Fine scale variations of surface water chemistry in an ephemeral to perennial drainage network

Although temporal variation in headwater stream chemistry has long been used to document baseline conditions and response to environmental drivers, less attention is paid to fine scale spatial variations that could yield clues to processes controlling stream water sources. We documented spatial and temporal variation in water composition in a headwater catchment (41 ha) at the Hubbard Brook Experimental Forest, NH, USA. We sampled every 50 m along an ephemeral to perennial stream network as well as groundwater from seeps and 35 shallow wells across varying flow conditions. Groundwater influences on surface water in this region have not been considered to be important in past studies as relatively coarse soils were assumed to be well drained in steep catchments with flashy runoff response. However, seeps displayed perennial discharge, upslope accumulated areas (UAA) smaller than those for channel initiation sites and higher pH, Ca and Si concentrations than streams, suggesting relatively long groundwater residence time or long subsurface flow paths not bound by topographic divides. Coupled with a large range in groundwater chemistry seen in wells, these results suggest stream chemistry variation reflects the range of connectivity with, and quality of, groundwater controlled by hillslope hydropedological processes. The magnitude of variations of solute concentrations seen in the first order catchment was as broad as that seen at the fifth order Hubbard Brook Valley (3519 ha). Reduction in variation in solute concentrations with increasing UAA suggested a representative elementary area (REA) value of less than 3 ha in the first order catchment, compared with 100 ha for the fifth order basin. Thus, the REA is not necessarily an elementary catchment property. Rather, the partitioning of variation between highly variable upstream sources and relatively homogenous downstream characteristics may have different physical significance depending on the scale and complexity of the catchment under examination. Copyright © 2012 John Wiley & Sons, Ltd.     

Seasonal and interannual variations of nitrate and chloride in stream waters related to spatial and temporal patterns of groundwater concentrations in agricultural catchments

Nitrate concentrations in streamwater of agricultural catchments often exhibit interannual variations, which are supposed to result from land‐use changes, as well as seasonal variations mainly explained by the effect of hydrological and biogeochemical cycles. In catchments on impervious bedrock, seasonal variations of nitrate concentrations in streamwater are usually characterized by higher nitrate concentrations in winter than in summer. However, intermediate or inverse cycles with higher concentrations in summer are sometimes observed. An experimental study was carried out to assess the mechanisms that determine the seasonal cycles of streamwater nitrate concentrations in intensive agricultural catchments. Temporal and spatial patterns of groundwater concentrations were investigated in two adjacent catchments located in south‐western Brittany (France), characterized by different seasonal variations of streamwater nitrate concentrations. Wells were drilled across the hillslope at depths ranging from 1·5 to 20 m. Dynamics of the water table were monitored and the groundwater nitrate and chloride concentrations were measured weekly over 2 years. Results highlighted that groundwater was partitioned into downslope domains, where denitrification induced lower nitrate concentrations than into mid‐slope and upslope domains. For one catchment, high subsurface flow with high nitrate concentrations during high water periods and active denitrification during low water periods explained the higher streamwater nitrate concentrations in winter than in summer. For the other catchment, the high contribution of groundwater with high nitrate concentrations smoothed or inverted this trend. Increasing bromide/chloride ratio and nitrate concentrations with depth argued for an effect of past agricultural pressure on this catchment. The relative contribution of flows in time and correlatively the spatial origin of waters, function of the depth and the location on the hillslope, and their chemical characteristics control seasonal cycles of streamwater nitrate concentrations and can influence their interannual trends. Copyright © 2004 John Wiley & Sons, Ltd.     

A method of catchments health assessment under value-pressure model and its application in urbanized river network area: A case study in Shanghai,China

Catchments health assessment is fundamental to effective catchments management. Generally, an as-sessment method should be selected to reflect both the purpose of assessment and local characteristics. A trial in Shanghai was conducted to test the method for catchments health assessment in urbanized river network area. Seven indicators that described four dimensions of river, river network, land use and function, and local feature were used to assess catchments values; while possible change rate of urbanization and industrialization in the next 3 years were chosen for catchments pressure assessment in the value-pressure model. Factors related to catchments classi-fication, indicators measurement and protection priority have been considered in the development strategies for catchments health management. The results showed that value-pressure assessment was applicable in urbanized catchments health management, particularly when both human and catchments had multiple demands. As a result of over 30-year rapid urbanization, more than 70% of Shanghai river network area was still in a healthy condition with high catchments values, among them, 39.3% was under high pressure. Poor water quality, simplified river system and weakened local feature of river pattern had largely affected catchments health in Shanghai. Lack of long-term monitoring data would seriously restrict the development and validity of catchments health assessment.     

