基于非均质地层参数表征的颗粒流模型构建

非均质地层参数的获取与表征方法是浅层地质体改造的重要依据。基于非均质地层的地质建模,表征具有随机不确定性和模糊不确定性的土体表观参数和物理力学参数。利用 Weibull 分布统计描述局部地层信息,并应用Diamond-Square分形插值方法,结合差分盒子维计算非均质地层分形维数,进一步合理演算整体地层参数。采用PFC3D数值模拟软件,结合马尔科夫链蒙特卡洛方法采样数据,对非均质地层块石颗粒及土颗粒进行建模。通过非均质地层模拟结果,发现其破坏过程与应力应变曲线要比均质土体复杂得多,由于块石大颗粒的含量、分布特性对土样力学性质影响显著。本文建模方法有助于非均质地层参数表征研究。     

模糊ISODATA聚类算法在声速剖面自动分类中的应用

依据中国海浅海区30′按月历史统计声速剖面数据,通过归一化处理和Akima差值采样得到梯度剖面,建立起各方区按月归化后的声速剖面分层梯度样本集,并采用模糊ISODATA聚类算法对声速剖面进行聚类分析.通过对分类结果和类内总方差和的分析表明,聚类参数m值在1.1～2.1之间,并以最远邻系统聚类法结果为初始类中心的模糊分类效果较好.应用该方法对海洋中的声速剖面进行自动分类和区划对海洋环境的战术应用意义重大.     

鄂尔多斯盆地白垩系主要含水岩组沉积岩相古地理对地下水水化学场形成和水质分布的影响

通过典型水文钻孔和露头剖面沉积地质、水文地质调查、样品测试及综合研究表明,鄂尔多斯盆地白垩系含水层形成时,北部环河组、洛河组均广泛发育河流相沉积,而南部环河组湖泊相为主、洛河组沙漠沙丘相广泛分布的沉积古地理格局,这对含水岩石中长石、粘土矿物、方解石、石膏等重要矿物组成和易溶盐含量及其空间分布形成明显控制,也控制了含水层和隔水层空间分布,并显著影响了深层地下水循环交替条件的区域分布变化。在沉积-成岩环境条件下,影响地下水水化学场形成和水质分布变化的主要水-岩作用包括硫酸盐、碳酸盐及硅酸盐矿物的溶解溶滤和阳离子交换作用等水文地球化学作用。受含水层沉积岩相古地理、地下水循环及水岩作用等因素控制,环河组、洛河组地下水总体表现为盆地北区TDS低、淡水发育、以HCO₃型为主,南区TDS高、微咸水和咸水发育、以HCO₃·SO₄型为主的分布规律,地下水水化学和水质分布在北区分布变化小、在南区上下含水层分布变化复杂。     

A mapping of the electron localization function for the silica polymorphs: evidence for domains of electron pairs and sites of potential electrophilic attack

The electron localization function, η, evaluated for first-principles geometry optimized model structures generated for quartz and coesite, reveals that the oxide anions are coordinated by two hemispherically shaped η-isosurfaces located along each of the SiO bond vectors comprising the SiOSi angles. With one exception, they are also coordinated by larger banana-shaped isosurfaces oriented perpendicular to the plane centered in the vicinity of the apex of each angle. The hemispherical isosurfaces, ascribed to domains of localized bond-pair electrons, are centered ～0.70 Å along the bond vectors from the oxide anions and the banana-shaped isosurfaces, ascribed to domains of localized nonbonding lone-pair electrons, are centered ～0.60 Å from the apex of the angle. The oxide anion comprising the straight SiOSi angle in coesite is the one exception in that the banana-shaped isosurface is missing; however, it is coordinated by two hemispherically shaped isosurfaces that lie along the bond vectors. In the case of a first-principles model structure generated for stishovite, the oxide anion is coordinated by five hemispherically shaped η-isosurfaces, one located along each of the three SiO bond vectors (ascribed to domains of bonding-electron pairs) that are linked to the anion with the remaining two (ascribed to domains of nonbonding-electron pairs) located on opposite sides of the plane defined by three vectors, each isosurface at a distance of ～0.5 Å from the anion. The distribution of the five isosurfaces is in a one-to-one correspondence with the distribution of the maxima displayed by experimental Δρ and theoretical ??²ρ maps. Isosurface η maps calculated for quartz and the (HO) ₃ SiOSi(OH) ₃ molecule also exhibit maxima that correspond with the (3,?3) maxima displayed by distributions of ??²ρ. Deformation maps observed for the SiOSi bridges for the silica polymorphs and a number of silicates are similar to that calculated for the molecule but, for the majority, the maxima ascribed to lone-pair features are absent. The domains of localized nonbonding-electron pair coordinating the oxide anions of quartz and coesite provide a basis for explaining the flexibility and the wide range of the SiOSi angles exhibited by the silica polymorphs with four-coordinate Si. They also provide a basis for explaining why the SiO bond length in coesite decreases with increasing angle. As found in studies of the interactions of solute molecules with a solvent, a mapping of η-isosurfaces for geometry-optimized silicates is expected to become a powerful tool for deducing potential sites of electrophilic attack and reactivity for Earth materials. The positions of the features ascribed to the lone pairs in coesite correspond with the positions of the H atoms recently reported for an H-doped coesite crystal.     

