高压密闭消解-电感耦合等离子体质谱法测定海洋沉积物中稀土元素

样品用HNO3-HF高压密闭消解,电感耦合等离子体质谱测定海洋沉积物中15种稀土元素。研究了消解方法、酸体系和质谱干扰对稀土元素测定的影响。结果表明,相比于电热板消解和微波消解,高压密闭消解具有酸用量少、消解完全、消解过程损失少等优点;HNO3-HF体系能有效地分解海洋沉积物样品;利用干扰离子校正方程,能有效地校正Ba和轻稀土元素所形成的多原子离子干扰。15种稀土元素的方法检出限为3～15 ng/g。使用水系沉积物标准物质GBW 07309和GBW 07311、海底沉积物标准物质GBW 07313进行验证,测定值与标准值基本吻合,相对标准偏差和相对误差均低于5%。方法用于长江口沉积物样品的测定,精密度(RSD,n=6)小于5%,加标回收率为95.8%～104%。该方法检出限低,精密度和准确度高,适用于大批海洋沉积物样品的分析。     

西南煤系地层山区采动型崩滑灾害研究关键问题

文章在分析采矿型崩滑灾害发育特征的基础上,得出西南煤系地层山区地下采动型崩滑灾害常发生在层状碳酸盐岩与碎屑岩地层组成的褶皱翼部和核部的陡崖带上,与地形地貌、地层结构与地下采矿工程活动等因素关系密切,并指出薄矿层开采诱发大型山体崩滑灾害的具体过程：①采空后覆岩顶板塌落—覆岩顶板离层,采空区上覆岩层内部及层间自下而上应力传递;②地下水运移通道形成,并加快更大范围岩体结构破坏及扩展,加速了岩体结构面的松动与破坏;③上覆岩层不均匀沉降导致坡脚压裂,山体大型岩体结构面逐渐拉剪或压剪变形扩展,最终山体发生累积损伤与大规模崩滑灾害。此外,传统经验公式的计算方法对此类采矿型崩滑灾害已不适用,建议开展西南煤系地层山区地质结构与地下采动诱发崩滑灾害的相互作用关系、薄矿层采空区上部山体累积断裂损伤—岩体松动、裂隙扩展-岩溶管道流、裂隙流变化的链式响应机制、地下采动型崩滑灾害评价方法等关键科学问题的研究,以推动采矿型地质灾害防灾减灾工作的发展。     

A seismic refraction study of cretaceous oceanic lithosphere in the Northwest Pacific Basin

A seismic refraction study on old (110 Myr) lithosphere in the northwest Pacific Basin has placed constraints on crustal and uppermantle seismic structure of old oceanic lithosphere, and lithospheric aging processes. No significant lateral variation in structure other than azimuthally anisotropic mantle velocities was found, allowing the application of powerful amplitude modeling techniques. The anisotropy observed is in an opposite sense to that expected, suggesting the tectonic setting of the area may be more complex than originally thought. Upper crustal velocities are generally larger than for younger crust, supporting current theories of decreased porosity with crustal aging. However, there is no evidence for significant thickening of the oceanic crust with age, nor is there any evidence of a lower crustal layer of high or low velocity relative to the velocity of the rest of Layer 3. The compressional and shear wave velocities rule out a large component of serpentinization of mantle materials. The only evidence for a basal crustal layer of olivine gabbro cumulates is a 1.5 km thick Moho transition zone. In the slow direction of anisotropy, upper mantle velocities increase from 8.0 km s^-1 to 8.35 km s^-1 in the upper 15 km below the Moho. This increase is inconsistent with an homogeneous upper mantle and suggests that compositinal or phase changes occur near the Moho.     

海底沉积物分析测试方法标准的研究

依据海底沉积物分析测试方法标准研究的总体设计，完成了40个分析项目的21份验证报告，进行了实验室间精密度协作性检验工作，在海底沉积物CaCo3,H2Os^-，H2O^ 的分析方法研究中取得新进展，并建立了ICP－AES法测定海底沉积物中常量、微量、稀土元素分析方法。     

露天转地下采场覆岩变形破坏特征及其层厚效应研究

借助数字照相量测技术,通过相似材料模拟试验,对6.80m、11.40m两种不同矿层厚度条件下,云磷集团晋宁磷矿2#坑口露天转崩落法地下开采后采场上覆岩层的变形破坏特征及动态演化过程进行了系统研究,同时对采场覆岩变形破坏特征的层厚效应进行了探讨分析。结果表明： （1）采场覆岩变形破坏的范围与程度均随着地下采场开挖空间范围的增加而增大,其演化过程可划分为局部小范围冒顶、线性持续增大以及整体非线性剧烈垮塌3个阶段;（2）矿体层厚由6.80m增至11.40m后,采场覆岩受采动影响的范围、变形破坏的幅度及垮落角均增大,沉降曲线则由类瓢形变为类半碗型;（3）充分开采阶段后,采场覆岩的变形破坏演化过程呈现明显突发性与时间效应。相关研究结论可为矿山露转井后地压管理提供一定的理论参考。     

