硅酸盐细菌GY92对伊利石的释钾作用

1992年在贵阳郊区玉米地中分离出一株硅酸盐细菌GY92,为探求GY92对伊利石的释钾作用,对采用的有关材料和方法、相关实验所获的GY92个体形态及培养特征、部分生理生化特征及其对伊利石的释钾作用等结果作了较详细的介绍,同时就GY92对伊利石的释钾机理等问题进行了简单讨论。     

晋城矿区无烟煤层中泥岩夹矸的变化特征及成因探讨

通过研究无烟煤层中泥岩夹矸的岩石矿物学特征，探讨其主要成分高岭石发生转化的主要方向及影响因素。对晋城矿区实地观测，并采集一定量的标本，通过显微镜下鉴定、差热分析、X射线粉晶衍射分析、红外吸收光谱分析等研究，发现无烟煤层泥岩夹矸中高岭石主要向伊利石转化，并有伊利石-蒙脱石(I／M)混层矿物及蒙脱石出现。煤的变质程度升高、夹矸矿物转化的主要原因是区域变质作用及周围介质条件的影响。     

长沙—澧陵—浏阳—带冷家溪群及板溪群的甚低级变质作用

湘东长沙-澧陵-浏阳一带中晚元古宇的冷家溪群及板溪群遭受了区域甚低级变质作用.在本地区所采的＜2μm的样品中,冷家溪群伊利石结晶度的Kübler指数为0.18～0.26°△2θ,板溪群为0.21～0.28°△2θ(Kisch国际标样校正).从而可把本地区冷家溪群的区域变质划归浅变质带和近变质带上部,温度大约为280～400℃.板溪群划归近变质带上部,温度大约为250～300℃.并未普遍达到目前人们认为的绿片岩相或者是低绿片岩相.样品中冷家溪群伊利石(白云母)b0值的范围在0.8999～0.9042 nm,板溪群为0.9018～0.9042nm.由冷家溪群b0频率累积曲线图,得出本区冷家溪群处于较典型的中压区.     

田黄萝卜纹的矿物组成与成因分析

萝卜纹是田黄的重要鉴定特征。本文通过岩石薄片、X射线衍射分析和电子探针分析等手段,确定萝卜纹的组成矿物为伊利石;萝卜纹的成因为田黄的原岩受到构造应力作用后产生了显微裂隙,次生的伊利石填充了显微裂隙;显微裂隙中的伊利石与岩石中的主要矿物迪开石光学性质差别较大而呈丝缕状(萝卜纹)。     

不同颜色青海软玉微观形貌和矿物组成特征

青海软玉颜色丰富,近年来对青海软玉矿物学的研究不少,但针对不同颜色青海软玉矿物学特征的研究还存在欠缺。本文利用偏光显微镜、扫描电子显微镜、电子探针及粉晶X射线衍射仪器,从透闪石微形貌特征、微观结构、矿物组成及结晶度四个方面,研究了青海软玉颜色与矿物学特征的对应关系。结果表明:白玉、烟青玉、糖玉中透闪石主要为纤维状,显微纤维变晶结构,结晶度为96. 12%～96. 88%;青白玉和翠青玉中透闪石主要为叶片状,显微叶片变晶结构,结晶度为97. 35%,97. 32%;青玉和碧玉中透闪石主要为叶片状,显微叶片-隐晶质变晶结构,结晶度为95. 48%,95. 29%;黄玉中透闪石主要为柱状,显微柱状变晶结构,结晶度为97. 84%。青海软玉主要组成矿物均为透闪石,含量在95%以上,部分次要矿物如翠青玉中的榍石、黄玉中的钙长石、青玉中的菱镁矿、碧玉中的铬铁矿、糖玉中的斜黝帘石只出现在特定颜色的青海软玉样品中。研究认为不同颜色青海软玉矿物学特征确实存在差异,这些特征为研究不同颜色青海软玉成矿环境及成矿条件提供了科学依据。     

Adsorption of Pentachlorophenol onto Oxide and Clay Minerals： Surface Reaction Model and Environmental Implications

The adsorption of pentachlorophenol （PCP） onto quartz, kaolinite, illite, montmorillonite and iron oxides has been investigated by batch equilibrium techniques. The pH-dependent isotherms are curves with peak values, the position of which is at about pH = 5-6 depending on the mineral species. Based on distribution of both speciation of surface hydroxyls on minerals and PCP in solution a surface reaction model involving surface complexation and surface electrostatic attraction is presented to fit the pH-dependent isotherms, and both reaction constants are calculated. The results show that on quartz and phyllosilicate minerals the predominant adsorption reaction is surface complexation, meanwhile both of surface electrostatic attraction and surface complexation are involved on the iron oxide minerals. The reaction constants of surface electrostatic adsorption are usually one to three orders in magnitude, larger than that of surface complexation. The concentration-dependent isotherms can be well fitted by Langmnir equation with the correlation coefficient R〉0.93 for kaolinite and iron oxides. The maximum adsorption is found in the order： hematite 〉 lepidocrocite 〉 goethite 〉 kaolinite 〉 quartz 〉 montmorillonite ≈ illite, which can be interpreted by consideration of both reaction mechanism and surface hydroxyl density. The significant adsorption of PCP onto mineral surfaces suggests that clay and iron oxide minerals will play an important role as HIOCs are adsorbed in laterite or latertoid soil, which is widespread in South China.     

伊利石矿床成因类型及应用

伊利石矿是一种粘土类矿产,其成因类型多样,应用领域广泛,本文主要对伊利石的成因类型及主要应用领域进行初步的探讨.     

塔里木盆地早二叠世岩浆特征及其对油气成藏关系初探

塔里木盆地早二叠世裂谷盆地阶段有一次强烈的岩浆活动,主要为玄武岩—中酸性凝灰岩喷发和大规模基性岩墙群的侵入,玄武岩K-Ar法同位素年龄为241~278Ma,而辉长岩的Sm-Nd法年龄为259Ma。火山活动产生的能量使得塔里木盆地内的寒武系—奥陶系烃源岩大量生烃并运移,自生伊利石K-Ar年龄测定数据显示哈得4石炭系油藏、塔中4CⅢ油藏油气充注时间为224~275Ma,与上述火成岩的活动时间相当。东河砂岩,一套深埋的优质储层,其形成的原因可能是二叠纪末油气的注入并导致其后期深埋时只有机械压实而无其他成岩作用的缘故。     

A white mica crystallinity study of the Berwyn Hills, North Wales

Abstract White mica crystallinity studies have been carried out on 90 samples of mudrocks, six of spotted slate, and five of accretionary lapilli tuff from the area around the Berwyn Hills, North Wales. Strain was measured for some of the spotted slate and tuff samples. The metamorphic grade increases from southeast to northwest, with values of the Kübler index varying from 0.64 to 0.20Δ2θ. Metamorphic zonal boundaries follow the strike of bedding and cleavage, but crystallinity values increase into stratigraphically younger rocks on the northwest side of the Berwyn Dome. This effect is attributed mainly to a rapid increase in the thickness of synmetamorphic overburden to the northwest, comprising exposed Silurian turbidites and inferred Lower Devonian non-marine sediments. Strain variations have a more local influence on crystallinity, and lateral variations in the contemporary geothermal gradient cannot be ruled out. However, only with unrealistically high gradients would the need for a thick Lower Devonian component to the overburden be removed. This reasoning implies that the metamorphic peak was coeval with the Acadian (late Caledonian) event, rather than with an early diastathermal event.