Silicate and carbonate weathering in the drainage basins of the Ganga-Ghaghara-Indus head waters: Contributions to major ion and Sr isotope geochemistry

The role of silicate and carbonate weathering in contributing to the major cation and Sr isotope geochemistry of the headwaters of the Ganga-Ghaghara-Indus system is investigated from the available data. The contributions from silicate weathering are determined from the composition of granites/ gneisses, soil profiles developed from them and from the chemistry of rivers flowing predominantly through silicate terrains. The chemistry of Precambrian carbonate outcrops of the Lesser Himalaya provided the data base to assess the supply from carbonate weathering. Mass balance calculations indicate that on an average ∼ 77% (Na + K) and ∼ 17% (Ca + Mg) in these rivers is of silicate origin. The silicate Sr component in these waters average ∼40% and in most cases it exceeds the carbonate Sr. The observations that (i) the⁸⁷Sr/⁸⁶Sr and Sr/Ca in the granites/gneisses bracket the values measured in the head waters; (ii) there is a strong positive correlation between⁸⁷Sr/⁸⁶Sr of the rivers and the silicate derived cations in them, suggest that silicate weathering is a major source for the highly radiogenic Sr isotope composition of these source waters. The generally low⁸⁷Sr/⁸⁶Sr (< 0.720) and Sr/Ca (∼ 0.2 nM/ μM) in the Precambrian carbonate outcrops rules them out as a major source of Sr and⁸⁷Sr/⁸⁶Sr in the headwaters on a basin-wide scale, however, the high⁸⁷Sr/⁸⁶Sr (∼ 0.85) in a few of these carbonates suggests that they can be important for particular streams. The analysis of⁸⁷Sr/⁸⁶Sr and Ca/Sr data of the source waters show that they diverge from a low⁸⁷Sr/⁸⁶Sr and low Ca/Sr end member. The high Ca/Sr of the Precambrian carbonates precludes them from being this end member, other possible candidates being Tethyan carbonates and Sr rich evaporite phases such as gypsum and celestite. The results of this study should find application in estimating the present-day silicate and carbonate weathering rates in the Himalaya and associated CO₂ consumption rates and their global significance.     

新型知识观下高校旅游管理专业课程知识的构建思考

旅游管理专业是1998年新设置的高校本科专业,受学科专业特点和旅游职业需求的影响,其课程知识与传统的学科专业相比,具有很强的实践性.为此,其课程知识的构建,需要深入认识旅游管理专业课程知识的特点,建立起"科学-人本观"的构建价值取向,并充分唤醒教学参与者的主体意识,发挥课堂对课程知识的构建作用.     

An experimental study on major element release from the sediments in the Changjiang (Yangtze River) Estuary

With the enhanced warming and acidification of global ocean, whether and to what extent the naturally-weathered fluvial sediment into the sea can release elements and thus influence the geochemical pro...     

高应变法在判定大直径灌注桩缺陷中的应用

测试数据准确可靠的高应变法检测,能够定量分析基桩缺陷,准确判定缺陷位置。通过工程桩的低应变法和高应变法对桩身完整性判定分析的工程实例,结合钻芯法验证,总结高应变法在不同情况下对桩身完整性的评定。     

水环境数学模拟的应用现状及存在问题

水环境中污染物的迁移转化过程模拟和预测是水生态环境健康诊断、预测、预警及控制管理的重要基础。水环境数学模拟已经在国内外有了非常广泛的应用,并且成为国内外学者研究的热点。本文介绍了水环境数学模型的基础研究和应用现状,并提出其发展趋势和国内水质数学模型存在的主要问题。     

月球的化学演化

月球是一个发生了化学分异的星球,它由月壳、月幔±一个小的金属月核组成。大量观察事实显示月球曾经有过岩浆洋,岩浆洋的结晶分异主导了月球的化学演化。目前主流观点认为,月球是在太阳系演化的早期,至少45亿年前,一个火星大小的星球,与即将完成原始吸积的地球胚胎发生偏心撞击,造成地球的熔融,形成岩浆洋,飞溅出来的物质迅速吸积形成绕地球运动的月球,并且在月球上形成了全球规模的岩浆洋,进而发生了结晶分异。,由于月球上没有海洋和板块俯冲,岩浆洋分异是其化学演化的主要途径。月球岩浆洋的80％～85％在大撞击后的100Ma内已经固化,这可能是由于月球体积小、表面没有大气包裹所致。月球极贫水,因此在岩浆结晶过程中斜长石首先结晶。斜长石由于密度小于玄武质岩浆而漂浮在岩浆洋的表层,橄榄石等密度大的矿物则堆积在岩浆洋的底部。随着结晶分异的进行,残余岩浆不断富集不相容元素,包括K、U等放射性元素;与此同时,密度较大的钛铁矿开始结晶,造成高钛堆晶岩密度大于其下的橄榄石堆晶岩的不稳定结构,进而发生月幔翻转,引发一系列岩浆活动,进而形成月球上特有的镁质系列、碱质系列等岩石。由于月球氧逸度较低,Eu主要以＋2价形式存在,因此斜长石高度富集Eu,相应地除高地斜长岩外,其他岩石均表现为Eu高度亏损的特点。与此同时,Re在低氧逸度下表现为强亲铁元素的特点,Re／Os在月球岩浆过程中不发生分异。月球的体积远小于地球,因而其演化时间远远短于地球,很多原始的分异被完整地保留下来。因此月球的化学演化是类地行星早期演化过程的“化石”,尽管与现代的地球存在较大差异,但是对于认识地球早期演化具有借鉴意义。     

