蜀南纳溪-合地区嘉陵江组天然气地球化学特征及其气源

通过分析纳溪—合江地区嘉陵江组天然气组分,碳、氢同位素组成以及该区烃源岩发育特征,认为嘉陵江组天然气为混源气,主要为下二叠统栖霞组—茅口组碳酸盐岩烃源岩生成的油型干气,混有下二叠统梁山组和上二叠统龙潭组生成的煤成气,下志留统龙马溪组泥质源岩可能也有贡献.研究区嘉陵江组烷烃气的氢同位素组成较重.纳溪气田烷烃气具有正常的碳...     

Fractionation of hydrogen and oxygen isotopes of gypsum hydration water and assessment of its geochemical indications

Fundamental knowledge of the isotopic fractionation between the hydration water and the mother solution and whether the primary information recorded in hydration water can be preserved or not in deposits or mines have long been unclear. In order to calculate the accurate hydrogen and oxygen isotopic fractionation factors between gypsum hydration water and its mother solution with new methods, to understand the mechanism of fractionation and synthetically assess the record-keeping abilities of the isotopic composition of hydration water during the process of diagenesis after deposition, experiments on the hydrogen and oxygen isotopic compositions of gypsum hydration water and its mother solution at different isothermal temperatures from 5 to 50°C were systematically conducted. In addition, samples from two typical gypsum deposits formed in different environmental conditions were also determined. Results show that during gypsum crystallisation, both hydrogen and oxygen isotopes show significant fractionation between the hydration water and the mother solution. The calculated hydrogen isotopic fractionation factors are <1, while the oxygen isotopic fractionation factors are >1 at temperatures from 5 to 50°C. The fractionation factors show no functional relationships with temperature. Isotopic compositions of gypsum hydration water in arid lake sediments can be used to trace the source of water and primary deposit environmental information. However, the isotopic composition of the gypsum hydration water can easily be altered by dissolution and secondary precipitation of gypsum during later diagenesis, particularly in areas with humid climate and abundant groundwater. A very careful assessment on record-keeping abilities of the primary isotopic composition of hydration water in gypsum during later diagenesis must be considered before application.     

氢气还原针铁矿紫外光协同催化双氧水氧化气体中甲醛

甲醛作为一种致畸、致癌的高毒性有机污染物,对人体健康构成威胁,如何有效去除气体中的甲醛是关注的热点问题之一。采用粒径0.84～3.35 mm的天然针铁矿矿石于300℃氢还原转化为磁铁矿纳米材料,将纳米磁铁矿固定床非均相Fenton氧化反应器与紫外光催化双氧水氧化反应器串接,对比研究了双氧水、双氧水-紫外光、磁铁矿-双氧水、磁铁矿-双氧水-紫外光4种不同反应体系中双氧水投加量、甲醛初始浓度、载气流量对甲醛净化效率的影响。通过小型质谱仪对甲醛Fenton光催化氧化产物进行在线监测及TOC碳平衡分析,探讨甲醛净化的机理。结果显示制备的磁铁矿作为催化剂去除甲醛气体效果明显,在紫外光-10%双氧水-磁铁矿协同作用下,最高去除率可达98%,且在不同气速下对气体中不同浓度的甲醛都有很好的净化效果。研究结果表明,制备的磁铁矿纳米材料催化剂在去除甲醛气体过程中起着重要作用,经紫外光均相催化的双氧水协同作用可以在常温下很好地把气体中的甲醛氧化为CO₂,是一种低成本的有机废气净化技术方法。     

HIGH-ACCURACY ANALYSIS OF SOIL HYDROGEN ANOMALY IN FAULT ZONE

Hydrogen is recognized as one of the most useful gases to detect fault activities. Based on long-term high-accuracy soil hydrogen observation data in fault zones, the paper evaluates the reliability of data according to the distribution of measurements. Through the evaluation of earthquake-reflecting ability of hydrogen concentration, we consider that there is a certain corresponding relationship between hydrogen concentration and seismic activity and we present the judging index for this anomaly. Hydrogen concentration characteristics with the earthquakes within the range of 350km around the station were analyzed, especially the two earthquakes, which occurred on October 24, 2010 and March 8, 2011 in Taikang, Henan Province, with magnitude M_S4.6 and M_S4.1 respectively. The observation station is located at Xiaxian in Shanxi Province, 300km away from the epicenter. In a week before the two earthquakes, high-accuracy soil hydrogen concentration measurements showed similar anomaly variation, which was increasing abruptly, then decreasing, and after the earthquakes it returned to background level. Overall, the changing scope was more than 20 times of the background value. We concluded that the anomaly was affected by tectonic setting of the earthquakes. The similar hydrogen distribution pattern recorded at the same station is attributed to the same tectonic position and focal mechanism solution. The hydrogen could be an effective tool for short-term and imminent earthquake prediction, which provides reference for short-term and imminent earthquake prediction in areas with high earthquake risk.     

