Evolution of mineralizing fluids in the Zn–Pb–Cu(–Ag ± Au) skarn and epithermal deposits of the world-class San Martín district, Zacatecas, Mexico

Mineralizing fluids at the San Martín skarn show an evolution characterized by prograde and retrograde associations. The prograde mineral associations consist of (1) a massive garnet zone, (2) a tremolite ± garnet zone, and (3) a late association of quartz, sphalerite, calcite and fluorite lining the vugs in the garnet zone. The fluids of the prograde associations exhibit decreasing temperatures of homogenization (Th) and variable salinities. The fluids of the massive garnet zone have salinities of 36 wt.% NaCl equiv. and Th of 645 to 570 °C, corresponding to pressures of 1055 bar. At the tremolite ± garnet zone, Th range from 438 to 354 °C. In the late association at the endoskarn, the following evolution can be drawn: (a) salinities of 50 to 42 wt.% NaCl equiv., and Th of 455 to 346 °C in quartz, (b) salinities of 46 wt.% NaCl equiv., and Th of 415 to 410 °C in sphalerite, (c) salinities of 50 to 37 wt.% NaCl equiv., and Th of 479 to 310 °C in calcite, (d) salinities of 33 to 28 wt.% NaCl equiv. and of 24 to 22 wt.% KCl in fluorite, and (e) two types of fluids with salinities of 2 and 39 wt.% NaCl equiv. and Th 344 and 300 °C, respectively, in later saccharoidal quartz segregations. The retrograde mineral associations comprise pervasive propylitic alteration to carbonization, and mantos with sulfides. Fluids in epidote have salinities of 7.6 wt.% NaCl equiv. and Th of 287 to 252 °C, and in calcite have salinities of 9.2 to 1 wt.% NaCl equiv. and Th of 188 to 112 °C. Fluids in the sulfide assemblages in the mantos have salinities of 8 to 3 wt.% NaCl equiv. and Th 300 °C, with corresponding pressures of 94 bar. Fluids in late epithermal veins close to the intrusive body have salinities of 10 to 5 wt.% NaCl equiv. and Th of 275 to 200 °C, and distal veins show salinities of 2 to 1 wt.% NaCl equiv. and Th of 160 °C.     

地下水流系统理论与研究方法的发展

地下水流系统理论的提出,推动了现代水文地质学的发展。以Tóth经典地下水流系统理论建立方法为基础,综述了基于Tóth方法的地下水流系统的模拟成果,分析了Tóth方法得出的水流模式与控制因素的关系,以及地下水流系统理论从概念到实际应用的发展。同时,对中国地质大学(武汉)提出的地下水流系统通量上边界模拟方法也进行了系统论述,在物理模拟实验与数值模拟基础上,认为通量上边界分析方法是对Tóth方法的改进与完善,有利于对地下水流系统发育的物理机制理解;该方法能够更全面认识地下水流系统模式及其转化,定量出各影响因素对地下水流模式的控制关系。最后指出地下水流系统理论是当代水文地质学的核心概念框架,应该重视地下水流系统理论物理机制和数学模拟方法的研究,加强新技术方法的引入,拓宽其应用领域的研究等。     

Aeromonas veronii, a tributyltin (TBT)-degrading bacterium isolated from an estuarine environment, Ria de Aveiro in Portugal

Organotin compounds are used in a variety of industrial processes therefore their subsequent discharge into the environment is widespread. Bacteria play an important role in biogeochemical transformations acting as natural decontamination agents. Therefore, screening for tributyltin (TBT)-resistant and -degrading bacteria is relevant for the selection of isolates with decontamination ability of these polluted areas. With this purpose, 50 strains were isolated from sediment and water from Ria de Aveiro and their tolerance to TBT, up to 3mM, was evaluated. Generally, occurrence of highly TBT-resistant bacteria was observed, and Gram negative bacteria exhibited more tolerance to TBT than Gram positive bacteria. A memory response was observed when bacteria were progressively exposed to increasingly higher TBT concentrations. One isolate, Aeromonas veronii Av27, highly resistant to TBT (3mM) uses this compound as carbon source and degrades it to less toxic compounds.     