Calcium,Na, K and Mg Concentrations in Seawater by Inductively Coupled Plasma‐Atomic Emission Spectrometry: Applications to IAPSO Seawater Reference Material,Hydrothermal Fluids and Synthetic Seawater Solutions

We report a measurement procedure to determine simultaneously the major cation concentrations (Na, Ca, K and Mg) of seawater‐derived solutions by inductively coupled plasma‐atomic emission spectrometry. The best results were obtained when the IAPSO (‘standard’) seawater reference material was diluted by thirty times with Milli‐Q^® water. We obtained an average reference value r_K (the ratio of the mass fraction of potassium to that of chlorine, i.e., (g kg^?1)/(g kg^?1)) for IAPSO seawater of 0.0205 ± 0.0006 (2.9% RSD), not significantly different from 0.0206 ± 0.0005 (2.4% RSD) for seawater composition reported in the literature. The measured Na, Ca and Mg concentrations correspond to r_Na, r_Ca and r_Mg values of 0.5406 ± 0.0026 (0.5% RSD), 0.02192 ± 0.00048 (2.2% RSD) and 0.06830 ± 0.00047 (0.7% RSD), respectively, in line with previous values measured by wet‐chemistry and atomic absorption spectrophotometry or wet‐chemical titration. Our measurement procedure was used successfully on synthetic seawater solutions and high‐temperature hydrothermal fluids.     

淮南煤田潘三煤矿4-2煤中矿物对岩浆侵入的响应

以淮南煤田潘三煤矿4-2煤层中的岩浆岩、天然焦和煤样品为研究对象,利用X射线衍射仪和X射线荧光光谱仪测试其矿物组成和主量元素含量,研究地下岩浆侵入对煤中矿物成分的影响。结果表明:煤变质成天然焦后,其总的矿物含量增多,并伴随着后生矿物如微斜长石和镁绿泥石的出现。天然焦中后生矿物的组成元素可能来源于岩浆或热液中的主量元素如Si、Al、Na、K、Fe和Mg。     

基于主体功能区的京津冀城市群碳收支时空分异与碳补偿分区

从主体功能区划视角研究碳收支和碳补偿分区,对于制定适应各主体功能区低碳发展策略,推动区域生态环境协同治理,实现高质量发展具有重要意义,也是地理学思想对于实现“双碳”目标的重要贡献。本文首先构建主体功能区视角下碳收支与碳补偿的理论框架,然后以京津冀城市群157个县级单元为研究区,引入集中化指数、标准显性比较优势指数、SOM-K-means聚类等方法研究功能区视角下京津冀城市群碳收支时空分异与碳补偿分区,并提出以低碳发展为导向的碳减排空间优化方案。结果表明：① 2000—2017年京津冀城市群碳收支量呈现波动上升态势,其集中化指数均高于0.4的“警戒线”,碳收支地区差异整体偏大。② 碳收支时空分异显著,碳排放高值区呈现以京津唐为中心,向外逐步降低的“核心—外围”空间格局;而碳吸收空间格局趋于稳定,总体呈现东、北、西部高,而中、南部低的倒“U”型格局。③ 京津冀城市群碳收支与主体功能区战略定位较为吻合,优化开发区和重点开发区是碳排放的主要承压区,而重点生态功能区是碳吸收的优势主导区,各功能区碳吸收集中化指数差别较碳排放集中化指数小。④ 京津冀城市群共有53个支付区、64个平衡区和40个获补区,结合主体功能区规划战略目标,最终形成9类碳补偿空间优化区,并提出每一类型区低碳发展方向及策略。⑤ 未来要加强更微观尺度的碳收支及碳补偿研究,丰富和完善碳补偿理论框架,将碳补偿融入到碳交易市场,探索实现“双碳”目标的多元化路径。