Precambrian Shield Wetlands: Hydrologic Control of the Sources and Export of Dissolved Organic Matter

Most Precambrian Shield forested catchments have some wetland component. Even small riparian wetlands are important modifiers of stream chemistry. Dissolved organic matter (DOM) is one of the most important products exported by wetlands in streams. Stratigraphic control of hydraulic conductivity generally leads to decreasing conductivity with depth. Thus important flowpaths occur in the uppermost organic rich layers and are reflected in chemical profiles of dissolved organic carbon (DOC). Accumulation of DOC in peat porewaters is the net effect of production, consumption and transport. DOC profiles vary with degree of interaction with the surrounding upland catchment and distance from the edge of the wetland as well as internal processes within the wetland. In wetlands, DOM production is offset by flushing resulting in decreasing DOC concentrations with increasing flows. Despite old carbon (2,000 to 3,000 years) at relatively shallow depths, 14C activity in DOC exported from wetlands is mostly modern (recent carbon), consistent with shallow flowpaths and export of DOM from shallow organic rich horizons. In contrast, the source area for DOM in upland catchments with developed B horizon soils increases with antecedent soil moisture conditions resulting in increasing DOC concentrations with higher stream flows. Activity of 14C in stream DOC from upland catchments span a range from low activities (older carbon) similar to B horizon soil water during dry moisture conditions to values slightly less than modern (more recent carbon) during high moisture conditions. The more modern carbon activities reflect the increased contribution of the organic rich litter and A horizon soil layers in the area immediately bordering the stream under wet antecedent moisture conditions. Reduced hydrologic export or loss of wetlands under drier climatic conditions may result in in larger fluctuations in stream DOC concentrations and reduced DOM loads to lakes.     

The effect of forestry drainage operations on upland sediment yields: The results of a storm-based study

The effects of pre-afforestation open ditching on the sediment yield of an upland catchment in the Southern Pennines, England are described. Marked increases in the production of suspended sediment following ploughing caused major pollution of a local reservoir. Sediment supply prior to ditching was limited and easily exhausted, but afterwards remained plentiful, allowing sustained erosion during periods of storm runoff. Large volumes of sediment were carried into the reservoir during the winter of 1980–81. More recently, exhaustion of supplies of loose material in the ditches and revegetation have led to a lower rate of sediment output.     

The effect of forestry drainage operations on upland sediment yields: A study of two peat-covered catchments

The suspended sediment yields of two adjacent, paired, catchments on blanket peat in mid-Wales were compared before and after preafforestation drainage works. Catchment A was ploughed whilst an adjacent catchment (B) was left unploughed. After eight months Catchment B was also ploughed. The ploughing strategy in both catchments was designed to minimize sediment loss. However, suspended sediment loss increased 2·5 times following ploughing in Catchment A, whilst no such increase occurred at this time in Catchment B. Subsequently, suspended sediment yields in Catchment B increased 4·8 times after it was ploughed. Organic sediment was lost mainly from furrow sides, and erosion pins showed maximum ground recession in summer, due to peat wastage. Summer desiccation prepared sediment for transport, and organic suspended sediment loads were highest in the autumn. Sediment loads were limited by vegetation colonization and some reduction in sediment loss was due to the presence of unploughed strips adjacent to stream courses.     

Impacts of land-use changes on watershed discharge and water quality in a large intensive agricultural area in Thailand

The objectives of this research were to evaluate the effect of land-use change on streamflow, sediment and water quality data along the Lower Yom River, Thailand, covering an intensively agricultural area of 14 613.6 km², and to assess the relative impact of point and non-point sources of pollution from multiple-land-use watersheds. Long-term calibration and validation of the SWAT (Soil and Water Assessment Tool) model was performed on data for 2000–2013. Land-use change led to a 13–49% increase in runoff in the basin and resulted in 37–427% increased sediment yield. The amount of NO₃-N load doubled in the upper and middle parts of the study area, while the increase in PO₄^3– ranged from 37 to 377%, reflecting the increase in agricultural lands and urban areas. It is concluded that the changed land use is closely associated with the quantity of runoff, sediment yield and the NO₃-N and PO₄^3– concentrations.     

Seasonal and storm flow dynamics of dissolved organic carbon in a Mediterranean mountain catchment (Vallcebre,eastern Pyrenees)

To improve understanding of DOC dynamics in seasonal Mediterranean environments, rainfall, soil water, groundwater and stream water samples were taken during a 27-month period in the Can Vila catchment (northeast Spain). Using these data, we characterized DOC dynamics in the different hydrological compartments and analysed the factors affecting them. We also analysed DOC dynamics during storm events and the factors that control DOC delivery to the stream. The results show some seasonality in rainwater and soil water DOC concentrations, while no clear seasonality was observed in stream water and groundwater, where DOC dynamics were strongly related to discharge and water table variations. For storm events with several discharge peaks, the slope of the discharge–DOC concentration relationship was higher for the first peak. The rather similar dynamics of stream water DOC concentration in all floods contrast with the observed diversity of hydrological processes. This raises the question of the origin of the observed rapid DOC increase.

