离子色谱法同时测定天然碱矿中氯离子和硫酸根离子

通过测定氯离子和硫酸根离子可以确定天然碱矿中石盐和芒硝的含量,目前分析方法比较少,且流程冗长,容易污染,生产效率低。本文建立了离子色谱-抑制电导法测定天然碱矿中氯离子和硫酸根的分析方法。样品中水溶性阴离子经热水溶解进入溶液,以30 mmol/L氢氧化钾溶液作为淋洗液,利用AG19阴离子保护柱、AS19阴离子分离柱分离样品中的氯和硫酸根,CRD 200碳酸盐消除装置去除了碳酸根的干扰。方法检出限氯离子为0.01 mg/L,硫酸根为0.02 mg/L;加标回收率为100.9%～104.1%;精密度(RSD,n=10)小于2.5%。实际样品分析结果与滴定法的测定值基本吻合。本法操作简单,重现性好,灵敏度高,结果可靠,不受样品复杂组分及形成缓冲溶液体系的干扰,很好地解决了传统方法费时、耗材、不能同时测定氯离子和硫酸根的问题。     

Processes on the Thermodynamic?Properties?of?Lithium?Borates

正1 Introduction Lithium and its compounds as national strategic resources are extensively used in national defense,industrial and agricultural production.As we know,the salt lakes in the western of China are famous for its high     

New Extraction System for Lithium from Brine with High Magnesium Content

正Lithium is an important element with a wide variety of applications,especially in lithium ion batteries and in the exploration of nuclear energy.Salt lake brine is the most abundant lithium source available in world,comp-rising70%~80%of all known lithium deposits.Lithium can be abstracted from brines with low magnesium content and processed into kinds of lithium compound in Atacama and Hombre Muerto of South America(Nie et al.,2013).     

Atmospheric deposition of nitrogen, sulfur and chloride in Thessaloniki, Greece

In the present study, the wet and dry depositions of particulate NO₃⁻, SO₄²⁻, Cl⁻ and NH₄⁺ were measured using a wet/dry sampler as a surrogate surface. Gas phase compounds of nitrogen, sulfur and chloride (HNO₃, NH₃, SO₂ and HCl) were measured by an annular denuder system (ADS) equipped with a back up filter for the collection of particles with diameter ≤ 5 μm. Ambient concentrations of NO, NO₂ and SO₂ were also taken into consideration. Sampling was conducted at an urban site in the center of the city of Thessaloniki, northern Greece. The presence of the aerosol species was examined by cold/warm period and the possible compounds in dry deposits were also considered. Dry deposition fluxes were found to be well correlated with ambient particle concentrations in order to be used for the calculation of particle deposition velocity. Average particulate deposition velocities calculated were 0.36, 0.20, 0.20 and 0.10 cm s^− 1 for Cl⁻, NO₃⁻, SO₄²⁻ and NH₄⁺, respectively. Total dry deposition fluxes (gas and particles) were estimated at 3.24 kg ha^− 1 year^− 1 for chloride (HCl + p-Cl), 9.97 kg ha^− 1 year^− 1 for nitrogen oxidized (NO + NO₂ + HNO₃ + p-NO₃), 5.32 kg ha^− 1 year^− 1 for nitrogen reduced (NH₃ + p-NH₄) and 15.77 kg ha^− 1 year^− 1 for sulfur (SO₂ + p-SO₄). 70–90% total dry deposition was due to gaseous species deposition. The contribution of dry deposition to the total (wet + dry) was at the level of 60–70% for sulfur and nitrogen (oxidized and reduced), whereas dry chloride deposition contributed 35% to the total. The dry-to-wet deposition ratio of all the studied species was found to be significantly associated with the precipitation amount, with nitrogen species being better and higher correlated. Wet, dry and total depositions measured in Thessaloniki, were compared with other countries of Europe, US and Asia.     

八所港矿砂码头混凝土腐蚀现状分析

针对海南八所港矿砂码头服役近30年的混凝土梁、柱和70年的甬道等结构腐蚀状况进行现场调研,发现钢筋混凝土结构出现钢筋锈蚀、混凝土剥落,部分混凝土严重破损。测量了其混凝土梁、柱、甬道等不同位置混凝土和铁锈中氯离子含量,分析了局部环境对氯离子分布的影响。根据调研结果总结分析了其破损原因。结果表明混凝土中氯离子分布呈现规律性变化,且铁锈中的氯离子含量远小于混凝土中氯离子含量。     

