5－（4－羧基苯偶氮）－8－（对甲苯磺酰氨基）－喹啉与金显色反应研究及应用

以８－氨基喹啉为母体，合成了新试剂５－（４－羧基苯偶氮）－８－（对甲苯磺酰氨基）－喹啉（ＣＰＴＳＱ），研究了它与Ａｕ的显色反应，在ＣＴＭＡＢ存在下，于ｐＨ１０～１３的ＮａＯＨ介质中，ＣＰＴＳＱ与Ａｕ形成２：１紫蓝色络合物，最大吸收峰位于６１０ｎｍ，摩尔吸光系数１．０×ｌ０５Ｌ·ｍｏｌ－１·ｃｍ－１，Ａｕ含量在０～１．２ｍｇ／Ｌ内符合比尔定律。方法选择性好，灵敏度高，操作简便，已用于金矿石样品中Ａｕ的测定，结果满意。     

湖南柿竹园钨多金属矿床成矿机理的实验研究

作者在深入柿竹园钨多金属矿床野外地质工作的基础上，采用矿区燕山期花岗岩和泥盆系灰岩作为试料，在含ｐＨ＝４．０的０．３ＭＮａＣｌ＋０．７ＭＫＦ水溶液的高压釜中持续了１２０小时的交代作用。实验的结果表明了：在４００～７００℃的温度和２５０×１０５～９００×１０５Ｐａ的压力下，形成的交代岩及其钨、锡、钼、铋矿物基本上与矿区的矽卡岩及其矿石矿物共生组合相吻合，揭示了湖南柿竹园矽卡岩型钨多金属矿床成矿的机理     

高温超高压下Ni40Mn30Fe30与叶蜡石反应的研究

本文对Ｎｉ４０Ｍｎ３０Ｆｅ３０合金与在不同焙烧温度下得到的含水叶蜡，在高温超高压下的反应进行了实验研究，温度测至１４２０℃，压是至５．５ＧＰａ，研究了该反应的物质－化学机制，以及反应速率与温度，压力，含水量等参数的关系，对高压下物质迁移运动的固有特征进行了探讨。     

A Study on the Geological—Geochemical Dynamics of Hydrothermal Ore Deposition as Exemplified by the Muping—Rushan Gold Deposit Belt,Eastern Shandong,China

This paper presents a method of establishing a hydrothermal ore-forming reaction system.On the basis of the study of four typical hydrothermal deposits,the following conclusions concerning geochemical dynamic controlling during hydrothermal mineralization have been sions concerning geochemical dynaamic controlling during hydrothermal mineralization have been drawn:(1)The regional tectonic activities control the concentration and dispersion of elements in the ore-forming process in terms of their effects on the thermodynamic nature and conditions of the ore-forming reaction system.(2)During hydrothermal mineralization the activites of ore-bearing faults can be divideb into two stages:the brittle splitting stage and the brittle-tough tensing stage,which would create characteristically different geodynamic conditions for the geochemical thermodynamic ore-forming system.(3)The hydrothermal ore-forming reaaction system is an open dynamic system.At the brittle splitting stage the system was so strongly supersaturated and unequilibrated as to speed up and enhance the crystallization and differentiation of ore-forming fluids.And at the brittle-tough tensing stage,the ore-forming system was in a weak supersaturated state;with decreasing temperature and pressure the crystallization of oreforming material would show down,and it can be regarded as an equilibrated state.(4)In the lates stages of hydrothermal evolution,gold would be concentrated in the residual ore-forming solution.The pulsating fracture activite in this stage led to the crush of pyrite ore and it was then filled with gold-enriched solution,forming high-grage“fissure”gold ore.This ore-forming process could be called the coupling mechanism of ore formation.     

右江裂谷区三叠系岩石物性特征及其与金矿化的关系

本文阐述了右江裂谷区微细粒浸染型金矿床控矿层位三叠系百蓬组泥质粉砂岩及砂质泥岩的粒度，比表面、孔隙度及孔隙类型和渗透率等物性特征，讨论了与其成矿流体的循回、水岩反应及其有效浸取围岩矿物质的关系。在此基础邮成矿流体和矿矿物质主要来自于地层；由于热液躲避低势能方向迁移，造成断理解发的盆地边缘区和水下隆起周围的环状断裂带为金矿床沉淀的场所。并通过形成金矿所需热液量的估算得出，该区金矿床的形成，是由于热流     

Characteristics of dynamic equilibrium for natural gas migration and accumulation of the gas field in the center of the Ordos Basin

The gas field in the center of Ordos Basin has been conventionally considered as a large gas pool with thin reservoirs. However, lots of phenomena contrary to this concept occur in the exploration and production process. It is proposed that the gas field is composed of many small lithological gas pools, sourced from and reservoired in the same Ordovician formation which is an underpressured fluid compartment. A dynamic equilibrium moldel of natural gas migration and accumulation has been developed to illustrate the formation mechanism of these gas pools.     

山西铝土矿床成矿物质来源

山西铝土矿矿石中鲕、豆、碎屑等组构均具红土性质，结合化学成分特征、稀土元素特征、氧同住素特征、锆石等副矿物特征及含矿岩系底部岩层与下伏中奥陶纪灰岩关系和矿床分布与古陆、古岛的依赖关系等方面分析，铝土矿的成矿物质多是异源的，多为古陆上的铝硅酸盐岩红土风化产物，经流水以机械碎屑形式被搬运至海盆，沉积成矿     

地质速率计—矿物氧扩散的应用

概述了同位素封闭体系内的矿物氧扩散和同位素交换机制及其在地质速率计上的应用。火成岩从高温冷却或变质岩从高峰主质温度冷却过程中，由于冷却速度不同，扩散作用导致的矿物晶体内部及晶粒间氧同位素再平衡也有所不同。通过实测岩石中各组成矿物氧同位素比值，模式含量和颗粒半径，据矿物氧扩散和同位素交换模型，可以估算出岩石的冷却速率。     

An Algorithm for the Determination of All Significant Pathways in Chemical Reaction Systems

When the output of a complex chemical model is analysed, a typical topic isthe determination of pathways, i.e., reaction sequences, that produce ordestroy a chemical species of interest.A representative example is the investigation of catalytic ozone destruction cycles in the stratosphere.An algorithm for the automatic determination of pathways in any given reactionsystem is presented. Under the assumption that reaction rates are known, it finds all significant pathways, i.e., all pathways with a rate above a prescribed threshold.The algorithm forms pathways step by step, starting from single reactions.The chemical species in the system are consecutively considered as `branching points'.For every branching-point species, each pathway producing it is connected witheach pathway consuming it.Rates proportional to `branching probabilities' are calculated.Pathways with a rate that is smaller than a prescribed threshold arediscarded.If a newly formed pathway contains sub-pathways, e.g., null cycles, it is split into these simpler pathways.In order to demonstrate the performance of the algorithm, it has been applied to the determination of catalytic ozone destruction cycles and methaneoxidation pathways in the stratosphere.     

云南省白竹箐-阳文山NE向构造带铅锌矿成矿地质条件及找矿方向

重点分析构造带的成矿地质条件，总结地层、构造、岩浆岩与矿床的关系，认为该地区具有寻找层控及热液改造型铅锌矿的远景，并指明找矿方向，根据化探异常及矿点分布的规律，圈定了找矿靶区。