EDITOR M.C. Acreman

ASSOCIATE EDITOR K. Heal     

Constant denudation rates in a high alpine catchment for the last 6 kyrs

Terrestrial cosmogenic nuclides (TCN) have widely been used as proxies in determining denudation rates in catchments. Most studies were limited to samples from modern active streams, thus little is known about the magnitude and causes of TCN variability on millennial time scales. In this work we present a 6 kyrs long, high resolution record of ¹⁰Be concentrations (n = 18), which were measured in sediment cores from an alluvial fan delta at the outlet of the Fedoz Valley in the Swiss Alps. This record is paired with a 3‐year time series (n = 4) of ¹⁰Be measured in sediment from the active stream currently feeding this fan delta. The temporal trend in the ¹⁰Be concentrations after correction for postdepositional production of ¹⁰Be was found to be overall constant and in good agreement with the modern river ¹⁰Be concentration. The calculated mean catchment‐wide denudation rate amounts to 0.73 ± 0.18 mm yr^?1. This fairly constant level of ¹⁰Be concentrations can be caused by a constant denudation rate over time within the catchment or alternatively by a buffered signal. In this contribution we suggest that the large alluvial floodplain in the Fedoz Valley may act as an efficient buffer on Holocene time scales in which sediments with different ¹⁰Be signatures are mixed. Therefore, presumable variations in the ¹⁰Be signals derived from changes in denudation under a fluctuating Holocene climate are only poorly transferred to the catchment outlet and not recorded in the ¹⁰Be record. However, despite the absence of high frequency signals, we propose that the buffered and averaged ¹⁰Be signal could be meaningfully and faithfully interpreted in terms of long‐term catchment‐averaged denudation rate. Our study suggests that alluvial buffers play an important role in regulating the ¹⁰Be signal exported by some alpine settings that needs to be taken into account and further investigated. Copyright © 2016 John Wiley & Sons, Ltd.     

滇池不同流域类型降雨径流对河流氮磷入湖总量的影响

通过对滇池三种不同流域类型的雨季初始期三场降雨径流的汇水河道的入湖口水质和流量监测 ,重点分析了典型城市纳污河流、城乡结合型河道和农业重污染区河道的营养盐携带状况与特征。研究结果表明 :不同流域类型河流的氮磷营养盐入湖总量受降雨过程及特征、流域类型特征、降雨径流流量、径流水营养盐浓度综合控制。城乡结合型河道 (大清河 )有最高的TP、KN (凯氏N)、NH3 N、NO3 N和NO2 N入湖总量 ,三场降雨累积量分别为11374 3、 12 7971 7、 85 36 5 4、 92 3 4和 84 1 2kg ;城市纳污河流 (乌龙河 )有最高的单位面积入湖总量负荷 ,TP、KN、NH3 N和NO2 N分别为 5 35 7、 5 86 0 5、 382 1 9和 2 4 6kg/km2 。     

新安江模型在资料匮乏的长江中下游山区中小流域洪水预报应用

水文资料匮乏流域的洪水预报(PUBs)是水文科学与工程中一个尚未解决的重大挑战.中国湿润山区中小流域大多是水文资料匮乏的流域,在此地区进行洪水预报的重要手段之一就是水文模型参数的估计.对基于参数物理意义的估算方法(以下简称物理估算法)及两种区域化方法进行了研究,将其用于新安江模型参数的估算及移植.皖南山区的29个中小流...     

MODELLING THE IMPACT OF LAND USE CHANGE ON WATER QUALITY IN AGRICULTURAL CATCHMENTS

Export coefficient modelling was used to model the impact of agriculture on nitrogen and phosphorus loading on the surface waters of two contrasting agricultural catchments. The model was originally developed for the Windrush catchment where the highly reactive Jurassic limestone aquifer underlying the catchment is well connected to the surface drainage network, allowing the system to be modelled using uniform export coefficients for each nutrient source in the catchment, regardless of proximity to the surface drainage network. In the Slapton catchment, the hydrological pathways are dominated by surface and lateral shallow subsurface flow, requiring modification of the export coefficient model to incorporate a distance–decay component in the export coefficients. The modified model was calibrated against observed total nitrogen and total phosphorus loads delivered to Slapton Ley from inflowing streams in its catchment. Sensitivity analysis was conducted to isolate the key controls on nutrient export in the modified model. The model was validated against long-term records of water quality, and was found to be accurate in its predictions and sensitive to both temporal and spatial changes in agricultural practice in the catchment. The model was then used to forecast the potential reduction in nutrient loading on Slapton Ley associated with a range of catchment management strategies. The best practicable environmental option (BPEO) was found to be spatial redistribution of high nutrient export risk sources to areas of the catchment with the greatest intrinsic nutrient retention capacity. © 1997 by John Wiley & Sons, Ltd.     

POTASSIUM CHEMISTRY OF A SMALL UPLAND STREAM FOLLOWING A MAJOR DROUGHT

Previously unpublished water quality data are used to explore the potassium chemistry of a small upland stream following the 1976 drought in England. The behaviour of potassium is a complex response to several factors: hydrological pathways operating during periods of storm runoff; sediment inputs; and the chemical properties of the transporting water. Analyses of ‘hysteresis loops’ for a series of storms show that the relationship between suspended sediment and potassium concentrations is not simple; spatial and temporal variations in surface and subsurface stormflow add complexity. In addition to the specific discussion of potassium, data are presented to show the recovery of stream discharge, and of sediment and solute concentrations during the immediate post-drought period. © 1997 by John Wiley & Sons Ltd.