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排序方式: 共有603条查询结果,搜索用时 62 毫秒
301.
金刚石中晶格氢的UHF法计算分析 总被引:1,自引:0,他引:1
对金刚石中晶格氢进行了UHF法计算,结果表明,空穴吸引1~4个氢原子均可以稳定存在。空穴具有吸引较多氢原子在其周围的倾向,最多可以达到4个氢原子。当空穴吸引1个氢原子时,氢原子倾向于直接存在于碳晶格空穴中,不改变化学键的键长,即以顺磁性氢的状态存在时更为稳定。 相似文献
302.
钻井现场有机地球化学录井与油气识别评价技术 总被引:1,自引:3,他引:1
在现场钻进过程中,尤其是在油基泥浆及各种添加剂烃类污染、地质录井难以确定真假油气显示的情况下,有机地球化学录井对确定油气显示有独特的作用。但由于其烃类污染对岩屑罐顶气、岩石冷溶烃、岩石热解等常规地球化学录井技术有不同程度的影响,其检测数据通过校正污染后才能用于含油气性评价。为此,在现场开展了钻井泥浆及各种添加剂中烃类有机地化检测试验,对泥浆中轻烃(C1-C12)、萃取烃(C1-C35)和岩石冷溶烃进行动态检测,研究其烃类组成及变化特征,对钻进中真假油气显示、油气层质量及产能大小、油气烃类母质类型、储油层确定等及时作出解释与评价,为油气勘探与开发快速提供地球化学依据。 相似文献
303.
J. Martinez-FrÍAs A. Delgado M. MillÁN E. Reyes F. Rull D. Travis R. Garcia F. LÓPez-Vera J. A. RodrÍGuez-Losada J. A. Martin-Rubi J. Raya E. Santoyo 《Journal of Atmospheric Chemistry》2005,52(2):185-202
Specific studies about the stable isotope composition (18O/16O and D/H) of atmospheric icy conglomerations are still scarce. The present work offers, for the first time, a very detailed
analysis of oxygen and hydrogen isotopic signatures of unusually large ice conglomerations, or “megacryometeors”, that fell
to the ground in Spain during January 2000. The hydrochemical analysis is based on the bulk isotopic composition and systematic
selective sampling (deuterium isotopic mapping) of eleven selected specimens. δ18O and δD (V-SMOW) of all samples fall into the Meteoric Water Line matching well with typical tropospheric values. The distribution
of the samples on Craig's line suggests either a variation in condensation temperature and/or different residual fractions
of water vapour (Rayleigh processes). Three of the largest megacryometeors exhibited unequivocally distinctive negative values
(δ18O = −17.2%0 and δD = −127 %0 V-SMOW), (δ18O = −15.6%0 and δD = −112%0 V-SMOW) and (δ18O = −14.4%0 and δD = −100%0 V-SMOW), suggesting an atmospheric origin typical of the upper troposphere. Theoretical calculations indicate that the vertical
trajectory of growth was lower than 3.2 km. During the period in which the fall of megacryometeors occurred, anomalous atmospheric
conditions were observed to exist: a substantial lowering of the tropopause with a deep layer of saturated air below, ozone
depression and strong wind shear. Moreover, these large ice conglomerations occurred during non-thunderstorm conditions, suggesting
an alternative process of ice growth was responsible for their formation. 相似文献
304.
Hydrogen and oxygen isotope compositions of eclogites from the Dabie Mountains and geodynamic implications 总被引:3,自引:0,他引:3
Heterogeneous δ18O values as low as - 2.6‰ to+7.0% are observed for ultrahigh pressure eclogites from the Dabie Mountains in East China. Oxygen
isotope equilibrium has been approached between the eclogite minerals, suggesting that the rocks would have acquired the unusual
δ18O values prior to ultrahigh pressure metamorphism by interaction with18O-depleted fluid. δD values of hydroxyl-bearing are between — 51% and - 83‰, precluding the possibility of paleoseawater involvement.
The only likely fluid is ancient meteoric water that exchanged oxygen isotopes with the eclogite precursor (a kind of basaltic
rocks) formerly resident on the continental crust. This suggests a crustal recycling process in the suture zone of late subduction.
Because silicate minerals undergo rapid oxygen isotope exchange at mantle pressures, preservation of the isotopic signature
of meteoric water in the eclogites indicates limited crust-mantle interaction and thus a short residence time (<20 Ma) when
the plate containing the eclogite precursor was subducted to mantle depths. The agreement in oxygen isotope temperatures for
different mineral pairs suggests a rapid cooling and ascent process for the eclogites subsequent to their formation at mantle
depths.
Project supported by the National Natural Science Foundation of China and the Chinese Academy of Sciences. 相似文献
305.
德清序村萤石矿的同位素研究 总被引:4,自引:0,他引:4
本文公布序村萤石矿的氢和锶同位素分析结果.讨论了成矿溶液和成矿物质Sr、Ba、Ca的来源,指出成矿溶液中存在有HF和SiF_4. 相似文献
306.
根据西窑地区地表水、地下水、降水中同位素的组成特征,确定了该区雨水线方程,并以δ ̄(18)O高程效应,氚的埋深效应,论述了西窑水源地补给、径流条件以及它与源涡水源地的关系,即二水源地虽都开采三叠系基岩裂隙水,但不属于同一含水系统,说明西窑饮用天然矿泉水水源地选址合理。 相似文献
307.
稳定同位素和元素组成判定潜水河雨后地表径流水的构成 总被引:5,自引:1,他引:5
潜水雨后地表径流由地表下潜水、雨水地面上径流、雨水风化层径流构成,三部分水均随河道流量的增减而增减。其中地表下潜水超过一半,雨水挤压和置换雨前地表下潜水的作用是该流域降雨形成产流的重要作用。雨水地面上径流在流量过程线退水段转折点附近基本消失。 相似文献
308.
Alfons V. Larcher Robert Alexander Steven J. Rowland Robert I. Kagi 《Organic Geochemistry》1986,10(4-6)
Acid-catalysed alkyl hydrogen exchange and configurational isomerisation has been studied in a series of acyclic isoprenoid acids when they were heated at 160°C in the presence of a montmorillonite. Hydrogen exchange occurred between the adsorbed water of the clay surface and the a position of the isoprenoid acids. In cases where this position was chiral, exchange was accompanied by configurational isomerisation. Configurational isomerisation occurred more slowly in experiments conducted without a clay matrix in the presence of water. These results have been rationalized in terms of a reaction mechanism involving protonation of the carbonyl oxygen causing enolization and consequent hydrogen exchange at the a position of the acids. This mechanism was used to account for the relatively fast rate of isomerisation of C-2 chiral centres in sedimentary acyclic isoprenoid acids during maturation. 相似文献
309.
水电解制氢设备是高空探测施放气球的保障,对高空业务是一个重要环节。为确保日常工作用氨安全,有必要作电解槽定期维修,维护。 相似文献
310.