelet model ofturbulence developed recently. In this model, turbulence is represented as asuperposition of self-similar localized eddies of many different scales. Wefind a functional form for these eddies that yields the von Kármán velocity spectrum exactly. We also show that other eddy functions producevelocity spectra that have the same general form as the von Kármán spectrum, and we consider possible quasi-wavelet representations of the`Kansas' spectrum and the `-1' spectrum. We also present asystematic determination, based on turbulence similarity theories, of theparameters of the von Kármán spectra of temperature and velocityfluctuations in an unstable atmospheric boundary layer.     

Geochemistry of the volcano-hydrothermal system of El Chichón Volcano, Chiapas, Mexico

 The 1982 eruption of El Chichón volcano ejected more than 1 km³ of anhydrite-bearing trachyandesite pyroclastic material to form a new 1-km-wide and 300-m-deep crater and uncovered the upper 500 m of an active volcano-hydrothermal system. Instead of the weak boiling-point temperature fumaroles of the former lava dome, a vigorously boiling crater spring now discharges  / 20 kg/s of Cl-rich (∼15 000 mg/kg) and sulphur-poor ( / 200 mg/kg of SO₄), almost neutral (pH up to 6.7) water with an isotopic composition close to that of subduction-type magmatic water (δD=–15‰, δ¹⁸O=+6.5‰). This spring, as well as numerous Cl-free boiling springs discharging a mixture of meteoric water with fumarolic condensates, feed the crater lake, which, compared with values in 1983, is now much more diluted (∼3000 mg/kg of Cl vs 24 030 mg/kg), less acidic (pH=2.6 vs 0.56) and contains much lower amounts of S ( / 200 mg/kg of SO₄, vs 3550 mg/kg) with δ³⁴S=0.5–4.2‰ (+17‰ in 1983). Agua Caliente thermal waters, on the southeast slope of the volcano, have an outflow rate of approximately 100 kg/s of 71  °C Na–Ca–Cl water and are five times more concentrated than before the eruption (B. R. Molina, unpublished data). Relative N₂, Ar and He gas concentrations suggest extensional tectonics for the El Chichón volcanic centre. The ³He/⁴He and ⁴He/²⁰Ne ratios in gases from the crater fumaroles (7.3R_a, 2560) and Agua Caliente hot springs (5.3R_a, 44) indicate a strong magmatic contribution. However, relative concentrations of reactive species are typical of equilibrium in a two-phase boiling aquifer. Sulphur and C isotopic data indicate highly reducing conditions within the system, probably associated with the presence of buried vegetation resulting from the 1982 eruption. All Cl-rich waters at El Chichón have a common source. This water has the appearence of a "partially matured" magmatic fluid: condensed magmatic vapour neutralized by interaction with fresh volcaniclastic deposits and depleted in S due to anhydrite precipitation. Shallow ground waters emerging around the volcano from the thick cover of fresh pumice deposits (Red waters) are Ca–SO₄–rich and have a negative oxygen isotopic shift, probably due to ongoing formation of clay at low temperatures. Received: 21 July 1997 / Accepted: 4 December 1997     

混合表面活性剂存在下锰的高灵敏显色反应研究

研究了碱性介质中,Ｍｎ（Ⅱ）被空气氧化生成Ｈ２ＭｎＯ３,然后在Ｈ３ＰＯ４介质中,Ｃｕ（Ⅱ）和阳离子型有机相／水相微乳液（ＣＴＭＡＢ／戊醇／正庚烷／水）的存在下,Ｍｎ（Ⅳ）与二安替比林对乙氧基苯基甲烷（ＤＡｐＥＭ）生成橙色产物,λｍａｘ为４５０ｎｍ,ε＝１．９５×１０５Ｌ·ｍｏｌ－１·ｃｍ－１。Ｍｎ（Ⅱ）的质量浓度在０～３２０μｇ／Ｌ内符合比尔定律。方法用于合金中锰的测定,结果与标准值符合,５次测定结果的ＲＳＤ＜３％。     

惯性区低-β等离子体中的动力学Alfvén孤波

运用双流体MHD方程描述电子和离子的行为, 采用非扰动理论, 把孤子看作经典粒子, 通过推导的赝势(也称Sagdeev势)方程, 结合数值计算来研究惯性区低-β等离子体中动力学Alfvén孤波的特性. 结果表明离子热效应对Alfvén孤波特性的影响不可忽略, 且在惯性区稀疏型孤波和压缩型孤波均存在. 此结论与Freja卫星在极区上空所观测结果吻合很好. Alfvén孤波携带有平行电场, 它对带电粒子的加速有重要作用, 这给极光粒子加速提供了一种可能的物理机制.