VERTICAL DISTRIBUTION CHARACTERISTICS OF ATMOSPHERIC AEROSOLS IN LIAONING*

16 aircraft missions were conducted for the measurement of atmospheric aerosols in separate days of late spring and early summer of 1996 and 1997.The paper deals with detailed analysis of the variation in vertical/horizontal distributions of the concentration of the particles and their size distribution at 0-5 km above ground,and with the relations to temperature and relative humidity documented in general.Evidence suggests that the concentrations show different distribution features in vertical above and below the cap of the mixed layer:the particle size distribution is subject to a range of forming mechanisms,displaying a multi-modal pattern:the horizontal concentration experiences remarkable variation:temperature and relative humidity stratifications have conspicuous influence on the concentration and size distribution of aerosols.     

罗源湾水母类的生态研究

样品于1986年11月至1987年10月在福建省罗源湾10个站位采集。经鉴定有52种水母。它们可分为沿岸暖水、沿岸暖温和大洋广布三种生态类群。水母类总数量和种类数的季节分布呈单周期,两者高峰均出现在7月。低谷分别出现于11月和1月。在平面分布上,以拟细浅室水母Lensia subtiloides占优势的月份,数量从湾口向湾顶递减,而以球型侧腕水母Pleurobrachia globosa占优势的月份,数量却递增。文中还讨论了水母类的分布和环境因素的关系。     

珠江三角洲软土微结构的定量研究

对用不同长度的PVC管在珠海和广州两地采得的淤泥样柱施于一定荷载，然后在扫描电镜下研究软土受压后在样柱垂深方向上的微结构变化，并将样品的微结构照片扫描，在计算机内进行量化处理。结果表明，样品的孔隙分布分维差随着离施压点距离的增加而逐渐减小，从而得到两者的关系方程。据此，可了解在一定荷载下应力在软土层中向下的衰减趋势。文章还对软土的天然含水量和围压对压缩变形的影响作了初步的讨论。     

Size Distributions and Elemental Compositions of Particulate Matter on Clear, Hazy and Foggy days in Beijing, China

Total suspended particulates(TSP)samples were collected using low pressure impactors(Andersen Series 20-800,USA)on typical clear,hazy and foggy days in Beijing in order to investigate the characteristics of size distributions and elemental compositions of particulate matter(PM)in different weather conditions. The concentrations of sixteen elements,including Na,Mg,Al,K,Ca,Mn,Fe,Ni,Cu,Zn,As,Se,Cd,Ba,Tl and Pb were detected using inductively coupled plasma mass spectrometry(ICP-MS).The results showed that Ca,Al,Fe,Mg and Ba on foggy days were 2.0-2.6 times higher than on clear days,and 2.3-2.9 times higher than on hazy days.Concentrations of Cu,Zn,As,Se and Pb on foggy days were 163.5,1186.7,65.9,32.0 and 708.2 ng m-3,respectively,in fine particles,and 68.1,289.5,19.8,1.6 and 103.8 ng m-3,respectively,in coarse particles.This was 1.0-8.4 times higher and 1.4-7.4 times higher than on clear and hazy days,respectively.It is then shown that Mg,Al,Fe,Ca and Ba were mainly associated with coarse particles,peaking at 4.7-5.8μm;that Cd,Se,Zn,As,Tl and Pb were most dominant in fine particles,peaking at 0.43-1.1μm;and that Na,K,Ni,Cu and Mn had a multi-mode distribution,with peaks at 0.43-1.1μm and 4.7-5.8μm.The enrichment factors indicated that coal combustion along with vehicle and industry emissions may be the main sources of pollution elements.     

黑河实验区地表植被指数的区域分布及季节变化

利用具有较高空间分辨率的Ｌａｎｄｓａｔ ＴＭ卫星资料估算了黑河实验区夏季和近冬季地表标准化差值植被指数ＮＤＶＩ,分析了ＮＤＶＩ的区域分布特征和季节变化。结果表明,由于该实验区下垫面的复杂性,ＮＤＶＩ表现出明显的空间和季节变化,ＮＤＶＩ的图像能够很好地反映出地表植被的分布状况。     

威海荣成桑沟湾海域海草床分布现状及其生态特征

海草床是生物圈最高产的生态系统之一,在氮捕获、碳封存、水质净化及维持生物多样性等方面发挥关键作用。2016年8月通过对威海荣成桑沟湾海域的现场调查,发现分布总面积约为471.72 ha的海草床,种类为鳗草(Zostera marina)、红纤维虾形草(Phyllospadix iwatensis)、日本鳗草(Zostera japonica)和丛生鳗草(Zostera caespitosa),分布面积分别为395.33 ha、37.28 ha、32.74 ha和6.37 ha。鳗草分布范围较广,平均茎枝密度817.0±27.6 shoots/m²,平均生物量646.6±41.8 g DW/m²;红纤维虾形草主要分布于桑沟湾北部养殖池和南部楮岛海域,平均茎枝密度2649.0±29.8shoots/m²,平均生物量2 381.3±27.3 g DW/m²;日本鳗草主要分布于桑沟湾西部八亩地海域,平均茎枝密度506.0±26.2 shoots/m²,平均生物量118.3±12.5 g...