Isotope Dilution Determinations of Lu,Hf, Zr,Ta and W,and Hf Isotope Compositions of NIST SRM 610 and 612 Glass Wafers

Isotope dilution determinations of Lu, Hf, Zr, Ta and W are reported for nine test portions (five for W) of NIST SRM 610 and 612 glass wafers. Additionally, all test portions were analysed for their Hf isotope compositions. In general, high field strength elemental (HFSE) distributions in NIST SRM 610 and 612 were reproducible to ～± 1%, except for Zr (± 5%) in NIST SRM 612, and absolute reported concentrations agreed with previously published values, but with higher precision. The slightly worse reproducibility of Zr in NIST SRM 612 compared to other HFSE is interpreted to result from analytical scatter, rather than sample inhomogeneity. The analyses demonstrated elemental homogeneity for both glass wafers for samples of 1–2 mg with respect to the precision of the method, i.e., ± 1% or better. Average Hf isotope compositions for both glass wafers agreed within uncertainty and the weighted average of all determinations yielded a mean ¹⁷⁶Hf/¹⁷⁷Hf ratio of 0.282111 ± 0.000009 (95% confidence level). However, although mean values for NIST SRM 610 and 612 agreed within analytical limits, NIST SRM 610 test portions showed a tendency of systematically elevated isotope composition of ～ 0.5 _?Hf units when compared to NIST SRM 612, which may indicate a slightly more radiogenic Hf isotope composition of NIST SRM 610. The results of this study suggest that NIST SRM 610 and 612 are valuable calibrators for HFSE in situ analyses within the given uncertainties.     

Warming in the Northwestern Indian Ocean Associated with the El Nio Event

This paper investigates possible warming effects of an El Nino event on the sea surface temperature anomaly (SSTA) in the northwestern Indian Ocean. Most pure positive Indian Ocean dipole (IOD) events (without an El Nino event co-occurring) have a maximum positive SSTA mainly in the central Indian Ocean south of the equator, while most co-occurrences with an El Nino event exhibit a northwest-southeast typical dipole mode. It is therefore inferred that warming in the northwestern Indian Ocean is closely related to the El Nino event. Based on the atmospheric bridge theory, warming in the northwestern Indian Ocean during co-occurring cases may be primarily caused by relatively less latent heat loss from the ocean due to reduced wind speed. The deepened thermocline also contributes to the warming along the east coast of Africa through the suppressed upwelling of the cold water. Therefore, the El Nino event is suggested to have a modulating effect on the structure of the dipole mode in the tropical Indian Ocean.     

A re-examination of the mechanism and human impact of catastrophic mass flows originating on Nevado Huascarán, Cordillera Blanca, Peru in 1962 and 1970

The 1962 and 1970 Huascarán mass movements, originated as rock/ice falls from the mountain's North Peak, transformed into higher-volume high-velocity mud-rich debris flows by incorporation of snow from the surface of a glacier below Huascarán and the substantial entrainment of morainic and colluvial material from slopes below the glacier terminus. Water for fluidization of the entrained material originated in the melting of incorporated snow and the liberation of soil moisture contained within the entrained materials. Eyewitness reports indicate very high mean velocities for the events; 17–35 m/s (1962) and 50–85 m/s (1970). The runout distances and velocity profiles of both events were simulated using DAN/W. Both mass movements continued downstream in the Rio Santa as debris floods (aluviones) that in 1970 reached the Pacific at a distance of 180 km. In strong contrast to publications in the geosciences literature, 1961 Peru Census data indicates that the death toll of the 1970 event is ca. 6000 and that total life loss in the two events did not exceed 7000 people.     

