Thermonuclear reaction rates from (p,n) reactions on targets withA = 92–122

From the experimentally measured (p,n) cross-sections for^92,94Zr,⁹³Nb,^95,96,98Mo,¹⁰³Rh,^107,109Ag,¹¹⁰Pd,¹¹⁵In,^117,122Sn nuclides, for proton energies below 7 MeV, thermonuclear reaction rates in the temperature range 1≤T ₉≤5(T₉=10⁹ K) have been extracted. These reaction rates have been fitted to a three parameter empirical expression proposed by Fowler.     

Sulfide intrusion in the tropical seagrasses Thalassia testudinum and Syringodium filiforme

Sulfur and oxygen dynamics in the seagrasses Thalassia testudinum and Syringodium filiforme and their sediments were studied in the US Virgin Islands (USVI) in order to explore sulfide intrusion into tropical seagrasses. Four study sites were selected based on the iron concentration in sediments and on proximity to anthropogenic nutrient sources. Meadow characteristics (shoot density, above- and below-ground biomass, nutrient content) were sampled along with sediment biogeochemistry. Sulfide intrusion was high in T. testudinum, as up to 96% of total sulfur in the plant was derived from sediment-derived sulfides. The sulfide intrusion was negatively correlated to the turnover of sulfides in the sediments regulated by both plant parameters and sediment sulfur pools. Sediment iron content played an indirect role by affecting sulfide turnover rates. Leaf production was negatively correlated with sulfide intrusion suggesting that active growth reduced sulfide intrusion. Sulfide intrusion was lower in S. filiforme (up to 44%) compared to T. testudinum consistent with a higher internal nighttime oxygen concentrations found for S. filiforme. When S. filiforme can take advantage of its ability to maintain high internal oxygen concentrations, as was the case on the USVI, it could increase its success in colonizing unvegetated disturbed sediments with potentially high sulfide concentrations.     

Anthropogenic lead concentrations and sources in Baltic Sea sediments based on lead isotopic composition

The Gulf of Gdańsk is influenced by heavy metals of anthropogenic origin. In this study, temporal concentration changes of Pb, Zn, Cd, and Cu were studied in six, 50 cm long sediment cores. The main aim of the study was to concentrate on the history of Pb fluxes and Pb isotopic composition (²⁰⁶Pb/²⁰⁷Pb and ²⁰⁸Pb/²⁰⁶Pb) to trace Pb sources. The lowest Pb concentrations (19 μg g⁻¹) were measured in sediments deposited circa 1860, while the highest Pb concentrations (63–147 μg g⁻¹) were measured in sediments deposited between 1960s and 70s. Pre-industrial Pb fluxes were 7 Pb m² year⁻¹, while after WWII they reached 199 Pb m² year⁻¹. Highest ²⁰⁶Pb/²⁰⁷Pb ratios (∼1.22) were measured in the oldest sediment layers, and the lowest ²⁰⁶Pb/²⁰⁷Pb ratios (∼1.165) were measured in the sediments deposited in 1970s–90s. During the period of highest Pb contamination, the anthropogenic Pb fraction reached up to 93%. A general discussion of the Pb sources, emissions, and loads for Poland is included.     

On the prediction of the Toce alpine basin floods with distributed hydrologic models

With the objective of improving flood predictions, in recent years sophisticated continuous hydrologic models that include complex land‐surface sub‐models have been developed. This has produced a significant increase in parameterization; consequently, applications of distributed models to ungauged basins lacking specific data from field campaigns may become redundant. The objective of this paper is to produce a parsimonious and robust distributed hydrologic model for flood predictions in Italian alpine basins. Application is made to the Toce basin (area 1534 km²). The Toce basin was a case study of the RAPHAEL European Union research project, during which a comprehensive set of hydrologic, meteorological and physiographic data were collected, including the hydrologic analysis of the 1996–1997 period. Two major floods occurred during this period. We compare the FEST04 event model (which computes rainfall abstraction and antecedent soil moisture conditions through the simple Soil Conservation Service curve number method) and two continuous hydrologic models, SDM and TDM (which differ in soil water balance scheme, and base flow and runoff generation computations). The simple FEST04 event model demonstrated good performance in the prediction of the 1997 flood, but shows limits in the prediction of the long and moderate 1996 flood. More robust predictions are obtained with the parsimonious SDM continuous hydrologic model, which uses a simple one‐layer soil water balance model and an infiltration excess mechanism for runoff generation, and demonstrates good performance in both long‐term runoff modelling and flood predictions. Instead, the use of a more sophisticated continuous hydrologic model, the TDM, that simulates soil moisture dynamics in two layers of soil, and computes runoff and base flow using some TOPMODEL concepts, does not seem to be advantageous for this alpine basin. Copyright © 2006 John Wiley & Sons, Ltd.     