Fine‐grained bed sediment storage within the main channel systems of the Frome and Piddle catchments,Dorset, UK

Lowland permeable catchments in the UK are particularly prone to sedimentation problems, on account of the increased fine sediment loadings generated by recent land‐use change and their stable seasonal hydrological regimes, which are frequently depleted by groundwater abstraction. Fine‐grained sediment storage on the bed of the main channel systems of the Frome (437 km²) and Piddle (183 km²) catchments, Dorset, UK, has been examined at 29 sites using a sediment remobilization technique. Measurements encompassed the period February 2003–July 2004. At individual sites in the Frome, average values ranged between 410 and 2630 g m^?2, with an overall mean of 918 g m^?2. In the Piddle, the average values for individual sites varied between 260 and 4340 g m^?2, with an overall mean of 1580 g m^?2. Temporal variations in fine bed sediment storage at each site were appreciable, with the coefficients of variation ranging between 43 and 155% in the Frome and between 33 and 160% in the Piddle. Average reach‐scale specific bed sediment storage increased markedly downstream along each main stem from 2 to 29 t km^?1 (Frome) and from 4 to 19 t km^?1 (Piddle). Total fine sediment storage on the channel bed of the Frome varied between 479 t (5 t km^?1) and 1694 t (17 t km^?1), with a mean of 795 t (7 t km^?1), compared with between 371 t (5 t km^?1) and 1238 t (14 t km^?1) with a mean of 730 t (9 t km^?1) in the Piddle. During the study period, fine bed sediment storage was typically equivalent to 18% (Frome) and 57% (Piddle) of the mean annual suspended sediment flux at the study catchment outlets. Copyright © 2006 John Wiley & Sons, Ltd.     

Hydrological modelling of Ethiopian catchments using limited data

The hydrological component of the soil and water assessment tool (SWAT) model is adapted for two Ethiopian catchments based on primary knowledge of the coherence spectrum between rainfall and stream flow data. Spectrum analysis using the available nearby climatic data is made to limit the temporal and spatial scales (inverse rate coefficients) subject to the calibration of compartmentalized runoff models. The exclusion of unwarranted time scales in the calibration implies that the model efficiency (r² values) decrease only moderately between calibration and validation, and the optimization is focused on warranted problems. On the basis of the available data for the two Ethiopian catchments, the implication is that only periods longer than about 50 days can be reliably evaluated in the model. The model structure of SWAT for the surface runoff and groundwater flow response is modified to make the time scales consistent with the results of the spectrum analysis. An optimization algorithm is developed to constrain and combine the model parameters with the spectrum analysis results. Copyright © 2009 John Wiley & Sons, Ltd.     

Runoff production processes in small alpine catchments within the unconsolidated Pleistocene sediments of the Lainbach area (Upper Bavaria)

In the Lainbach catchment, unconsolidated Pleistocene moraine sediments are widely distributed. Because of the great natural risk of floods, together with extreme loads of sediments, investigations of runoff production processes have been conducted in this area. At hillslope scale three test sites with different states of soil development and vegetation cover were instrumented with V‐shaped weirs, precipitation gauges and measurement devices for electrical conductivity (EC) of discharge water. The EC has been used as a geochemical tracer for hydrograph separation, since the statistical relationship between content of dissolved Ca²⁺, Mg²⁺ cations and EC is highly significant for different stages of runoff. This method allows hydrograph separation at high temporal resolution for both the rising and falling limb of the hydrograph. The following results of the investigations can be resumed. If relief conditions are similar, the effectiveness of runoff production decreases with an increasing density of vegetation cover. The runoff delivery ratio decreases as well as the peaks of runoff. In contrast, concentration times of hillslope catchments are equal, even if vegetation cover is of great density and soils are well developed. As a reason for the short reaction times, different runoff production processes have been detected. On bare ground, infiltration excess overland flow intensified by surface sealing processes is the main source for quick runoff. On hillslopes well covered by vegetation, translatory flow processes indicated by soil water with high solute contents force a rapid runoff reaction only a few minutes after rainfall has begun. It is to be assumed that translatory flow is a runoff production process typical for hillslopes covered by vegetation in a steep alpine relief. By means of the areal distribution of the topographic index, concentration of runoff production on a small part of the catchment has been demonstrated for hillslopes densely covered by vegetation. The investigations have shown that there is a lack of studies on runoff production processes in steep alpine relief, as well as a deficit of methods to quantify hydraulic properties of coarse‐grained soils with a wide grain size distribution. Copyright © 2003 John Wiley & Sons, Ltd.     

