基于流量监测的西藏东南部然乌湖水量平衡季节变化及其补给过程分析

青藏高原分布着亚洲大陆最大的湖泊群,其湖泊变化对气候变化响应敏感。基于遥感数据的湖泊面积变化不足以反映外流湖对气候变化的响应,需借助湖泊水量平衡过程分析来进一步研究各补给要素的变化。本文利用2015年4月-11月然乌湖水文气象监测数据,通过建立流量—水位关系,依据连续的水位数据重建了观测期内然乌湖主要径流的水文过程线,并结合SRM模型分析了然乌湖的水量平衡过程及季节变化。结果表明,观测期内然乌湖入湖水量约为18.49×10⁸ m³,其中冰川融水约为10.06×10⁸ m³,冰川融水占然乌湖补给的54%以上,湖面降水、湖面蒸发对湖泊水量平衡过程影响微弱。流域降水对湖泊的补给具有明显的季节特征。春季受西风南支扰动影响,然乌湖地区降水量大,降水是春季然乌湖的主要补给源。夏季和早秋由于气温升高,冰川消融量大,冰川融水是湖泊补给的主控因素。在未来气候变暖的条件下,冰川融水将会在湖泊补给中占据更大比例,并可能使得流域内的冰湖水量增加,产生潜在灾害风险。     

Three mechanisms of ore re-mobilisation during amphibolite facies metamorphism at the Montauban Zn–Pb–Au–Ag deposit

The relative importance of mechanical re-mobilisation, hydrothermal dissolution and re-precipitation, and sulphide melting in controlling redistribution of metals during concurrent metamorphism and deformation is evaluated at the middle amphibolite facies Montauban deposit in Canada. As at many other deposits, ductile deformation was important in driving mechanical re-mobilisation of massive sulphides from limb regions into hinge regions of large-scale folds and is thus the most important for controlling the economics of Pb and Zn distribution. Two possible stages of hydrothermally driven re-mobilisation are discussed, each of which produces characteristically different alteration assemblages. Prograde hydrothermal re-mobilisation is driven by pyrite de-sulphidation and concurrent chlorite dehydration and is thus an internally driven process. At Montauban, the H₂S-rich fluid generated through this process allowed re-mobilisation of gold into the wall rock, where it was deposited in response to sulphidation of Fe Mg silicates. Retrograde hydrothermal re-mobilisation is an externally driven process, whereby large volumes of fluids from outside the deposit may dissolve and re-precipitate metals, and cause hydration of silicate minerals. This second hydrothermally driven process is not recognised at Montauban. Sulphide melting occurred as temperatures neared the peak metamorphic conditions. Melting initiated in the massive sulphides through arsenopyrite breakdown, and a small volume of melt was subsequently re-mobilised into the wall rock. Trace element partitioning and fractional crystallisation of this melt generated a precious metal-rich fractionate, which remained mobile until well after peak metamorphism. Thus, prograde hydrothermal re-mobilisation and sulphide melting were the most important mechanisms for controlling the distribution of Au and Ag.     

硫铁矿地下深井巷堵水工程设计

本文工程设计阐述了在动水条件下,封堵水平巷道的“三段式”组合灌浆方法,以及定向钻进在地下深井巷堵水工程中的应用。     

祁连山南麓退耕地主要植物群落植冠层的截留性能

退耕地人工群落植冠层的截留能力,是群落生态效益的重要组成部分,这一研究不仅可以掌握退耕还林还草工程作用的机理,还可以更好地指导工程实践,促进工程建设步伐。通过“简易吸水法”,可以快速掌握退耕地植冠层的最大截留潜力。青海省大通县退耕较早、平均年龄约10a以上的青海云杉、华北落叶松等几种人工群落,它们的林冠截留量较高,平均达1．93mm,为当地3种截留量最高、林龄50a之上天然群落的61％。青海云杉、华北落叶松、白桦、青杨、中国沙棘等退耕地人工群落的截留量,基本上显示出与林龄之间呈线性或Cubic、Quadratic正相关关系。在植物群落分层截留、消化吸收降雨的这一空间垂直序列中,植冠层截留量虽然较低,平均仅1．29mm(0．25～2．38mm),但植冠层的主要作用还在于减轻、缓冲雨水直接打击地面,改变降水的侵蚀性危害,而这些作用要远远高于截留量自身的区区数量。     

The transition from peraluminous to peralkaline granitic melts: Evidence from melt inclusions and accessory minerals

Fractional crystallization of peraluminous F- and H₂O-rich granite magmas progressively enriches the remaining melt with volatiles. We show that, at saturation, the melt may separate into two immiscible conjugate melt fractions, one of the fractions shows increasing peraluminosity and the other increasing peralkalinity. These melt fractions also fractionate the incompatible elements to significantly different degrees. Coexisting melt fractions have differing chemical and physical properties and, due to their high density and viscosity contrasts, they will tend to separate readily from each other. Once separated, each melt fraction evolves independently in response to changing T/P/X conditions and further immiscibility events may occur, each generating its own conjugate pair of melt fractions. The strongly peralkaline melt fractions in particular are very reactive and commonly react until equilibrium is attained. Consequently, the peralkaline melt fraction is commonly preserved only in the isolated melt and mineral inclusions.

