Magnetic petrology of the 1991–1995 dacite lava of Unzen volcano,Japan: Degree of oxidation and implications for the growth of lava domes

To understand the oxidation state and process of oxidation of lava domes, we carried out magnetic petrological analyses of lava samples obtained from domes and block-and-ash-flow deposits associated with the 1991–1995 eruption of Unzen volcano, Japan. As a result, we recognize three different types of magnetic petrology, each related to deuteric high-temperature oxidation during initial cooling. Type A oxides are characterized by homogenous titanomagnetite and titanohematite, indicating a low oxidation state and high titanomagnetite concentrations. Type B oxides are weakly exsolved and contain titanohematite laths and rutile lenses, indicating a higher oxidation state. Type C oxides, which represent the highest oxidation state, are completely exsolved and composed of Ti-poor titanomagnetite, titanohematite, rutile, and pseudobrookite, indicating high hematite concentrations. Some grains in Types A and B show indications of reduction, which was related to interaction with volcanic gases subsequent to high-temperature oxidation. In terms of geological occurrence, the oxidation processes probably differed for endogenous and exogenous domes. Endogenous dome lavas are oxidized concentrically and are classified into the three types according to their location within the dome: samples from the surface are strongly oxidized and classified as Type C, while the inner part is unoxidized and classified as Type A. Exogenous dome lavas are unoxidized and assigned to Type A. Some samples show signs of reduction, which may have occurred around fumaroles. We propose that location within the dome and the process of dome growth are the factors that control oxidation.     

Salt-bearing fumarole deposits in the summit crater of Oldoinyo Lengai, Northern Tanzania: interactions between natrocarbonatite lava and meteoric water

Oldoinyo Lengai in the Northern Tanzania rift is the only active nephelinite–carbonatite stratovolcano. We report the discovery of thermonatrite, aphthitalite, halite and sylvite fumarole deposits on recent natrocarbonatite lava flows erupted in the summit crater during the wet season. These salt deposits occur as delicate, concave fringes or tubes that line the cooling cracks in the lava flows and consist of intergrowths of euhedral crystals. The presence of a dark altered zone, depleted in halides and alkalies, adjacent to cooling cracks and observations of steam fumaroles emanating from the fractures suggest that the salts are formed by sublimation from saturated vapours generated by the extrusion of lavas over meteoric water. The crystallisation sequence recorded in the salts suggests that mixing between meteoric steam and magmatic CO₂ and H₂S occurs at high temperatures resulting in the sublimation of carbonates and sulphates. At lower temperatures the vapours are dominated by meteoric steam and sublimate halides. The high solubility of the fumarole salts within meteoric water and their formation only during the wet season implies that these are ephemeral deposits that are unlikely to be preserved in the geological record.     

In situ formation of welded tuff-like textures in the carapace of a voluminous silicic lava flow,Owyhee County,SW Idaho

 The Badlands rhyolite, on the Owyhee Plateau of southwestern Idaho, can be demonstrated to be a large lava flow on the basis of its geometry of large and small flow lobes, its well-exposed near-vent features, and its response to pre-existing topography. However, samples of the dense upper vitrophyre of the unit reveal a range of annealed fragmental textures, including material which closely resembles the compressed, welded glass shards which are characteristic of ignimbrites. Formation of these tuff-like textures involved processes probably common to emplacement of most silicic lava flow units. Decompression upon extrusion causes inflation of pumice at the surface of the lava flow; some of this pumice is subsequently comminuted, producing loose bubble-wall shards, bits of pumice, chips of dense glass, and fragments of phenocrysts. This debris sifts down around loose blocks and into open fractures deeper in the flow, where it can be reheated, compressed, and annealed to varying degrees. The end result is a dense vitrophyre layer (beneath the true upper, non-welded carapace breccia) which can be extremely texturally heterogeneous, with areas of flow-foliated lava occurring very near lava which in many aspects looks like welded ignimbrite, complete with flattened pumices. Identical textures in other silicic units have been cited by previous workers as evidence that those units erupted as pyroclastic flows which then underwent sufficient rheomorphism to create a flow-foliated rock which otherwise appears to be lava. The textures described herein indicate that lava flows can come to mimic rheomorphic ignimbrites, at least at scales ranging from thin sections to outcrops. Voluminous silicic units with scattered fragmental textures, but with otherwise lava-like features, are probably true effusive lava flows. Received: January 30, 1995 / Accepted: January 22, 1996     

江西相山碎斑熔岩成因和钾长石亚显微结构

相山碎斑熔岩含铁铝榴石(1340g/T)、红柱石等岩浆结晶副矿物,具S型火山岩地球化学和Nd、Sr、O同位素组成的特征。据光学测定和X光粉晶衍射测定,斑晶钾长石主要是高正长石或低透长石,有序参数δ′=-0.32—-0.01。在透射电镜下,出溶的细钠长石页片由共格拐点分解形成,成分波长约50—100nm;出溶的宽钠长石页片由无应力离溶作用形成,页片宽50—200nm。结果表明,碎斑熔岩是在火山环境下形成,而不是在深成环境下形成。     

黑龙江省五大莲池火山群中老黑山熔岩磁组构特征分析

近一二十年,岩石磁学有了飞速发展,并在地质学领域内占有越来越重要的位置。国内外研究的焦点是磁组构与应变相关性以及磁组构在岩浆岩、沉积岩构造分析中的应用。本文着重研究了未变形火山熔岩的磁组构特征,为火山岩的磁组构与有限应变相关性等项研究提供基本对比参照体系,也为室内有关的模拟实验提供依据。     

