Predictions of the electrical conductivity and charging of the aerosols in Titan's atmosphere

The electrical conductivity and electrical charge on the aerosols in atmosphere of Titan are computed for altitudes between 0 and 400 km. Ionization of methane and nitrogen due to galactic cosmic rays (GCR) is important at night where these ions are converted to ion clusters such as CH⁺₅CH₄, C₇H⁺₇, C₄H⁺₇, and H₄C₇N⁺. The ubiquitous aerosols observed also play an important role in determining the charge distribution in the atmosphere. Because polycyclic aromatic hydrocarbons (PAHs) are expected in Titan's atmosphere and have been observed in the laboratory and found to be electrophilic, we consider the formation of negative ions. During the night, the very smallest molecular complexes accept free electrons to form negative ions. This results in a large reduction of the electron abundance both in the region between 150 and 350 km over that predicted when such aerosols are not considered. During the day time, ionization by photoemission from aerosols irradiated by solar ultraviolet (UV) radiation overwhelms the GCR-produced ionization. The presence of hydrocarbon and nitrile minor constituents substantially reduces the UV flux in the wavelength band from the cutoff of CH₄ at 155 to 200 nm. These aerosols have such a low ionization potential that the bulk of the solar radiation at longer wavelengths is energetic enough to produce a photoionization rate sufficient to create an ionosphere even without galactic cosmic ray (GCR) bombardment. At altitudes below 60 km, the electron and positive ion abundances are influenced by the three-body recombination of ions and electrons. The addition of this reaction significantly reduces the predicted electron abundance over that previously predicted. Our calculations for the dayside show that the peaks of the charge distributions move to larger values as the altitude increases. This variation is the result of the increased UV flux present at the highest altitudes. Clearly, the situation is quite different than that for the night where the peak of the distribution for a particular size is nearly constant with altitude when negative ions are not present. The presence of very small aerosol particles (embryos) may cause the peak of the distribution to decrease from about 8 negative charges to as little as one negative charge or even zero charge. This dependence on altitude will require models of the aerosol formation to change their algorithms to better represent the effect of charged aerosols as a function of altitude. In particular, the charge state will be much higher than previously predicted and it will not be constant with altitude during the day time. Charging of aerosol particles, whether on the dayside or nightside, has a major influence on both the electron abundance and electrical conductivity. The predicted conductivities are within the measurement range of the HASI PWA instrument over most but not all, of the altitude range sampled.     

饱和指数法在地下热水化学研究中的应用

本文利用饱和指数法对陕西蓝田汤峪2号孔的地下热水化学分析资料进行了系统处理,绘制出了该孔热水的SI—T曲线和SI—pH曲线。由曲线图上确定出了汤峪2号孔热水与深部围岩矿物达到溶解平衡时的温度为87℃;平衡时水的pH值为8.52;参与平衡的矿物为低钠长石、玉髓、镁绿泥石、浊沸石和微斜长石。同时还判断出,在热水由深部热储上升到地表的过程中,大约有47.37％的低矿化度水混入。     

Factors controlling the major ion chemistry of streams in the blue ridge and valley and ridge physiographic provinces of Virginia and Maryland

The factors controlling the chemistry of 69 low-order streams in the Blue Ridge and Valley and Ridge physiographic provinces of Virginia and Maryland were studied over a 13-month period. Principal component analysis was used to examine regional patterns in stream chemistry and to examine the degree to which the chemistry of low-order streams is controlled by the bedrock upon which they flow. Streams clustered into regionally isolated groups, strongly related to bedrock type, with SO^2?₄ and HCO^?₃ the chemical variables of most importance. Sulphate concentrations appear to be strongly controlled by climate and hydrology, and sorption in the soils within the watershed. Much of the atmospherically derived SO^2?₄ accumulates in watersheds during the growing season and is later flushed out. Weathering reactions were found to be particularly important in the production of HCO^?₃, accounting for 91 per cent on an annual basis, and export of divalent cations from these watersheds, accounting for 48–50 per cent on an annual basis. About half of non-anthropogenic Na⁺ was derived from weathering of silicates, whereas nearly all K⁺ was identified with leaching by SO^2?₄. Water chemistry was strongly related to the rock type in the watershed and the weatherability of the component minerals. Rock type is not a randomly distributed function; instead, it is controlled by geologic factors that result in clusters of similar rock types in a given region. When planning large synoptic studies, it is extremely important to consider that a sampling scheme based on random sampling of a non-randomly distributed function May, not provide the most accurate representation of the variables of interest. Instead, a hierarchical sampling scheme May, be indicated. Our results also suggest that, although one sample in time May, be sufficient to characterize the primary geochemical factors controlling stream chemistry throughout the year, it May, not be sufficient to detect subtle, flow-related alterations in chemistry.     