两项新技术及其在海水苗种生产中的应用

本文介绍了两项新技术，用泡沫净化空气、海水和生物效应灯，及其在海水苗种生产中的应用。文中分别讨论了它们的原理、设计安装及使用效果。希望这两项新技术能够得到推广，以提高出苗率，增加海水苗种生产的经济效益。     

冷空气过程对黄海东海区域海洋大气边界层结构影响的个例分析

利用一次冷空气过程的14组GPS探空数据,采用位温梯度法确定了冷空气过境前后大气边界层高度,并分析了冷空气过程对大气边界层结构的影响。结果表明：冷锋过境加大了海洋大气边界层的静力不稳定度,使边界层内对流活动增强,且锋面过后距离锋面越近的区域边界层的静力不稳定度越大;冷锋过境使边界层的平均高度升高,边界层顶处逆温梯度增大。结合ERA-Interim再分析资料,分析认为大气边界层高度与静力稳定度（海气温差）存在显著的正相关关系（相关系数达0.73）,海气温差越大,大气边界层高度越高。     

西天山那拉提构造带及邻区几个地层问题的讨论

西天山—伊宁地区以独特的结构特征和关键的大地构造部位,历来成为中外地质学家所关注、研究的重要地区,而那拉提构造带及邻区又在西天山—伊宁地区占有举足轻重的地位。由于客观条件的制约,那拉提构造带及西天山造山带在基础地质的许多方面存在不少问题,直接影响到对天山造山带和伊犁盆地的正确认识。笔者根据近十年来在那拉提带及邻区进行10个1∶5万区调填图和收集到的其它资料,对该区几个重要层位的时代、大哈拉军山火山岩系的形成背景、蛇绿岩和蓝闪片岩的产出特征以及该区的结构、构造单元划分和发展演化的动力学机制进行了讨论,其中的许多认识和看法将对该区的进一步研究产生推动作用。     

绳索取心钻进技术在松散盐岩地层中的应用探讨

地质岩心钻探中,岩心采取率一直是地质找矿、地学科研工作者重点关注的对象,也是岩心钻探重要的考核指标。传统的钻探取心方法在松散、软弱、含盐地层,特别是含易溶盐地层的取心质量不佳;绳索取心钻探在完整地层取心效果较为理想,同时可大大提高劳动生产率、降低劳动强度,而对于松散、软弱地层,其取心难度比起传统钻探有时更为复杂。通过柴达木盆地达布逊干盐湖科学钻探工程,对钻遇的地表层、松散地层如何采取技术方法提高岩心采取率进行了探索和研究。实践证明,通过改善冲洗液性能、改进取心卡簧特性及钻头出水方式3个方面技术措施,可大大提高绳索取心钻进在松散、软弱、弱固结、含盐地层的岩心采取率,由改进前的平均30%提高为平均96%。     

Field experiments of multi-channel oceanographic fluorescence lidar for oil spill and chlorophyll-a detection

A Multi-channel Oceanographic Fluorescence Lidar (MOFL), with a UV excitation at 355 nm and multiple receiving channels at typical wavelengths of fluorescence from oil spills and chlorophyll-a (Chl-a), has been developed using the Laser-induced Fluorescence (LIF) technique. The sketch of the MOFL system equipped with a compact multi-channel photomultiplier tube (MPMT) is introduced in the paper. The methods of differentiating the oil fluorescence from the background water fluorescence and evaluating the Chl-a concentration are described. Two field experiments were carried out to investigate the field performance of the system, i.e., an experiment in coastal areas for oil pollution detection and an experiment over the Yellow Sea for Chl-a monitoring. In the coastal experiment, several oil samples and other fluorescence substances were used to analyze the fluorescence spectral characteristics for oil identification, and to estimate the thickness of oil films at the water surface. The experiment shows that both the spectral shape of fluorescence induced from surface water and the intensity ratio of two channels (I ₄₉₅/I ₄₀₅) are essential to determine oil-spill occurrence. In the airborne experiment, MOFL was applied to measure relative Chl-a concentrations in the upper layer of the ocean. A comparison of relative Chl-a concentration measurements by MOFL and the Moderate Resolution Imaging Spectroradiometer (MODIS) indicates that the two datasets are in good agreement. The results show that the MOFL system is capable of monitoring oil spills and Chl-a in the upper layer of ocean water.