where k (M− 2 s− 1) can be determined from the
in the pH range 2 to 5, from 5 to 40 °C and 0.01 to 1 M.The effect of pH and ionic strength on the reaction suggest that the rates are due to
where H2A = H2CrO4, HA = HCrO4, H2B = H2SO3 and HB = HSO3. The overall rate expression over the investigated pH range can be determined from
k=kH2A–H2B(αH2A)(αH2B)2+kHA–H2B(αHA)(αH2B)2+kH2A–HB(αH2A)(αHB)2
with kH2A−H2B = 5.0 × 107, kHA–H2B = 1.5 × 106 and kH2A–HB = 6.7 × 107.Fe(III) in the range 1.5 to 20 μM exerts a small catalytic effect on the reaction and significantly lowers the initial concentration of Cr(VI) compared to the nominal value. Contrary to Fe(III), formaldehyde (20 to 200 μM) reacts with S(IV) to form the hydroxymethanesulfonate adduct (CH2OHSO3), which does not react with Cr(VI). Major cations Mg2+ and some minor elements such as Ba2+ and Cu2+ did not affect the rates. The application of this rate law to environmental conditions suggest that this reaction may have a role in acidic solutions (aerosols and fog droplets). This reaction becomes more important in the presence of high Fe(III) and low HMS concentrations, contributing to affect the atmospheric transport of chromium species and the distribution of redox species of chromium, which reach surface water from atmospheric depositions.  相似文献   
266.
Carbon cycling in a high-arctic marine ecosystem – Young Sound, NE Greenland     
Sren Rysgaard  Torkel Gissel Nielsen 《Progress in Oceanography》2006,71(2-4):426
Young Sound is a deep-sill fjord in NE Greenland (74°N). Sea ice usually begins to form in late September and gains a thickness of 1.5 m topped with 0–40 cm of snow before breaking up in mid-July the following year. Primary production starts in spring when sea ice algae begin to flourish at the ice–water interface. Most biomass accumulation occurs in the lower parts of the sea ice, but sea ice algae are observed throughout the sea ice matrix. However, sea ice algal primary production in the fjord is low and often contributes only a few percent of the annual phytoplankton production. Following the break-up of ice, the immediate increase in light penetration to the water column causes a steep increase in pelagic primary production. Usually, the bloom lasts until August–September when nutrients begin to limit production in surface waters and sea ice starts to form. The grazer community, dominated by copepods, soon takes advantage of the increased phytoplankton production, and on an annual basis their carbon demand (7–11 g C m−2) is similar to phytoplankton production (6–10 g C m−2). Furthermore, the carbon demand of pelagic bacteria amounts to 7–12 g C m−2 yr−1. Thus, the carbon demand of the heterotrophic plankton is approximately twice the estimated pelagic primary production, illustrating the importance of advected carbon from the Greenland Sea and from land in fuelling the ecosystem.In the shallow parts of the fjord (<40 m) benthic primary producers dominate primary production. As a minimum estimate, a total of 41 g C m−2 yr−1 is fixed by primary production, of which phytoplankton contributes 15%, sea ice algae <1%, benthic macrophytes 62% and benthic microphytes 22%. A high and diverse benthic infauna dominated by polychaetes and bivalves exists in these shallow-water sediments (<40 m), which are colonized by benthic primary producers and in direct contact with the pelagic phytoplankton bloom. The annual benthic mineralization is 32 g C m−2 yr−1 of which megafauna accounts for 17%. In deeper waters benthic mineralization is 40% lower than in shallow waters and megafauna, primarily brittle stars, accounts for 27% of the benthic mineralization. The carbon that escapes degradation is permanently accumulated in the sediment, and for the locality investigated a rate of 7 g C m−2 yr−1 was determined.A group of walruses (up to 50 adult males) feed in the area in shallow waters (<40 m) during the short, productive, ice-free period, and they have been shown to be able to consume <3% of the standing stock of bivalves (Hiatella arctica, Mya truncata and Serripes Groenlandicus), or half of the annual bivalve somatic production. Feeding at greater depths is negligible in comparison with their feeding in the bivalve-rich shallow waters.  相似文献   
267.