Effects of wildfire and logging on streamwater chemistry and cation exports of small forested catchments in Southeastern New South Wales,Australia

In January 1979 four experimental catchments in forests of southeastern New South Wales were burnt by wildfire. Logging before the fire had no detectable effect on concentrations of Ca, K, Mg, Na, Cl, NO₃, nor on pH of stream waters. In all burnt catchments mean K concentrations increased by from 20 per cent to 60 per cent for a 12 month period and nitrate concentrations increased by factors of about ten in severely burnt catchments. In one of the catchments (unlogged) Ca also increased. From one year to four years after the fire, concentrations of all ions were either close to or less than levels predicted from the control but, during the fifth and sixth years, concentrations of Mg and Na were higher by 20 per cent to 60 per cent. In all burnt catchments, cation exports increased considerably during the first three years after the fire but major components of these increases were elevated levels of runoff. Exports of Mg and Na were higher than those of the control during the fifth and sixth years after the fire, although runoff had returned to pre-fire levels in the two unlogged catchments and was 10 per cent to 20 per cent greater than the control in the two logged catchments. During this final period, increased ion concentrations were the main factors which contributed to the elevated exports. Post-fire logging in one catchment had no detectable effects on streamwater parameters measured in the study but was associated with a further increase in runoff.     

Significance of atmospheric fallout on the upper layer water chemistry of the North-Western Mediterranean

The atmospheric input is established for almost forty trace and major elements at a coastal site on the North-Western Mediterranean. Comparison with the Rhône River input at the scale of the Gulf of Lions shows that the total atmospheric input dominates for elements of anthropogenic origin such as Cd, Pb, Sb and Zn. Dissolved input of atmospheric origin is very important for these elements and for those of terrigenous origin (Al and Fe). In the coastal zone, both dissolved external sources (atmosphere and Rhône River) can explain the high Mediterranean Surface waters concentrations. Atmospheric input becomes rapidly the predominant factor, while the riverine influence being negligible in the few tens' kilometers outside the river mouth.Paper submitted to the 7th International Symposium of the Commission for Atmospheric Chemistry and Global Pollution on the Chemistry of the Global Atmosphere held in Chamrousse, France, from 5 to 11 September 1990.     

Metamorphic and post-metamorphic fluid flow in the low-grade rocks of the Harlech Dome, north Wales

A combination of fluid inclusion, stable isotope and geochemical techniques has been used to study the nature of fluids present and their behaviour during Caledonian low-grade metamorphism of the Harlech Dome, north Wales. Fluid inclusion studies show that in most of the metasedimentary sequence the peak metamorphic fluid was an aqueous Na–K–Cl brine but in the graphitic Clogau Formation and in parts of the overlying Maentwrog Formation immiscible H₂O-rich and CH₄-rich fluids coexisted. Late-stage inclusions are of calcium-rich brine and a dilute aqueous fluid. The chemical composition of chlorite in metamorphic veins and rocks varies between different formations and quartz-oxygen isotopic compositions show considerable variation between different units. Both of these features are taken to indicate that there was little or no pervasive movement of fluid between different units at the peak of metamorphism. After the metamorphic peak there was focused flow of fluid upward through the sequence along fractures, in response to end-Caledonian uplift and unloading. Where the migrating fluid crossed the graphitic shales, interaction between the fluid and the shales gave rise to the formation of the auriferous veins of the Dolgellau Gold Belt. Subsequent to this mineralizing event there was widespread development of ¹⁸O-enriched calcites and micas. In the case of vein minerals it is possible that these crystallized directly from late-stage fluids at lower temperature than the quartz in the same veins. Alternatively, the original vein minerals may have re-equilibrated with later ¹⁸O-enriched or cooler fluid. In the case of muscovites in the rock matrix it is proposed that the isotopically heavy compositions are the result of re-equilibration of initially light grains with an introduced fluid, requiring considerable influx of fluid. This event may relate to either of two late-stage fluids observed as inclusions.     

