离子类型对石油污染含水层中微生物去除苯的影响

近来利用微生物原位修复受石油污染的含水层已被广泛关注,然而地下水中含有许多离子成分,这些无机离子对微生物降解有机污染物的影响机制还不清楚。本文采用批量实验研究了淄博齐鲁石化污染地下水中常见的7种无机离子(NO3-、PO4 3-、SO4 2-、Cl-、Ca2+、Mg2+、Fe3+)对微生物生长及生物降解苯的影响规律,利用高通量测序技术进一步探究了苯降解菌的种群特征。结果表明：7种离子都存在一个最适宜微生物生长的离子浓度,低于或超过该浓度苯的去除率明显降低,其中NO3-、SO42-、Fe3+最适宜浓度为0. 4mmol/L,PO4 3-、Cl-、Ca2+、Mg2+最适宜浓度分别为0. 2mmol/L、0. 1mol/L、2. 5mmol/L、2mmol/L;从微生物含量及其变化幅度来看,地下水环境中的NO3-离子对微生物的生长及苯的去除影响最显著,其他离子的影响则较小,但微生物对Cl-的耐受浓度较高。高通量测序结果显示驯化出的苯降解菌主要属于脱硫弧菌属(Desulfovibrio sp)、脱硫芽胞弯曲菌属(Desulfosporosinus sp)、不动杆菌属(Acinetobacter sp)和假单胞菌属(Pseudomonas sp)中的菌株。研究结果可为石油污染地下水的原位生物修复提供一定的科学依据。     

非金属矿物材料及其发展现状与趋势

本文论述了矿物材料的定义、类型，矿物材料学的概念、研究内容和任务；介绍并分析了我国非金属材料的发展现状与趋势；指出发展我省非金属矿物材料产业，对振兴湖南经济有重要意义。     

无机高分子絮凝剂絮凝机制的研究进展

近年来无机高分子絮凝剂的研究已成为水处理药剂研究的热点。本文概述近年来无机高分子絮凝剂絮凝机理的研究进展 ,包括我们所最近研制的三系列含水聚硅酸铝铁钠废水净化剂 ,它们的优缺点及其絮凝机理。重点阐明研制絮凝剂时通常采用共存阴离子和活性硅酸与铝盐或 /和铁盐的聚合作用 ,并探索絮凝剂中各组分对絮凝剂的絮凝效果的贡献。     

畜禽粪肥中无机元素的测定与评价

采用干灰化法消解有机粪肥样品，利用ＩＣＡＰ法同时测定Ｂ、Ｂｅ、Ｃａ、Ｃｄ、Ｃｏ、Ｃｒ、Ｃｕ、Ｆｅ、Ｍｇ、Ｍｎ、Ｎｉ、Ｐ、Ｐｂ、Ｓｒ、Ｖ、Ｚｎ等元素。方法的检出限、准确度、精密度和回收率令人满意。     

Vegetation and soil characteristics of the wasteland of Valika Chemical Industries near Manghopir, Karachi

The vegetation of the wasteland of Valika chemical industries near Manghopir road, Karachi was studied. Nine plant communities were recognized based on dominant species. In these plant communities the vegetation was disturbed, mostly halophytic and dominated bySuaeda fruticosa,Tamarix indica,Salsola baryosma,Cressa cretica,Atriplex griffithii,Haloxylon recurvum,Indigofera hochstetteri,Prosopis julifloraandChenopodium album.The physico-chemical properties of the soils were also analysed. Soil texture was mostly sandy loam, which exhibited slight variations in the water-holding capacity. The soils contained a sufficient amount of CaCO₃⁻and exhibited mostly alkaline soil pH. The soils of the different plant communities had scarcely any organic matter or inorganic phosphorus. The exchangeable sodium in the soils of many halophytic plant communities was high, with appreciable concentrations of potassium.     

Variations and net transport of dissolved inorganic nutrients in the South Passage of the Changjiang （Yangtze River） Estuary

Dissolved inorganic nutrient elements were analyzed from the samples collected in the South Passage of the Changjiang (Yangtze River) Estuary in March 2003, including NH4 , NO3-, NO2- and PO43-. The water samples were collected with a Niskin sampler hourly at the near-surface, middle and near-bottom depths at the three stations -A1, A2 and A3-during two complete tidal cycles of neap tide and spring tide. Results showed that 1) the concentrations of NH4 , NO3- and NO2- were a little higher respectively during the neap tide than those during the spring tide, while PO43- showed an opposite trend, and each was higher in the ebb tide than in the flood tide, either for the neap tidal cycle or the spring tidal cycle; 2) higher stratification of the nutrients existed obviously in this area, with the concentrations of which increased from the bottom to the surface, especially for NH4 and NO3-; 3) the coefficient of variation (C.V.) values of all dissolved inorganic nutrients varied from 4.06% to 36.8% beyond different influences of the tidal current and Changjiang runoff; 4) with increasing suspended matter in the water column, the concentrations of PO43- became lower in the filtered water; and 5) the total transport of each tidal cycle was much more in the spring tide than in the neap tide, and the positive values indicated that the nutrients had been exported to the East China Sea. Studies on the variations and net transport of dissolved inorganic nutrients in the South Passage of the Changjiang Estuary will provide the scientific basis for the study of the mechanism of red tide in the East China Sea.     