遥感信息技术在公路环境评价中的应用     
张微  林恒章  王薇  范秀英 《地理空间信息》2006,4(5):28-30
介绍了遥感技术在交通项目环境评价中的应用领域,并以随岳高速公路湖南段工程作为应用研究的实例,充分说明该技术是进行交通类项目环境评价中生态评价专题的有效手段之一,尤其适用于进行项目的土地利用现状调查和生态景观影响分析,它具有直观、快速、成本低等特点,值得在类似项目的评价中广泛重视和采用。  相似文献   
268.
岩溶生态系统脆弱性研究   总被引:21,自引:3,他引:18  
李阳兵  邵景安  王世杰  魏朝富 《地理科学进展》2006,25(5):1-9
生态系统的脆弱性评价对于生态系统管理具有重要作用。在分析岩溶生态系统脆弱性特 征和影响因素的基础上,构建了针对岩溶自然系统的脆弱性评价指标体系, 涵盖了岩溶生态系统 的结构脆弱性、生态过程脆弱性、生态功能脆弱性和人为胁迫脆弱性4 个方面,评价指标分别是 结构稳定性、多样性生境、能量利用和积累、直接使用价值、石漠化程度和速率等。以不同类型的 原生岩溶生态系统的生态基准值作为比较基础, 评价系统将现有的退化岩溶生态系统的脆弱性 划分为轻微脆弱、中度脆弱、重度脆弱以及系统崩溃4 级。  相似文献   
269.
陆地生态系统氮状态对碳循环的限制作用研究进展   总被引:34,自引:1,他引:33  
任书杰  曹明奎  陶波  李克让 《地理科学进展》2006,25(4):58-67
陆地生态系统碳循环和氮循环密切相关, 碳贮量与碳通量在很大程度上受氮循环的影响 和限制。由于氮循环的复杂性, 在以往的大多数碳循环研究中, 更多考虑水分、温度和大气CO2 浓 度等因子的影响, 考虑碳氮相互作用的研究较少。氮素可限制植物光合、有机质分解、同化产物的 分配以及生态系统对大气CO2 浓度升高的响应。根据目前有关碳氮模型的发展状况可将碳氮耦 合循环模型分为三大类: 一是静态模型, 它的土壤养分水平或者叶氮含量不变, 是常数, 这类模型 适合于在站点或氮素浓度变化不大的区域应用; 二是土壤氮限制模型, 能够保持稳定的生态系统 氮收支, 在NPP(Net Primary Productivity, 净初级生产力)的模拟中考虑土壤氮有效性的动态变化 的影响, 使模拟结果更为合理; 三是叶氮限制模型, 在NPP 的模拟中考虑叶片氮浓度的动态变化 的影响。这三类模型虽然都考虑了氮对碳循环的限制作用, 但在氮碳循环机理方面尚有不少欠 缺, 所以在研究中可能会带来很大的不确定性。在以后的研究中, 应通过加强碳氮相互作用的实 验研究, 增进对碳氮过程的深入了解, 进而建立综合动态的碳氮耦合模型, 以减少目前碳循环研 究中的不确定性。  相似文献   
270.
基于大数据的生活圈范围与服务设施空间匹配研究——以北京为例   总被引:3,自引:2,他引:1  
赵鹏军  罗佳  胡昊宇 《地理科学进展》2021,40(4):541-553
生活圈建设是新时代国土空间规划的关键内容之一,生活圈内服务设施配置是做好生活圈规划的首要基础,居民生活圈与服务设施的空间匹配关系也是地理学“人地关系”在城市社区尺度的重要体现.学术界对生活圈与服务设施的匹配关系已有研究,但主要采用问卷调查数据,该类数据存在样本量少、地域覆盖范围小等不足.论文将采用手机信令数据和POI(...  相似文献   
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261.