Analysis of storm run-off sources using oxygen-18 in a headwater swamp

A combination of hydrometric data and observations of natural isotope (oxygen-18) variations in saturation overland flow and stream discharge were used to investigate the sources of storm run-off in a headwater swamp located in a permanent groundwater discharge zone near Toronto, Canada. The results of a two-component hydrograph separation indicated that pre-event water formed 80–90% of the stream hydrograph volume for six of the seven storms analyzed in June–November 1990. However, the instantaneous event water contribution showed considerable variability, ranging from maximum values of 20–25% for four moderate intensity storms to 63% for a high intensity thunderstorm with a return period of two years. The relative contribution of event and pre-event water to storm run-off from saturated areas and small streamlets within the swamp was similar to the main outlet stream. The dominance of pre-event water during storms could be accounted for by the mixing of a small volume of event water with a large pool of pre-event water on the surface of permanently saturated areas within the swamp. Occasional storms of high intensity or long duration produced a greater shift towards an event water signature in the saturated areas and a larger event water contribution to the outlet stream hydrograph.     

Influence of mineral weathering reactions on the chemical composition of soil water,Springs, and ground water,Catoctin Mountains,Maryland

During 1983 and 1984, wet precipitation was primarily a solution of dilute sulphuric acid, whereas calcium and bicarbonate were the major ions in springs and ground water in two small watersheds with a deciduous forest cover in central Maryland. Dominant ions in soil water were calcium, magnesium, and sulphate. The relative importance of mineral weathering reactions on the chemical composition of these subsurface waters was compared to the contribution from wet precipitation, biological processes, and road deicing salts. Mineral reaction models, developed from geochemical mass-balance relationships, involved reactions of primary and secondary minerals in metabasalt and metarhyolite with hydrogen ion. Geochemical weathering reactions account for the majority of total ion equivalents in soil water (46 per cent), springs (51 per cent), and ground water (68 to 77 per cent). The net contribution of total ion equivalents from biological processes was 20 and 16 per cent for soil water and springs, respectively, but less than 10 per cent for ground water. The contribution of total ion equivalents from deicing salts (10 to 20 per cent) was related to proximity to roads. Strong acids in precipitation contributed 44 per cent of the total amount of hydrogen ions involved in mineral-weathering reactions for ground water in contact with metarhyolite compared to 25 per cent for ground water in contact with metabasalt, a less resistant rock type to weathering.     

松树沟超镁铁岩岩石化学特征及其成因意义

通常岩石化学变异有两种趋势:地幔残余(R)趋势表明,地幔源曾遭受了亲岩浆元素的贫化或辉石矿物相的消耗过程;岩浆结晶趋势及其矿物解指示了玄武质(M_1)岩浆和超镁铁质(M_2)岩浆的两种结晶系列。松树沟岩体NiO— Cr_2O_3、MgO—FeO的图解结果表明与上述结论相同。因此,松树沟超镁铁岩亦可区分为地幔残余(R)型和岩浆结晶(M)型等两种成因类型,属复合成因岩体。     

CMHMIS及其在煤矿水化学特征研究中的应用

利用笔者开发的煤矿水文地质管理信息系统(CMHMIS)来研究煤矿地下水的化学特征。在简要介绍CMHMIS总体设计及其各模块功能的基础上,着重阐述了利用CMHMIS研究张双楼矿井地下水系统水化学特征的结果,并得出一种适合该矿具体情况的最佳分析方案