Application of chloride profile and water balance methods in estimating groundwater recharge in Luanjing Irrigation Area,Inner Mongolia / Application des méthodes du profil de chlorure et du bilan hydrique pour l'estimation de la recharge hydrogéologique dans le Périmètre Irrigué de Luanjing,Mongolie Intérieure

Abstract

A study was carried out to investigate the use of the chloride profile method in conjunction with the water balance method to estimate the annual groundwater recharge in both natural and irrigation sites in Luanjing Irrigation Area, Inner Mongolia. Groundwater recharge from precipitation, estimated by the chloride profile method, is less than 0.1 mm year^?1 which accounts for just 0.06% of the long-term average annual rainfall, indicating that rainfall presently plays a minor role in the groundwater recharge. It appears that recharge events only occurred after heavy rain or sustained rainfall events. In the cropped area, the chloride profile method indicated that the average annual recharge is 268 mm year^?1 with an infiltration rate of 32.5%, which is reasonably consistent with the 33.1% obtained by the water balance method in 2007. The study shows that about one third of that water is discharged back to the groundwater.     

拉萨地块西段中新世赛利普超钾质火山岩富集地幔源区和岩石成因:Li同位素制约

作为一种“非传统稳定同位素”,锂同位素地球化学研究已经成为近年来国际上研究的热点之一.文章成功应用锂同位素对青藏高原西南部赛利普超钾质火山岩进行了示范研究.研究表明,赛利普超钾质火出岩的w(Li)为11.2×10-6～22.9× 10-6,同位素组成δ7Li为1.2‰～+3.5‰,平均值为0 2‰,与平均上地壳的相当.超钾质火山岩的锂同位素组成与岩浆结晶分异程度参数之间不存在任何相关性,这表明在超钾质火山岩结晶分异过程中没有发生明显的锂同位素分馏,锂同位素组成特征反映了其形成时的源区特征.超钾质火山岩的锂同位素组成变化范围达4.7‰,并且与pb-Sr-Nd同位素和岩浆结晶分异参数之间亦无任何相关性,表明锂同位素异常可能反映了不均匀源区岩石特征.通过计算模拟以及与前人的类似研究成果进行对比,笔者认为俯冲印度地壳而不是特提斯洋壳(包括沉积物)的流体/熔体参与了超钾质火山岩的源区富集,并在此基础上提出了超钾质火山岩成因模式.     

A brief review of isotopically light Li – a feature of the enriched mantle?

Lithium isotope geochemistry is increasingly being used to trace deep-earth processes, reflecting the observed large variation of Li isotope ratios in mantle-derived rocks, including peridotite xenoliths associated with ancient continents. We briefly review the Li isotopic compositions of major geochemical reservoirs, the assumed mechanisms of Li isotopic fractionation, and, in particular, the origins of isotopically light Li in mantle-derived rocks based on the latest developments in Li isotope geochemistry. Comparison of Li isotope data with existing Sr-Nd isotope ratios reflects the subduction-recycling of ancient oceanic crust and the reappearance of Li in volcanic rocks. This circulation may play an important role in generating the isotopically light-Li component in the mantle – perhaps the enriched mantle end member defined by the Sr-Nd isotopic compositions of oceanic basalts.     

海水环境下钢筋混凝土人工鱼礁的耐久性寿命预测

根据人工模拟的流动海水环境(流速约为0.15m/s)下的混凝土侵蚀试验测得的混凝土中氯离子质量分数,分别测定了腐蚀350,380,400d后混凝土的氯离子扩散系数,并计算和预测了混凝土人工鱼礁的耐久性寿命。研究结果表明:氯离子在混凝土人工鱼礁中的扩散规律基本上遵循Fick第二定律;钢筋混凝土人工鱼礁的耐久性寿命与保护层厚度的平方成正比;海水盐度对混凝土人工鱼礁的耐久性寿命影响较大。     

氯盐和冻融循环复合作用对深埋公路隧道安全性能的影响

对氯盐和冻融循环复合作用后Ⅳ级围岩中埋深为30 m的隧道,运用同济曙光软件建立荷载-结构法拉压弹簧模型进行分析计算,该荷载-结构模型在拱顶152°范围内设置拉弹簧,其余部位设置压弹簧,计算表明：随着环向裂缝宽度（钢筋锈蚀程度的增加）以及纵向裂缝深度的增加,隧道安全性能逐渐降低;衬砌具有相同钢筋锈蚀程度和纵向裂缝深度时,拱顶处病害比拱腰处病害对隧道安全性能的影响大;当环向裂缝宽度小于0.2 mm时,环向裂缝宽度的变化对隧道衬砌安全性能影响不大。