华北克拉通南缘豫西燕山期花岗岩类的 Pb-Sr- Nd同位素地球化学特征

对华北克拉通南缘豫西燕山期具类似于板块俯冲带花岗岩成分变化规律（成分极性）的八宝山、柳关、后瑶峪花岗斑岩类的Pb、Sr、Nd同位素地球化学特征的研究,揭示了这些斑岩的主要物质来源是新太古代的太华群斜长角闪岩部分熔融产生的熔浆与地幔来源物质混合形成的产物。稀土元素含量非常低的八宝山花岗斑岩在岩石形成过程中有流体与其发生交代作用,由于交代及混合作用造成花岗斑岩类的Rb—Sr等时线多为假等时线;柳关花岗斑岩基本上完全由太华群的斜长角闪岩提供物质,豫西地区燕山期的花岗岩岩基其物质来源更为复杂,可能有宽坪群为其提供物质。     

Late Pleistocene paleoclimatic history documented by an oxygen isotope record from carbonate sediments in Qarhan Salt Lake,NE Qinghai–Tibetan Plateau

Late Pleistocene paleoclimatic variability on the northeastern Qinghai–Tibetan Plateau (NE QTP) was reconstructed using a chronology based on AMS ¹⁴C and ²³⁰Th dating results and a stable oxygen isotopic record. These are derived from lake carbonates in a 102-m-long Qarhan sediment core (ISL1A) collected from the eastern Qaidam Basin. Previous research indicates that the δ¹⁸O values of lacustrine carbonates are mainly controlled by the isotopic composition of lake water, which in turn is a function of regional P/E balance and the proportion of precipitation that is monsoon-derived on the NE QTP. Modern isotopic observations indicate that the δ¹⁸O values of lake carbonates in hyper-arid Qaidam Basin are more positive during the warm and wet period. Due to strong evaporation and continental effect in this basin, the positive δ¹⁸O values in the arid region indicate drier climatic conditions. Based on this interpretation and the δ¹⁸O record of fine-grained lake carbonates and dating results in ISL1A, the results imply that drier climatic conditions in the Qarhan region occurred in three intervals, around 90–80 ka, 52–38 ka and 10–9 ka, which could correspond to late MIS 5, middle MIS 3 and early Holocene, respectively. These three phases were almost coincided with low lake level periods of Gahai, Toson and Qinghai Lakes (to the east of Qarhan Lake) influenced by ASM on the orbital timescales. Meanwhile, there was an episode of relatively high δ¹⁸O value during late MIS 3, suggesting that relatively dry climatic condition in this period, rather than “a uniform Qarhan mega-paleolake” spanning the ∼44 to 22 ka period. These results insight into the understanding of “the Greatest Lake Period” on the QTP.     

Sr isotopes in the Orgueil CI meteorite: Chronology of early solar system hydrothermal activity

New Sr isotopic analyses and calculated formation ages of carbonates from the Orgueil CI meteorite are reported. Among the samples analyzed in this work, dolomites give the youngest formation ages and may have been deposited intermittently starting near the time of parent body formation and continuing for at least 30 Ma. The Sr isotope data also suggest that breunnerites (Fe-Mn-Mg carbonates) crystallized after dolomite formation. Leaching experiments on bulk meteorite samples provide evidence for a very mobile, water soluble Sr reservoir in Orgueil that is characterized by extremely radiogenic Sr (⁸⁷ Sr/⁸⁶ Sr≈ 0.81-0.82). This unsupported Sr reflects recent element redistribution, possibly at the time of parent body breakup recorded by the ∼ 10 Ma exposure age of Orgueil. The carbonate data in particular corroborate earlier indications that hydrothermal processes were among the earliest events to affect the CI parent body.     

松辽盆地徐家围子断陷深层天然气同位素倒转现象研究

天然气的同位素组成受源岩有机质类型、热演化程度和成藏后的次生变化等多种因素的影响, 其单体烃同位素分布特征是区分各种因素影响程度的地球化学指纹.天然气单体烃同位素通常有随碳数增加而变重的趋势, 而徐家围子深层天然气单体烃同位素倒转现象却比较普遍, 高地温和细菌氧化对于造成该区同位素倒转的可能性不大, 浅层油型气或无机气的混合作用没有充分的地质证据, 同层有机质中不同类型气的混合和盖层微渗漏造成的蒸发分馏作用可能是导致徐家围子断陷深层天然气同位素倒转的主要原因.      