《China Geology》2021,4(3):421-432
The Badain Jaran Desert is the third largest desert in China, covering an area of 50000 km2. It lies in Northwest China, where the arid and rainless natural environment has a great impact on the climate, environment, and human living conditions. Based on the results of 1∶250000 regional hydrogeological surveys and previous researches, this study systematically investigates the circulation characteristics and resource properties of the groundwater as well as the evolution of the climate and ecological environment since the Quaternary in the Badain Jaran Desert by means of geophysical exploration, hydrogeological drilling, hydrogeochemistry, and isotopic tracing. The results are as follows. (1) The groundwater in the Badain Jaran Desert is mainly recharged through the infiltration of local precipitation and has poor renewability. The groundwater recharge in the desert was calculated to be 1.8684×108 m3/a using the water balance method. (2) The Badain Jaran Desert has experienced four humid stages since the Quaternary, namely MIS 13-15, MIS 5, MIS 3, and the Early–Middle Holocene, but the climate in the desert has shown a trend towards aridity overall. The average annual temperature in the Badain Jaran Desert has significantly increased in the past 50 years. In detail, it has increased by about 2.5°C, with a higher rate in the south than in the north. Meanwhile, the precipitation amount has shown high spatial variability and the climate has shown a warming-drying trend in the past 50 years. (3) The lakes in the hinterland of the Badain Jaran Desert continuously shrank during 1973–2015. However, the vegetation communities maintained a highly natural distribution during 2000–2016, with the vegetation cover has increased overall. Accordingly, the Badain Jaran Desert did not show any notable expansion in that period. This study deepens the understanding of groundwater circulation and the climate and ecological evolution in the Badain Jaran Desert. It will provide a scientific basis for the rational exploitation of the groundwater resources and the ecological protection and restoration in the Badain Jaran Desert.© 2021 China Geology Editorial Office.  相似文献   
262.
对基本气候态和降水日变化的分析是检验模式模拟性能、理解模式误差来源的重要手段。为了评估出对热带气候模拟效果较好的物理参数化方案组合,本文应用WRF带状区域模式,主要比较了四种积云对流参数化方案:NewTiedtke、Kain-Fritsch、newSAS、Tiedtke,和两种辐射参数化方案:RRTMG和CAM,对热带带状区域的气候模拟结果。研究表明:使用NewTiedtke积云对流参数化方案和RRTMG辐射方案的试验,表现出对气温、降水及降水日变化等综合性最好的模拟性能;NewTiedtke积云对流参数化方案能模拟出较好的降水空间分布和降水日变化位相分布特征;与RRTMG辐射方案相比,CAM辐射方案会使温度模拟偏低,特别是陆地上更明显,这种陆地上的冷偏差可能主要来源于Tmin的模拟偏冷。  相似文献   
263.
文章选取通辽市各气象站点气象数据、基础地理信息数据、历史灾情数据、第二次土地调查数据及相关社会经济等统计数据,基于自然灾害风险原理,利用数理统计、层次分析法及空间叠加分析等方法,提出了通辽市暴雨洪涝灾害风险评价指标体系,得到通辽市暴雨洪涝灾害风险评估空间分布图。结果表明:高风险区主要分布在通辽市北部山区、中东部地区及偏南部地区,包括扎鲁特旗鲁北镇、科尔沁区、科左中旗东南部及库伦旗东南部;而科左后旗大部地区易形成由短时强降水引发的洪涝,为次高风险区;低风险区及次低风险区主要分布在通辽市中部、西南部地区,包括开鲁县、奈曼旗北部、科左中旗西部。  相似文献   
264.
本文分析了JPEG2000压缩算法的基本原理,对某地区的数字航空遥感影像进行了压缩试验,通过比较不同压缩比下各种评价指标的变化,来研究JPEG2000压缩算法对重建影像构像质量的影响,评价结果表明压缩比的增加,重建影像灰度平均值、标准方差和信息熵在一定范围内波动;同时,随着压缩比的增加,重建影像纹理越来越粗,视觉效果降低,并且重建影像与原始影像的一致性程度降低,差别越来越大。  相似文献   
265.
The rates of the reduction of Cr(VI) with S(IV) were measured in deaerated NaCl solution as a function of pH, temperature and ionic strength. The rates of the reaction were found to be first order with respect to Cr(VI) and second order with respect to S(IV), in agreement with previous results obtained at concentrations two order higher than the present study. The reaction also showed a first-order dependence of the rates on the concentration of the proton and a small influence of temperature with an apparent energy of activation ΔHapp of 22.8 ± 3.4 kJ/mol. The rates were independent of ionic strength from 0.01 to 1 M. The rate of Cr(VI) reduction is described by the general expression
−d[Cr(VI)]/dt=k[Cr(VI)][S(IV)]2
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