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191.
The mixing behaviour of iron, manganese, phosphate and humic acid in a Delaware salt marsh creek was studied using field data, laboratory mixing experiments, and geochemical mass balance equations. Property-salinity diagrams for field data indicated that the removal of iron is 56–70% in the 0–10‰ salinity range. A proposed mechanism of removal is the flocculation of colloidal iron, perhaps with humic acid. Phosphate, however, undergoes 195% addition in the same low salinity region, which may be due to release of phosphate from resuspended sediments. Dissolved manganese is conserved, as is humic acid throughout the salt marsh mixing zone. Within the uncertainty of the data the maximum possible removal of humic acid is 23%.Laboratory mixing experiments that simulated salt marsh mixing along the same salinity gradient as observed in the field (5–25‰) showed only small-scale additions and removals compared to the field results. Such small-scale changes occurred largely at salinities >10‰ in the laboratory experiments, whereas most removals and additions occurred at salinities <10‰ in the field. Mixing studies also showed little difference between prefiltered and unfiltered mixes. The studies suggest that simple mixing of salt marsh waters, with or without suspended material, does not strongly influence the observed behaviour of dissolved constituents in salt marshes, and that other processes (e.g. sediment or intertidal exchange) must dominate their behaviour. 相似文献
192.
济南张马屯铁矿安全生产30年,其根本保证是通过帷幕注浆建立起了一条长效稳定的地下“拦水大坝”。该技术不仅具有极高的安全效益和经济效益,同时具有保护地下水资源的社会效益。该项技术适用范围广、工艺成熟、易于实施,应该作为深井大水矿山地下水治理的主要技术方法予以推广应用。 相似文献
193.
M. Â. B. C. Menezes C. V. S. Sabino M. B. Franco E. C. P. Maia C. C. B. Albinati 《Journal of Atmospheric Chemistry》2004,49(1-3):403-414
The workers health service is guided to look for risks. There is not an evaluation of the onset of the disease linked to a long-term exposure to low levels of toxic agents. Besides, there are few records of the level of metal concentration in the environmental air in industry, as well as few records of the level of contamination of factory workers. To assess the level of pollution in workplace, galvanising industry was chosen as the object of this study. The worker exposure and contamination levels were assessed by means of airborne particulate matter collected in air filters and biomonitors. The analysis of the air filter, hair and toenail samples were carried out by Instrumental Neutron Activation Analysis, and urine samples by Graphite Furnace Atomic Absorption Spectrophotometry. The statistical multivariate analysis and ANOVA methods were applied to elemental concentration. Copper and iron elements were highlighted as the main contributors on the differentiation of the classes. The results point out the effectiveness of biomonitors in occupational studies. 相似文献
194.
FENG Xionghan LIU Fan TAN Wenfeng LIU Xiangwen & HU Hongqing . College of Resources Environment Huazhong Agricultural University Wuhan China . Testing Center China University of Geosciences Wuhan China 《中国科学D辑(英文版)》2004,47(8):760-768
Todorokite is one of the common manganese ox-ides in manganese ore deposits, weathering product of manganese-bearing rocks, soils and sediments. It is also an important component in the abundant marine manganese nodules. Since todorokite was firstly found in Japanese Todoroki mine in 1934, its properties and origination have appeared to be very interesting to many researchers[1—3]. It has a stable structure similar to porous molecular sieves, constructed of triple MnO6 octahedral chains. Th… 相似文献
195.
Jia?RongfenEmail author Peng?Xianzhi Zhou?Zheng Liu?Dehan Wang?Guanxin Wang?Deqiang 《中国地球化学学报》2004,23(3):197-206
Relatively strongly magnetic fine components (< 30μm, XS-4J and DS-4J) which are most environmentally sensitive were separated from layer S5-1 in the Xifeng and Duanjiapo loess sections and analyzed by MPV-3 for their morphometric characteristics and reflectance, SEM-ESD for their element contents and XRD for their mineral phases, respectively. The results showed that minerals in both samples are dominated by detrial Fe-Ti oxides of aeolian origin. In sample XS-4J the reflectance and iron contents of magnetic minerals are usually high. In addition to magnetite (Fe3O4), maghemite (γFe2O3) and hematite (Fe2O3), some Fe-high oxide (72.25 wt%–86.67 wt%), ilmenite (FeTiO3), and magnetite-ulvöspinel [Fe(FeCr)O4, Fe (FeNi)O4] were also detected. In sample DS-4J obvious negative linear correlations were found between Ti and Fe, and the contents of Mn, Si, Al and Ca are usually high and the minerals are dominated by magnetite (maghemite), goethite (FeOOH) and limonite (containing Si and OH). In addition, the signs of corrosion of magnetic minerals and newly crystallized magnetite (maghemite) were recognized. Differences in the composition and assemblage characteristics of magnetite minerals between XS and DS reflect significant differences in source rocks and preserving conditions. 相似文献
196.
197.
In this paper, the application of a homemade Nation and Co(Salen) modified platinum microelectrode and an ISO-NOPMC microsensor (World Precision Instruments, USA ) to measure nitric oxide in natural seawater is reported. These two microelectrodes are suitable for the measurement. In natural seawater, the sensitivity and stability of the ISO-NOPMC microsensor are higher than that of the homemade Nation and Co(Salen) modified platinum microelectrode. 相似文献
198.
原子吸收分光光度法快速测定铬铁矿中钙、镁、锰 总被引:2,自引:0,他引:2
通过在标液中加入相应的Sr来消除离子干扰,采用原子吸收分光光度法快速测定CaO、MgO、MnO的含量,方法经国家标准物质验证,其RSD<2%(n=6)。其结果与标准值相符。方法达到了准确、简便、快速、实用性强。 相似文献
199.
含铬废水具有有机物含量高,难降解物质浓度高,色度大,悬浮物多,水质、水量变化大,含有微量毒性物质等特点。本文探讨了在不同参数条件下,硫酸亚铁、铁、硫化亚铁三种还原剂对含铬废水处理效果的影响,实验表明:硫酸亚铁具有明显的优越性,在同等条件下其去除率达到99%以上。 相似文献
200.