关于发展辽宁矿产资源综合利用、精深加工的思考

发展矿产资源的综合利用、精深加工是矿产资源有效保护、合理利用、可持续发展和矿业产业结构战略性调整中的一项重要任务。针对辽宁省矿产资源综合利用、精深加工的现状及面临的问题，本文提出应制定相应的法律，依法保障矿产资源利用、精深加工；定期发布辽宁省《矿产资源精深加工、综合利用目录》，公布鼓励开发生产的产品；制定配套的矿业政策；开展政府网络信息服务；建立基金制度；提高技术水平并引进技术；有关部门应重视、支持、配合，这样才能最终实现矿产资源和矿业经济的整体性可持续发展。     

Generation of realistic synthetic catchments to explore fine continental surface processes

Understanding, analysing, and predicting the erosion mechanisms and sedimentary flows produced by catchments plays a key role in environmental conservation and restoration management and policies. Numerical case-testing studies are generally undertaken to analyse the sensitivity of flood and soil erosion processes to the physical characteristics of catchments. Most analyses are conducted on simple virtual catchments with physical characteristics that, unlike real catchments, are perfectly controlled. Virtual catchments generally correspond to V-shaped valley catchments. However, although these catchments are suitable for methodical analysis of the results, they do not provide a realistic representation of the spatial structures of the landscape and field conditions. They can, therefore, lead to potential modelling errors and can make it difficult to extend or generalize their results. Our proposed method bridges the gap between real and traditional virtual catchments by creating realistic virtual catchments with perfectly controllable physical characteristics. Our approach represents a real alternative to traditional test case procedures and provides a new framework for geomorphological and hydrological communities. It combines a field procedural generation approach, geographic information system processing procedures, and the CAESAR-Lisflood landscape evolution model. We illustrate how each of these components acts in the process of generating virtual catchments. Five physical parameters were adjusted and tested for each virtual catchment: drainage density, hypsometric integral, mean slope of the main channel, granulometry, and land use. One of our virtual catchments is compared with a real catchment and a virtual catchment produced by a standard method. This comparison indicates that our approach can produce more realistic virtual catchments than those produced by more traditional methods, while a high degree of controllability is maintained. This new method of generating virtual catchments therefore offers significant research potential to identify the impacts of the physical characteristics of catchments on hydro-sedimentary dynamics and responses.     

Combining regression and spatial proximity for catchment model regionalization: a comparative study

Abstract

Spatial error regression is employed to regionalize the parameters of a rainfall–runoff model. The approach combines regression on physiographic watershed characteristics with a spatial proximity technique that describes the spatial dependence of model parameters. The methodology is tested for the monthly abcd model at a network of gauges in southeast United States and compared against simpler regression and spatial proximity approaches. Unlike other comparative regionalization studies that only evaluate the skill of regionalized streamflow predictions in ungauged catchments, this study also examines the fit between regionalized parameters and their optimal (i.e. calibrated) values. Interestingly, the spatial error model produces parameter estimates that better resemble the optimal parameters than either of the simpler methods, but the spatial proximity method still yields better hydrologic simulations. The analysis suggests that the superior streamflow predictions of spatial proximity result from its ability to better preserve correlations between compensatory hydrological parameters.

Editor D. Koutsoyiannis; Associate editor Y. Gyasi-Agyei     

Surface and subsurface water contributions to streamflow from a mesoscale watershed in complex mountain terrain

An understanding of surface and subsurface water contributions to streamflow is essential for accurate predictions of water supply from mountain watersheds that often serve as water towers for downstream communities. As such, this study used the end‐member mixing analysis technique to investigate source water contributions and hydrologic flow paths of the 264 km² Boulder Creek Watershed, which drains the Colorado Front Range, USA. Four conservative hydrochemical tracers were used to describe this watershed as a 3 end‐member system, and tracer concentration reconstruction suggested that the application of end‐member mixing analysis was robust. On average from 2009 to 2011, snowmelt and rainwater from the subalpine zone and groundwater sampled from the upper montane zone contributed 54%, 22%, and 24% of the annual streamflow, respectively. These values demonstrate increased rainwater and decreased snow water contributions to streamflow relative to area‐weighted mean values derived from previous work at the headwater scale. Young water (2.3 ± 0.8 months) fractions of streamflow decreased from 18–22% in the alpine catchment to 8–10% in the lower elevation catchments and the watershed outlet with implications for subsurface storage and hydrological connectivity. These results contribute to a process‐based understanding of the seasonal source water composition of a mesoscale watershed that can be used to extrapolate headwater streamflow generation predictions to larger spatial scales.