We demonstrate that the differences between melt fractions that can be seen most clearly in differing melt inclusion compositions are also visible in the composition of the resulting ore-forming and accessory minerals, and are visible on scales from a few micrometers to hundreds of meters.     

核爆炸玻璃、撞击玻璃和玻璃陨石源岩

本文根据核爆炸岩石熔融玻璃的地球化学研究结果,与超速陨石撞击坑的熔岩进行比较,获得在远离热力学平衡条件下,各种玻璃和熔岩在化学成分上分布十分均匀的重要结论。岩石玻璃和熔岩是由基岩各组成岩石按一定比例混合熔融形成的。它们的主量元素和痕量元素丰度受基岩元素背景值制约。文中根据熔体和靶岩的化学成分,计算了熔岩各组成岩石的百分比。玻璃陨石是地壳岩石受撞击熔融形成的。同一撒布区的玻璃陨石化学成分相近,说明起源于同一源坑;而玻璃陨石化学成分的不同,则说明母岩组成分量的差异。因此,文中通过模拟计算,得出各玻璃陨石的组成源岩。澳大利亚撒布区的玻璃陨石,Al₂O₃,K₂O 和Na₂O 与 SiO₂及 K₂O/Na₂O 比值不完全相同,说明澳大利亚撒布区存在着几个不同的源岩和源坑,至少有印支、爪哇、菲律宾和澳大利亚四个相应撞击坑。     

X射线荧光光谱法测定重晶石中的硫酸钡方法研究

应用XRF可快速测定重晶石中钡元素的总量,但当测定硫酸钡含量时,由于样品中的碳酸钡计入钡量造成硫酸钡的测定结果不准确,铜、铅、锌等有色金属元素对熔样坩埚会造成损害,需要进行酸处理除去碳酸钡、铅等干扰。而样品经酸处理后不同样品的剩余量不同,造成熔剂与样品的比例不确定,也不能准确测定硫酸钡的含量,因此保证熔剂与样品比例一致是解决该问题的关键。本文优化了样品前处理、熔片制样和仪器工作条件,将一定量样品以10%盐酸和10%硝酸溶解,过滤除去碳酸钡、硫酸钙及铜、铅、锌等有色金属元素,未溶解样品在700℃下灼烧后以氧化铝补充到原取样量,实现了熔剂与样品比例一致,再以硝酸铵作氧化剂,溴化锂和碘化铵作脱模剂,1075℃熔融制片,即可用XRF准确测定硫酸钡的含量。本方法的相对标准偏差(RSD)小于0.4%,检出限为72μg/g,较ICP-OES等方法的检测周期短、干扰元素少,提高了测试效率和分析质量。     

赣南西华山黑钨矿中熔融包裹体的发现和初步研究

文中概述了西华山黑钨矿中熔融包裹体的一些基本特征和初步测定结果,并提供了相关照片。文中还分析了存在这种包裹体的可能性以及它与普通水溶液包裹体或偶然捕获的流体+晶体等异常包裹体的区别。     

高寒区抽水融冰渠道水温沿程衰减规律——以红山嘴水电站为例

抽水融冰技术是解决高寒区引水式电站冬季运行冰害问题的有效措施之一。为研究抽水融冰对电站引水渠道冬季引水的水温控制规律,以红山嘴水电站为例,基于RNG κ-ε模型数值模拟研究结果,从热流量比角度探讨了渠道水温沿程衰减规律,并采用2013年2月和2014年1月原型观测结果进行了验证。结果表明:渠道水温沿程衰减过程可分为骤降段、过渡段和缓降段3部分,各段范围受外界条件控制;衰减曲线呈幂函数分布,相关系数达到98%;对比气温对渠温沿程衰减的影响表明,随着大气温度的降低,渠道水温沿程衰减速度明显加快;-10 ℃为水温衰减过程变化转折点,当气温高于-10 ℃时,可以近似认为渠温衰减规律一致,渠温沿程变化主要受到热流量比值影响;低于-10 ℃时,气温对渠道水温沿程变化影响显著。     

100MPa、800℃下Mo和W在流体／花岗质熔体相间分配的实验研究

利用“RQV-快速内冷淬火”（外加热冷封式）高温高压实验装置,在100MPa、800℃条件下,以东秦岭地区出露的高钾钙碱性岩浆岩（合峪花岗岩）为实验初始物,实验研究了Mo和W在花岗岩-H2O、花岗岩-NaCl（KCl）-H2O及花岗岩-NaF-H2O体系流体／熔体相间的分配行为。实验结果表明,Mo比W更倾向于分配进入流体相（DMo^流体/溶体〉〉DW^流体/溶体）,相对于纯水体系而言,流体介质中Cl和F的存在均有利于Mo和W向流体相迁移富集,随体系内Cl含量的不断增高,Mo和W的分配系数呈线性增大趋势,而在天然花岗岩可能含有的F含量范围之内,F含量的增高将阻碍Mo、W向流体相迁移,流体介质中Na／K（摩尔比）的变化对Mo和W的分配系数没有明显影响,表明体系碱质（Na或K）类型不是Mo和W在流体／熔体相间分配的主要影响因素。