武汉市冬季灰霾期PM2.5中水溶性无机离子的特征

2018年1月,利用颗粒物采样器采集武汉市大气PM_2.5样品并进行水溶性无机离子（F^-、Cl^-、NO₃^-、SO₄^2-、Na⁺、NH₄⁺、K⁺、Mg²⁺、Ca²⁺）的分析.结果表明,NO₃^-、SO₄^2-、NH₄⁺是PM_2.5中最主要的3种水溶性无机离子,除Mg²⁺与Ca²⁺外,PM_2.5与WSⅡs （水溶性无机离子）之间的相关性显著,且移动源贡献占主导地位.阴阳离子平衡表明武汉市冬季灰霾期PM_2.5呈中性或弱酸性.通过混合单粒子拉格朗日综合轨迹模式模拟并采用分层聚类得出了4种主要的后向气流轨迹及相应的PM_2.5和水溶性离子浓度,结果表明区域传输对此次灰霾期影响较大.     

Geochemistry of shallow sediments in Guaymas Basin, gulf of California: hydrothermal gas and oil migration and effects of mineralogy

Offset of prograde hydrothermal alterations by retrograde reactions is evident in sediments from a piston core (PC6, 8 m long) from the Guaymas Basin, Gulf of California. Geochemical and mineralogical analyses of sediments and pore fluids show superimposed geochemical signals that indicate currently active reactions are modifying previously formed secondary solids. Hydrothermal barite was formed in a previously active flow channel between 150 and 250 cm depth. Hydrothermal gypsum is presently dissolving at depths > 780 cm, below which hydrothermal fluid flow is channeled by a secondary dolomite layer. Thermal stress of organic matter generates hydrothermal gas and petroleum having wide ranges of compositions and maturities. A significant amount of hydrothermally generated oil has been transported laterally through a porous debris flow (approx. 240 cm subbottom), overwhelming the indigenous bituminous matter. Water soluble petroleum constituents have disseminated throughout the cored sediments. From 400 to 700 cm depth the immature organic matter continues to experience thermally-enhanced diagenesis, and an even higher thermal stress has occurred at the bottom of the core. Enhanced bacterial degradation of organic matter has led to depletion of pore water sulfate and enrichment of ammonium (NH₄⁺) in both pore fluid and sediment, resulting in formation of NH₄⁺ bearing secondary clay minerals at depths below 780 cm.     

多元分析法在无机多组份光度分析中的应用

本文介绍了一些多元分析法,诸如多元线性回归、主成份分析、因子分析、偏最小二乘、聚类分析等方法的基本原理及各自的特点,并就这些方法的近代进展及在无机多组份光度分析中的应用作了综述。     

The saturation of calcite and aragonite in the Arctic Ocean

We report on the chemical saturation of CaCO₃ in the waters of the Arctic Ocean calculated from total alkalinity (A_T) and total dissolved inorganic carbon (C_T). Data based on four different expeditions are presented: International Arctic Ocean Expedition (IAOE-91), Arctic Ocean Section 94 (AOS94), Polarstern Arctic '96 expedition (ACSYS 96), and Joint Ocean Ice Study 97 (JOIS 97). The results show a lysocline at around 3500 m for aragonite and that most of the Arctic Ocean sea floor lies above the lysocline for calcite. The only anomaly is the low degree of saturation at the shelf break depth in the Canadian Basin seen in the sections of the AOS94 and JOIS 97 cruises, correlated with nutrient maxima and very low O₂ concentration, suggesting decomposition of organic matter. The insignificant variability in degree of saturation between the deep waters of the different basins in the Arctic Ocean indicates a very low sedimentation/remineralisation of organic soft matter.     

南沙群岛海域溶解无机磷的分布

根据“八五”,“九五”国家科技专项南沙群岛海域综合科学考察的现场调查资料,对该海域的溶解无机磷（PO4^3- -P）分布进行了分析。结果表明,南沙群岛东南部海域的PO4^3- -P含量高于其它海区;PO4^3- -P随深度的增加而增加,变化速度在50-100m范围内最大;周日变化随季节及站点的不同而不同。南沙群岛海域PO4^3- -P含量分布是物理过程和生物过程共同作用的结果。     

The reliability of the thermodynamic constants for the dissociation of carbonic acid in seawater