Late Quaternary strata and carbon burial records in the Yellow River delta,China

Sediment carbon sequestration plays an essential role in mitigating atmospheric CO2 increases and the subsequently global greenhouse effect. To clarify the late Quaternary strata and carbon burial records in Yellow River delta(YRD), detailed analysis of benthic foraminifera, total carbon(TC), organic carbon(Corg), sedimentary characteristics and moisture contents of sediments, was performed on core ZK3, 30.3 m in length and obtained from YRD in 2007. Eight depositional units(designated U1-U8 in ascending order) were identified. A comprehensive analysis method of historical geography and sedimentary geology was used to determine the precise depositional ages of the modern Yellow River delta(MYRD), from which pre-MYRD ages were deduced. The results indicates that the maximum burial rates of TC, inorganic carbon(IC) and Corg occurred in the delta front(U5), and the minimum in the shallow sea(U3). Remarkable high sedimentation rates in the MYRD are responsible for burial efficiency of carbon, with an average rate of Corg burial reaching 2087±251 g(m2 yr)-1, and that of IC reaching 13741±808 g(m2 yr)-1, which are much higher than those of other regions with high contents of Corg. Therefore, YRD has a significant burial efficiency for carbon sequestration.     

沉积岩石学的室内研究方法综述*

为了正确、高效地完成沉积岩石学的研究内容,势必要求沉积岩石学的研究方法具多样性和先进性,并可在实践中不断完善和发展。作者着重阐述了沉积岩石学的室内研究方法,旨在为沉积岩石学研究者系统介绍合适的技术和手段。室内研究方法主要包括矿物成分与结构分析、无机与有机地球化学分析和其他实验方法。矿物成分与结构分析主要包括薄片鉴定、粒度分析、重矿物分析、激光拉曼光谱和荧光光谱分析、微区矿物识别和元素分析、阴极发光分析,以及X射线衍射、红外光谱和热谱分析。无机地球化学分析主要包括元素地球化学、风化强度的量化、稳定同位素分析和测年分析。有机地球化学分析主要包括总有机碳、岩石热解分析、镜质体分析、气相色谱分析和生物标志物色谱—质谱分析、非生物标志化合物和有机化合物稳定同位素组成分析等。此外,沉积岩石学的室内研究方法还包括磁性矿物学、物理和数值模拟、岩石地球物理方法和地质大数据方法等。新技术、新方法的应用和发展,是促进沉积岩石学发展的重要原因之一。     

天津平原区浅层地下水水化学特征及碳酸盐风化碳汇研究

大气 CO₂浓度在控制全球气候变化方面具有至关重要的作用,研究碳循环、CO₂收支平衡和精确评估是制定区域CO₂减排策略和寻找新的碳汇途径最重要的组成部分。碳酸盐风化碳汇是全球碳循环研究的一个重要方向。为此,本研究以天津平原区浅层地下水为研究对象,通过对地下水调查及水样的采集与分析,运用水化学分析方法分析了地下水水化学特征,并估算了地下水总储存量、DIC储量和碳酸盐风化碳汇量。研究结果表明:浅层地下水化学场自北部山前平原向南部冲积平原和滨海平原,呈现出自北而南和由北西向南东的水平水化学分带规律,地下水由低浓度的淡水、微咸水变为高浓度咸水,沿此方向水化学类型由HCO₃-Ca·Na·Mg→Cl·SO₄-Na→Cl·HCO₃-Na→Cl-Na型转变;淡水区、微咸水区和咸水区面积分别为733、3 034和6 564 km²。地下水水化学组分中Ca²⁺、Mg²⁺和 {\mathrm{HCO}}_3^{-}主要来源于碳酸盐的溶解作用。研究区浅层地下水总储存量为2 241 640万m³,总DIC储量为8.13×10⁶ t,总碳汇量为4.11×10⁶ t。研究区浅层地下水淡水区、微咸水区和咸水区地下水储存量分别为157 799万、6 245 936万和1 459 247万 m³,DIC浓度分别为19200、19200和19342 mg/L,DIC储量分别为0.67×10⁶、1.65×10⁶和0.58×10⁶ t,碳汇量分别为0.22×10⁶、0.90×10⁶和2.98×10⁶ t。沿地下水流向,DIC、储量和碳汇量的空间分布均呈现出由低到高的趋势。     

关中盆地地下水无机指标数据集(2015年度)

本数据集包含了2015年在关中盆地采集的200个地下水样品的位置信息、取样层位信息及33项无机地球化学成分测试结果信息。水质综合评价的结果按照地下水质量级别划分,除去10个空白水样,样品中Ⅱ类水2件,Ⅲ类水57件,Ⅳ类水56件,Ⅴ类水75件;按照地下水水质类型划分,淡水111件,半咸水71件,咸水8件。采样过程规范,测试结果均由具备国家认可资质的实验室测试完成,数据质量可靠。关中盆地从盆地边缘至盆地中心,地下水化学类型由HCO₃-Ca型经HCO₃-Ca·Mg·Na型转变为SO₄·Cl-Na型,呈明显的水平分带性规律。水质评价的结果表明,该时段关中盆地地下水质量状况较差,有68.9%的地下水不适于直接饮用。其中Ⅱ-Ⅲ类水主要分布在关中盆地的南部、西部和北部的局部地区;Ⅳ类水主要分布在渭河边、高陵县、泾阳县和乾县;Ⅴ类水主要分布在大荔县、蒲城县、富平县、阎良区、咸阳市区周边、三原县和礼泉县。本数据集可为研究关中盆地地下水循环演化等提供地球化学指标参考。