云南腾冲地块北部空树河组一个菱铁矿结核中的C、O同位素变化特征

空树河组是滇西腾冲地块北部的石碳－二叠纪冈瓦纳相沉积。菱铁矿结核见于该组顶部的黑色泥岩中。将一个结核通过中心切开，在切面上由中心向边缘用牙钻等间隔提取10个样品。同位素测试结果显示，δ^13C自中心向边缘逐渐由－8．09％减为－16．12％，最外一个样例外（－15．39‰），而δ^18O自中心向边缘逐渐由－10．64‰增加为0‰左右。δ^13C的变化情况表明，菱铁矿结核可能形成于硫酸盐还原带。在解释δ^18o的变化情况时，推测在结核开始生长时可能有δ^18O亏损的大气降水掺入，随着埋藏深度的逐渐加大，孔隙水的O同位素逐渐趋近正常海水的值（0‰）。     

Column Amounts of ClONO2, HCl, HNO3, and HF from Ground-Based FTIR Measurements Made Near Kiruna, Sweden, in Late Winter 1994

During SESAME phase I ground-based FTIR measurements were performed atEsrange near Kiruna, Sweden, from 28 January to 26 March 1994. Zenith columnamounts of ClONO₂, HCl, HF, HNO₃,O₃, N₂O, CH₄, and CFC-12 werederived from solar absorption spectra. Time series of ClONO₂and HCl indicate a chlorine activation at the end of January and around 1March. On 1 March a very low amount of HCl of 2.09times; 10¹⁵molec. cm^-2 was detected, probably caused by a second chlorineactivation phase starting from an already decreased amount of HCl. The ratioof column amounts of HCl to ClONO₂ decreased inside the vortexfrom about 1 in January to 0.4 in late March compared to values of about 2outside the vortex. Although the Arctic stratosphere was rather warm in winter1993/94 and PSCs occurred seldom, chlorine partitioning into its reservoirspecies HCl and ClONO₂ changed during that winter andClONO₂ is the major chlorine reservoir at the end of thewinter as in cold winters like 1991/92 and 1994/95.     

库车盆地西北缘下第三系碳、氧同位素特征及成岩环境

库车盆地西北缘及柯坪地区下第三系碳酸盐岩稳定同位素分析结果显示氧同位素组成在相对较小的范围内变化，而碳同位素组成变化很大。沉积学研究表明塔拉克组和小库孜拜组海相地层主要为潮坪、萨布哈和渴湖相沉积，在成岩过程中或成岩期后，沉积物不同程度地受到了淡水作用的影响。所分析的样品大部分形成于大气淡水成岩环境，富集１２Ｃ，δ１３Ｃ为正值的样品一般形成于海水成岩环境。稳定同位素分析是研究成岩作用的有效手段之一。     

松辽盆地白垩系的密集段及海水进侵的新证

在总结松辽盆地白恶系层地层特征的基础上，阐述了密集段的地质学和地球物理学标志，经分析，大多数重要反射与密集段相关而并非是层序边界，根据扫描电镜分析结果，在密集段中首次发现了钙质超微化石，为区内白垩纪海水进侵的提供了新的证据，由稳定同位素分析，密集段形成了缺氧，相对可容纳空间最大及水体最深时期。     

Oxygen Isotope Exchange Kinetics Between Coexisting Minerals and Water in the Aral Granite Pluton of the Altay Mountains, Northern Xinjiang

Coexisting quartz, feldspar and biotite vary widely in their δ18O values and display a remarkable 18O/16O disequilibrium relation; especially, a quartz-feldspar reversal (△ 18OQUartz_feldspar< 0) exsists in the Aral granite pluton of the Altay Mountains, northern Xinjiang. The 18O / 16O exchange reaction definitely occurred between granite and water. Initial δ18O values of the granite and exotic fluid are evaluated by the mass balance consideration. The conventional method of discrimination between various magma derivations simply with δ18O values of either whole rock or separate minerals is misleading and unreliable. Experiments carried out by the authors show that the 18O / 16O exchange reaction is not accompanied by what geologists describe as petrological and mineralogical alteration effect. This decoupling relation implies that exchange reaction occurs at a relatively high temperature during subsolidus-postmagmatic cooling of magmas. The exchange mechanism is mainly diffusion-controlled. It is     

中国东部寒武系与奥陶系界线地层的碳氧同位素研究

对我国东部不同地层区一些代表性的寒武系-奥陶系界线层位开展了碳?氧同位素研究?结果表明,由于沉积环境差异和成岩蚀变影响,界线层位的δ18O值变化较大,规律性不明显,δ13C值变化虽小,但在界线处均发生不同程度漂移?漂移的层位与寒武纪-奥陶纪主要生物群面貌变化的界线相一致?综合各方面资料分析,笔者认为,碳同位素组成的漂移很可能由晚寒武世到早奥陶世时期内海平面的升降所引起.     

Genesis of Kanggur Gold Deposit in Eastern Tianshan Orogenic Belt, NW China: Fluid Inclusion and Oxygen and Hydrogen Isotope Constraints

Abstract. Primary fluid inclusions in quartz and carbonates from the Kanggur gold deposit are dominated by aqueous inclusions, with subsidiary CO₂-H₂O inclusions that have a constant range in CO₂ content (10–20 vol %). Microthermometric results indicate that total homogenization temperatures have a wide but similar range for both aqueous inclusions (120 to 310C) and CO₂-H₂O inclusions (140 to 340C). Estimates of fluid salinity for CO₂-H₂O inclusions are quite restricted (5.9∼10.3 equiv. wt% NaCl), whereas aqueous inclusions show much wider salinity ranging from 2.2 to 15.6 equivalent wt %NaCl.
The 6D values of fluid inclusions in carbonates vary from -45 to -61 %, in well accord with the published δD values of fluid inclusions in quartz (-46 to -66 %). Most of the δ¹⁸O and δD values of the ore-forming fluids can be achieved by exchanged meteoric water after isotopic equilibration with wall rock by fluid/rock interaction at a low water/rock ratio. However, the exchanged meteoric water alone cannot explain the full range of δ¹⁸O and δD values, magmatic and/or meta-morphic water should also be involved. The wide salinity in aqueous inclusions may also result from mixing of meteoric water and magmatic and/or metamorphic water.     

古海洋溶解氧研究方法综述

介绍了国内外在古海洋溶解氧研究领域内的主要方法和动态，并分别对沉积构造法、沉积硫法、同位素法、微量元素法、稀土元素法、有机地球化学法及古生态法等研究方法进行了全面的分析和评论，指出,古海洋溶解氧含量重建对于理解大洋循环、古气候、生物绝灭、地质事件以及有机质演化具有十分重要的科学意义，它有赖于溶解氧含量的替代性指标的建立、富氧问题研究的进一步深入以及综合分析气圈、水圈、沉积圈、生物圈等各子系统内部及它们之间氧的物质输送和转化。