Laboratory measurements of all four CO₂ parameters [f_CO2 ( = fugacity of CO₂), pH, TCO₂ ( = total dissolved inorganic carbon), and TA ( = total alkalinity)] were made on the same sample of Gulf Stream seawater (S = 35) as a function of temperature (5–35 °C) and the ratio of TA/TCO₂ (X) (1.0–1.2). Overall the measurements were consistent to ±8 μ atm in f_CO2, ± 0.004 in pH, ± 3 μ mol kg⁻¹ in TCO₂, and ± 3 μ mol kg⁻¹ in TA with the thermodynamic constants of Goyet and Poisson (1989), Roy et al. (1993), and Millero (1995). Deviations between the measured pH, TCO₂, TA and those calculated from various input combinations increase with increasing X when the same constants are used. This trend in the deviations indicates that the uncertainties in pK₂ become important with increasing X (surface waters), but are negligible for samples with the lower X (deep waters). This trend is < 5 μ mol kg⁻¹ when the pK₂ values of Lee and Millero (1995) are used.The overall probable error of the calculated f_CO2 due to uncertainties in the accuracy of the parameters (pH, TCO₂, TA, pK₀, pk₁, and pK₂) is ± 1.2%, which is similar to the differences between the measured values and those calculated using the thermodynamic constants of Millero (1995).The calculated values of pK₁, (from f_CO2-TCO₂-TA) agree to within ± 0.004 compared to the results of Dickson and Millero (1987), Goyet and Poisson (1989), Roy et al. (1993), and Millero (1995) over the same experimental conditions. The calculated values of pK₂ (from pH-TCO₂-TA) are in good agreement (± 0.004) with the results of Lee and Millero (1995) and also in reasonable agreement (± 0.008) with the results of Goyet and Poisson (1989), Roy et al. (1993), and Millero (1995). The salinity dependence of our derived values of pK₁ and pK₂, (S = 35) can be estimated using the equations determined by Millero (1995).     

Nutrient Concentrations are High in the Turbid Waters of the Colorado River Delta

We studied the seasonal change of the spatial distribution of nitrite (NO^-₂), nitrate (NO^-₃), reactive phosphate (PO^3-₄), and silicate (SiO₂) in the Colorado River Delta. We also generated 24-h time series at one location to study their short-period variability. The delta is a negative estuary. During summer, salinity may be as high as 40. Amplitude of spring tides is as large as 9 m, and this causes great water turbidity by sediment resuspension. Nutrient concentrations were high throughout the whole year, with lower values towards the oceanic region. Maximum nutrient values in the river delta were 15, 53, 11·5 and 92 μM, for NO^-₂, NO^-₃, PO^3-₄, and SiO₂, respectively. Most values were under 2, 40, 5, and 60 μM, for NO^-₂, NO^-₃, PO^3-₄, and SiO₂, respectively. Our nutrient data show no clear seasonal pattern. Possibly, high NO^-₃ values in the delta are due to groundwater input, mostly at the internal extreme, and high NO^-₂, PO^3-₄, and SiO₂ values are due to resuspension of sediments and mixing of porewaters with the water column, caused mainly during spring tides. In the case of NO^-₂, oxidation of NH⁺₄ in the water column would be part of the mechanism. This would explain the high negative correlation between NO^-₃ and sea-level, and the relatively low correlation between the other nutrients and sea-level, for the time series generated at a single location.     

海洋大气气溶胶的离子色谱分析

对分析方法如采样滤膜的均匀性，滤膜上阴，阳离子的萑萃取率，方法的精密度和检出限等进行了基础性研究，并采用该方法测定了厦门海域大气中的Ｃｌ＾－，Ｆ＾－，ＳＯ＾２－４，ＮＯ＾－３，ＮＨ＾＋４和Ｎａ＾＋。本文法有较高的灵敏度，重现性好，可同时测定多种无机离子，适用于海洋大气气溶胶分析。     

海水养殖与生态环境关系的研究——Ⅰ.无机氮对浮游植物生长的影响

采用中尺度受控生态实验、小型混养实验和虾池取样测定,研究海水中无机氮、N/P比值和藻类光合作用速率的变化规律,分析了无机氮和溶解有机氮(DON)的相互转化,比较了钙质角毛藻对不同形式无机氮的吸收,探讨了人工养殖海水中无机氮对浮游植物生长的影响。