Assessing the impact of the hydraulic properties of a crusted soil on overland flow modelling at the field scale

Soil surface crusts are widely reported to favour Hortonian runoff, but are not explicitly represented in most rainfall‐runoff models. The aim of this paper is to assess the impact of soil surface crusts on infiltration and runoff modelling at two spatial scales, i.e. the local scale and the plot scale. At the local scale, two separate single ring infiltration experiments are undertaken. The first is performed on the undisturbed soil, whereas the second is done after removal of the soil surface crust. The HYDRUS 2D two‐dimensional vertical infiltration model is then used in an inverse modelling approach, first to estimate the soil hydraulic properties of the crust and the subsoil, and then the effective hydraulic properties of the soil represented as a single uniform layer. The results show that the crust hydraulic conductivity is 10 times lower than that of the subsoil, thus illustrating the limiting role the crust has on infiltration. Moving up to the plot scale, a rainfall‐runoff model coupling the Richards equation to a transfer function is used to simulate Hortonian overland flow hydrographs. The previously calculated hydraulic properties are used, and a comparison is undertaken between a single‐layer and a double‐layer representation of the crusted soil. The results of the rainfall‐runoff model show that the soil hydraulic properties calculated at the local scale give acceptable results when used to model runoff at the plot scale directly, without any numerical calibration. Also, at the plot scale, no clear improvement of the results can be seen when using a double‐layer representation of the soil in comparison with a single homogeneous layer. This is due to the hydrological characteristics of Hortonian runoff, which is triggered by a rainfall intensity exceeding the saturated hydraulic conductivity of the soil surface. Consequently, the rainfall‐runoff model is more sensitive to rainfall than to the subsoil's hydrodynamic properties. Therefore, the use of a double‐layer soil model to represent runoff on a crusted soil does not seem necessary, as the increase of precision in the soil discretization is not justified by a better performance of the model. Copyright © 2005 John Wiley & Sons, Ltd.     

广西凌云县地下水资源量评价

为研究广西凌云县地下水资源状况,在分析区内地质构造、岩溶发育特征、含水介质及水动力条件的基础上,采用降水入渗系数法和枯季径流模数法分别对凌云县地下水天然补给量和可开采资源量进行评价,并对地下水资源空间分布特征进行分析。结果表明: 全区地下水多年平均天然补给量112 619.73万m³/a,其中岩溶地下水多年平均天然补给量69 797.68万m³/a,基岩裂隙水多年平均天然补给量为42 822.05万m³/a,可开采资源量为9 840.37万m³/a。区内岩溶发育较强烈,岩溶形态丰富,岩溶发育在垂向上具有一定分带性,高程跨度大,地下水资源空间分布总体相对较为均匀。研究成果为凌云县地下水资源可持续开发利用提供了科学依据。     

Maximized erosion at the last glacial maximum revealed by thermoluminescence thermochronometry

Increased erosion rates during the last 2 Myr of Earth history are commonly associated with widespread glaciation and global cooling. However, whether erosion rates actually increased during that period of time remains debated. This is in part because the respective role of fluvial and glacial erosion is difficult to assess, and because many existing techniques used to estimate erosion rates may be affected by averaging biases that may produce increased erosion rates towards the present. Here, we apply thermoluminescence thermochronometry to granitic bedrock samples of the southern-central Chilean Andes, a region which experienced a full transition from glacial-humid to fluvial-dry conditions during the Quaternary. Inverse modelling of the thermochronological data enables us to extract unbiased time series of erosion rates during the last ∼100 kyr. We find that erosion rates were systematically higher during around the last glacial maximum than at present, with differences exceeding an order of magnitude. Our findings indicate that glacial erosion is probably more efficient than fluvial erosion and imply that erosion has remained transient during the Quaternary.     

基于Richards传导方程的降雨型浅层滑坡稳定性分析

基于描述流体在多孔介质中毛细传导行为的Richards方程,Iverson（2000）推导了斜坡中任意深度处的孔隙水压力对降雨入渗的响应方程,本文在此基础上进一步推导了降雨型浅层滑坡稳定性计算表达式。该表达式考虑了坡体非饱和区饱和度和坡体重度在降雨入渗过程中的变化。算例结果表明：降雨入渗过程中浅层滑坡稳定性系数逐渐降低,且在降雨停止后的较短时间内达到最小值,之后逐渐增大,但增大速率比降低速率要低。这种变化趋势在不同初始地下水位竖向埋深情况下是一致的,但稳定性系数随初始地下水位竖向埋深增大而减小。降雨历时和降雨入渗率对浅层滑坡的稳定性均有显著影响,表现为降雨历时和降雨入渗率越长（大）,稳定性系数降低幅度越大,但后者的影响受到滑坡体竖向渗透系数的控制。     

一种用于突发性场地污染模拟的解析模型

为了及时有效地应对各种突发性环境污染事故,有必要开发一种简单实用、适于各类型污染物的场地污染数学模型。通过污染事故发生后污染物在包气带、饱和带迁移转化的概化,建立了污染物运移的自由入渗模型以及降雨入渗模型并给出各自相应的解析解。无降雨时,考虑污染物在重力作用下随包气带向下渗透的作用,建立一维垂直入渗模型。有降雨时,考虑污染场地（包气带）中污染物迁移和转化的对流作用、扩散作用及挥发、生物降解、吸附、根系吸收等作用,建立包气带剖面二维溶质运移模型和饱和带平面二维溶质运移数学模型。建模过程中,假定降雨量的平均分布及土壤质地、水力参数以及有机物成分、种类均相同,同时假定污染物与多孔介质间的作用为线性吸附,植物根系对污染物的吸附遵循一级动力学。基于模型的解析解,实现案例的模拟计算。模拟结果表明：该模型具有适用范围广、模拟高效快捷等优点,能够较准确预测污染发生后污染物在土壤中的动向、到达饱和带的时间以及饱和带中污染物的迁移情况。