Analysing Lava Risk for the Etnean Area: Simulation by Cellular Automata Methods

The model SCIARA, based on the Cellular Automata paradigm, is a versatile instrument whose scope is to analyse volcanic risk from lava flows.The possible fields of intervention are:[(a)] Long term forecasting of the flow direction at various eruption rates and points of emission by locating potential risk areas and permitting the creation of detailed maps of risk;[(b)] The possibility to follow the progress of an event and predict its evolution;[(c)] The verification of the possible effects of human intervention on real or simulated flows in stream deviation.A risk scenario has been developed for the Etnean territories of the towns of Nicolosi, Pedara and S. Alfio, simulating possible episodes with different vent locations along the fracture opened in the 1989 eruption and successively activated in the 1991–1993 eruption.The main characteristics of lava flows, that might be dangerous to the inhabited areas, have been analysed on the basis of the carried out Cellular Automata.     

滇黔桂卡林型金矿区水系沉积物和岩石金含量与时空分布

为研究滇黔桂卡林型金矿区水系沉积物和岩石中金的地球化学时空分布及其与金矿规模的对应关系,系统收集了该区1:20万区域化探全国扫面计划水系沉积物和全国地球化学基准计划岩石金的地球化学数据,绘制了水系沉积物和岩石金的地球化学分布图。滇黔桂卡林型金矿区以水系沉积物金地球化学异常面积大于1000 km^2为准,共圈定5处金的地球化学省,这些金的地球化学省同时也是矿床大规模产出的部位。区内右江盆地水系沉积物金背景值(1.94×10^–9)高于扬子克拉通(1.68×10^9),其内以泥岩、页岩、砂岩、灰岩为代表的容矿岩石金背景值(0.51×10^–9)也高于扬子克拉通(0.39×10^–9)。研究区不同构造单元及沉积相中水系沉积物金背景值受岩石金背景值的制约。金的地球化学省是地壳演化过程中不均匀分布的高金背景岩石、金矿化作用及金矿床次生风化作用相互叠加的结果。该研究有助于有效判断异常成因、识别成矿作用存在,对研究金的区域成矿规律和聚焦找矿靶区具有重要意义。     

Direct Observations of Atmospheric Transport and Stratosphere-Troposphere Exchange from High-Precision Carbon Dioxide and Carbon Monoxide Profile Measurements

The balloon-borne Aircore campaign was conducted in Inner Mongolia,China,on June 13 and 14 2018,which detected carbon dioxide(CO_2) and carbon monoxide(CO) profiles from surface to 24 km,showing strong positive and negative correlations between 8 km and 10 km on 13 and 14 June,respectively.Backward trajectories,meteorological analyses,and CO_2 horizontal distributions were combined to interpret this phenomenon.The results indicated that the source region experienced a stratospheric intrusion and exhibited a large horizontal CO_2 gradient;namely,lower CO concentrations corresponded to higher CO_2 concentrations and vice versa.The laminar structure with multiple origins resulted in the highly negative correlation between CO_2 and CO in the upper troposphere on 14 June.The contribution of stratospheric air mass to the upper troposphere and that of tropospheric air mass to the lower stratosphere were 26.7% and24.3%,respectively,based on a mass balance approach.Another interesting phenomenon is that CO_2 and CO concentrations increased substantially at approximately 8 km on 13 June.An analysis based on the backward trajectory implied that the air mass possibly came from anthropogenic sources.The slope of CO_2/CO representing the anthropogenic sources was 87.3 ppm ppm~(-1).In addition,the CO_2 profile showed that there was a large CO_2 gradient of 4 ppm km-1 within the boundary layer on 13 June,and this gradient disappeared on 14 June.     

Une dépression piézométrique naturelle en hausse au Sahel (Sud-Ouest du Niger)A rising piezometric depression in the Sahel (southwestern Niger)

In southwest Niger, the Continental Terminal water table displays a natural hollow shape about 10 m in depth over an area of 4000 km². A 10-year survey of this hollow aquifer has shown that current recharge is above $\text{20 }\text{mm}\text{yr}{}^{\mathrm{?1}}$. The water table has risen continuously since the 1950–1960s as a result of land clearance. This shows a disequilibrium in the aquifer balance. The long-term recharge rate is estimated by radioisotopes to be around $\text{1 }\text{mm}\text{yr}{}^{\mathrm{?1}}$. This figure fits with the only possible origin of the piezometric depression, i.e. evapotranspiration losses in its centre. To cite this article: G. Favreau et al., C. R. Geoscience 334 (2002) 395–401.     

喀喇沁玻基橄辉岩中的磷酸盐质熔体及磷灰石

磷酸盐在本文讨论的坡基橄辉岩中以多种形式产生,有早期结晶的磷灰石斑晶;有熔离的磷酸盐质熔浆液滴;也有晚期穿入橄榄石斑晶的磷酸盐质细脉,表明元素磷活跃在岩浆演化的每一个阶段。磷酸盐质熔浆液滴的存在,说明磷酸盐质熔体可能是由于岩浆的熔离作用而形成的。沿着橄榄石晶格生长石出现的磷酸盐质玻璃细脉则进一步证实地幔中含磷流体不但存在,而且具有很强的活动性。