Middle Eocene deformation–sedimentation in the Luracatao Valley: Tracking the beginning of the foreland basin of northwestern Argentina

The Andean foreland basin overlaps the Cretaceous-Paleogene Salta rift basin in northwestern Argentina. Knowledge of the relationship between rift and foreland basins is key to understanding the initial stages of foreland basin development related to Andean shortening. We present a new stratigraphic scheme for the Luracatao Valley, revealing that the Quebrada de los Colorados Formation (Payogastilla Group) lies over the Santa Bárbara Subgroup (Salta Group) through an erosional unconformity that turns into an angular unconformity close to folds and faults recorded in the Santa Bárbara Subgroup. The base of the Quebrada de los Colorados Formation shows growth strata along the west frontal limb of an anticline with Santa Bárbara units in its core. The finding of a mammalian fossil at the base of the Quebrada de los Colorados Formation allows us to assign a Middle-Upper Eocene age to the sedimentation; therefore, the time elapsed between the deposition of the final postrift strata and the beginning of Andean sedimentation was brief and constrained to the Lower-Middle Eocene. This data indicates that the Eocene deformation phase described in other portions of the Puna-Cordillera Oriental transition (e.g., the northern Calchaquí Valley and Aguilar range) is also present in the Luracatao Valley, offering new tools for interpreting the ages and distributions of the initial episodes of sedimentation and deformation related to the Andean shortening. Thus, the Luracatao Valley provides new evidence for tracking the distribution of the Paleogene deformation in northwestern Argentina.     

The use of geoprocessing to assess vulnerability on the east coast aquifers of Rio de Janeiro State,Brazil

The east coast of Rio de Janeiro State, Brazil, shows a worrying overlap between areas with intrinsic groundwater vulnerability and the most significant urban expansion zones. It experienced a rapid population growth in recent years, mainly due to the tourism industry, resulting in a significant pressure on drinking groundwater resources. In this regard, development and use of techniques to control and protect areas susceptible to contamination is crucial. The elaboration of aquifer vulnerability maps is thus extremely helpful to support water resources management. The aim of the work is to present the methodological approach in the use of Geoprocessing techniques to obtain a suitable groundwater vulnerability model in Rio de Janeiro east coast. Considering the existing problems and the current land use and characteristics of the study region, it is clear that the most vulnerable areas (that is, “extreme” and “very high” vulnerability areas), coincide with the most significant zones of urban occupation, corresponding to 11% of the total study area, demanding adoption of urgent measures in the near future. Geoprocessing tools and remote sensing for characterization of Rio de Janeiro’s east coast aquifer vulnerability gave good results, representing a satisfactory method for management actions at low cost.     

Genesis and evolution of the structurally controlled vein mineralization (Sb–Hg) in the Escarlati deposit (León,Spain): Evidence from fault population analysis methods,fluid-inclusion research and stable isotope data

The Escarlati deposit is located in the Cantabrian Zone of the Variscan Massif and is one of the best examples in the Iberian Peninsula of Sb and Hg both coexisting in the same paragenesis. The Sb–Hg mineralization appears filling hydraulic and collapse breccias hosted in Late-Variscan fractures affecting Carboniferous black limestones.     

塔里木盆地侏罗系煤岩热模拟生物标志化合物特征研究

通过对塔里木盆地侏罗系煤岩热模拟实验研究,其结果表明生物标志化合物的组成不仅受其母质的控制,而且还受热成熟度和生油岩的岩性影响。这与生油岩中生物标志化合物先质在不同演化阶段释放出不同碳数生物标志化合物的强度有关。同时,在烃源岩热演化过程中时,不能仅依靠OEP值作为热成熟度的判识指标;正构烷烃峰型在整个热演化过程中呈现出双峰型,前驼峰的主峰碳主要集中在nC₁₆-nC₁₈,而后驼峰则随着模拟温度的升高逐渐增大;煤岩的ΣC_21-/ΣC₂₂₊值与热模拟温度之间呈现出规律性变化;原始煤岩的Pr/Ph值随热模拟温度由250℃～550℃升高,总体呈逐渐降低的趋势。