冀东下营坊地区晚古生代富碱侵入岩锆石U-Pb年代学、岩石地球化学及其地质意义

富碱侵入岩具有重要的地质和矿产意义,倍受学者关注。冀东地区晚古生代钙碱性岩浆岩十分发育,而碱性岩少见,笔者首次在冀东下营坊地区识别出一批与金(铜铅锌银)多金属矿化有关的晚古生代中晚期的富碱侵入岩体。通过锆石LA-ICP-MS U-Pb测年,获得下营坊地区三处富碱侵入岩的侵位年龄分别为300.0±1.5Ma、299.3±2.1Ma、300.0±2.0Ma,侵位时间显示这些岩浆岩均为晚石炭世末—早二叠世的产物。岩石地球化学特征显示富碱(K2O+Na2O8%),稀土元素含量较高,并强烈富集轻稀土,指示其具有富碱侵入岩的基本特征。下营坊富碱侵入岩富集大离子亲石元素,高La/Yb比,较高的La/Sm比值且变化范围大(5),低Y,Eu异常不明显等特点,表明其源区可能与富集地幔有关,并可能受到俯冲板片脱水所释放流(熔)体的影响,在岩浆的侵位过程中可能受到地壳物质的混染。由成岩时代结合区域构造演化历史推断,该地区富碱侵入岩很可能与古生代期间古亚洲洋板块向华北板块俯冲有关,并形成于由俯冲板块后撤的伸展环境。     

胶南新元古代花岗片麻岩中淡色脉体的锆石年代学和稀土元素研究

苏鲁造山带中出露了大面积的新元古代花岗片麻岩,这些花岗片麻岩中赋存规模不等、形态各异的变质岩包体,已有资料表明它们均受到印支期高压-超高压变质作用的强烈影响.在花岗片麻岩及包体中经常可见以白色为主的长英质淡色脉体,脉体通常较窄,宽度多在1厘米以内,少数可达几个厘米,它们一般随片麻理方向延展,亦可见切穿片麻理的淡色脉,通常认为这类淡色脉体是母岩部分熔融的产物.作者等对出露于山东诸城市石河头乡新元古代花岗片麻岩中淡色脉体的锆石年代学及地球化学进行了探索性研究,取得了宝贵的地质信息.研究结果表明,淡色脉体中锆石SHRIMP法U-Pb年龄为(147.6±2.5)Ma,同时锆石具有高铀、极低钍和重稀土富集等特征.文中在简略介绍地质背景的基础上,着重对淡色脉体中锆石的特征、锆石微区年龄和REE测定结果的地质意义进行了讨论.     

Zircon U–Pb and pyrite Re–Os age constraints on pyrite mineralization in the Yinjiagou deposit,China

We report new zircon U–Pb and pyrite Re–Os geochronological studies of the Yinjiagou poly-metallic deposit, sited along the southern margin of the North China Craton (SMNCC). In this deposit, pyrite, the most important economic mineral, is intergrown/associated with Mo, Cu, Au, Pb, Zn, and Ag. Prior to our new work, the age of chalcopyrite–pyrite mineralization was known only from its spatial relationship with molybdenite mineralization and with intrusions of known ages. The U–Pb and Re–Os isotope systems provide an excellent means of dating the mineralization itself and additionally place constraints on the ore genesis and metal source. Zircons separated from the quartz–chalcopyrite–pyrite veins include both detrital and magmatic groups. The magmatic zircons confine the maximum age of chalcopyrite–pyrite mineralization to 142.0 ± 1.5 Ma. The Re–Os results yield an age of 141.1 ± 1.1 Ma, which represents the age of the chalcopyrite–pyrite mineralization quite well. The common Os contents are notably low (0.5–20.1 ppt) in all samples. In contrast, the Re contents vary considerably (3.0–199.2 ppb), most likely depending on intensive boiling, which resulted in an increase of Re within the pyrite. This study demonstrates that the main chalcopyrite–pyrite mineralization occurred late in the magmatic history and was linked to a deeper intrusion involving dominant mantle-derived materials. This mineralization event might be related to the Early Cretaceous lithospheric destruction and thinning of the SMNCC.     

西太平洋富钴结壳超微化石与分子化石地层划分及对比

对具典型三层构造的西太平洋海山群富钴结壳样品进行了钙质超微化石地层学研究,获取了富钴结壳从内层致密层、中间疏松层到外层较致密层的生长时代:CM1D03为晚古新世-早始新世、始新世中期、中中新世-更新世;CM3D06分为晚古新世-早始新世、中始新世-晚中新世、上新世-更新世。对富钴结壳壳层的甾烷系列分子(C27、C28、C29)进行了检测并计算了相对含量,结果表明,两块富钴结壳的甾烷分布构型在结壳生长时代上具有一致性:晚古新世-早始新世,呈反"L"型分布;中始新世呈C27优势的"V"型分布;中新世-更新世呈C29优势的"V"型分布。甾烷分布构型的变化与古海洋环境演化造成的海底甾烷输入波动有关,具有一定的时代特征钙质超微化石和分子化石地层学划分方法在富钴结壳层主要生长时代及生长间断的界定上具有一致性,可以用于富钴结壳的地层划分和对比。