黑河流域不同生境植物水分来源及环境指示意义

选择黑河流域三种典型生境类型(绿洲、 绿洲-荒漠过渡带、 荒漠), 通过分析其不同植物木质部水分与其土壤潜在水源稳定氢(δD)和氧(δ¹⁸O)同位素组成, 研究了不同生境中植物的水分来源情况. 结果表明: 荒漠生境中植物倾向于利用深层土壤水(>160 cm); 绿洲-荒漠过渡带中沙蒿和沙拐枣主要利用20~40 cm层位的土壤水, 梭梭可能的利用层位是60~80 cm, 花棒可能利用100 cm左右的水分, 柽柳则利用120 cm以下的土壤水; 绿洲植物吸水层位多集中在0~100 cm, 其中, 假苇拂子茅可能水源是20 cm左右的土壤水, 玉米则为20~40 cm, 柽柳和杨树的吸水层位为60 cm左右, 棉花则是利用80 cm左右的水分. 稳定性同位素估测各生境植物水分来源的结果与其土壤含水量的结果一致, 同一生境中吸水层位相似的植物间存在水分来源竞争. 不同生境中植物水分来源的深浅存在递变, 从深到浅表现为荒漠>过渡带>绿洲, 不同生境同种植物也存在同样变化, 说明植物稳定氢氧同位素组成可以用来指示干旱区绿洲化、 荒漠化过程.     

一氧化氮和过氧化氢对万寿菊不定根形成的影响

以万寿菊（Tagetes erecta L.）为试材,研究了一氧化氮（NO）和过氧化氢（H2O2）对植物不定根形成中的影响及其相互关系。结果表明,外源NO供体肖普纳（SNP）和H2O2可显著地促进万寿菊外植体不定根的形成,且呈现明显的剂量效应,最适的SNP和H2O2浓度分别为50 μM和200 μM。NO和H2O2共同处理的万寿菊不定根的数量和根长显著高于NO或H2O2单独处理。NO在H2O2诱导万寿菊不定根形成的信号途径中起了重要作用;同时,H2O2包含在NO诱导不定根形成途径中。NO引起万寿菊外植体内源H2O2含量增加,H2O2亦促进内源NO积累。可见,NO和H2O2在万寿菊不定根形成过程中具有协同诱导效应,两者在促进不定根形成过程中可能通过互作反应提高各自的信号水平。     

夏县地震台痕量氢观测技术与地震关系研究

研究夏县地震台痕量氢气与气温、气压及降雨量的变化关系,与理论固体潮进行对比,重点对痕量氢气突变时段进行分析。结果表明,该测项具有较好的短临及临震异常对应关系,对判断地震短临异常有一定指示意义,体现痕量氢观测技术的可行性,对进一步开展痕量氢观测奠定基础。     

Application of stable isotope tracing technologies in identification of transformation among waters in Sanjiang Plain, Northeast China

In order to investigate the transformation among the precipitation,groundwater,and surface water in the Sanjiang Plain,Northeast China,precipitation and groundwater samples which were collected at the meteorological station of the Sanjiang Mire Wetland Experimental Station,Chinese Academy of Sciences and the surface water which collected from the Wolulan River were used to identify the transformation of three types of water.The isotope composition of different kinds of water sources were analyzed via stable isotope(deuterium and oxygen-18) investigation of natural water.The results show a clear seasonal difference in the stable isotopes in precipitation.During the cold half-year,the mean stable isotope in precipitation in the Sanjiang Plain reaches its minimum with the minimum temperature.The δ18O and δD values are high in the rainy season.In the Wolulan River,the evaporation is the highest in August and September.The volume of evaporation and the replenishment to the river is mostly same.The groundwater is recharged more by the direct infiltration of precipitation than by the river flow.The results of this study indicate that the water bodies in the Sanjiang Plain have close hydrologic relationships,and that the transformation among each water system frequently occurs.     

Neutral hydrogen in nearby 3C radio galaxies

Observations of three nearby 3C radio galaxies, 3C430, 3C449, and 3C465, with the Nan?ay radio telescope (France) reveal for the first time the 21 cm absorption line of neutral hydrogen. The line is blue shifted by several hundred km/s in all three objects. This can probably be explained by an outflow of neutral hydrogen from the parent galaxies. Translated from Astrofizika, Vol. 51, No. 4, pp. 535–542 (November 2008).     

Cold gas accretion in galaxies

Evidence for the accretion of cold gas in galaxies has been rapidly accumulating in the past years. HI observations of galaxies and their environment have brought to light new facts and phenomena which are evidence of ongoing or recent accretion: (1) A large number of galaxies are accompanied by gas-rich dwarfs or are surrounded by HI cloud complexes, tails and filaments. This suggests ongoing minor mergers and recent arrival of external gas. It may be regarded, therefore, as direct evidence of cold gas accretion in the local universe. It is probably the same kind of phenomenon of material infall as the stellar streams observed in the halos of our galaxy and M 31. (2) Considerable amounts of extra-planar HI have been found in nearby spiral galaxies. While a large fraction of this gas is undoubtedly produced by galactic fountains, it is likely that a part of it is of extragalactic origin. Also the Milky Way has extra-planar gas complexes: the Intermediate- and High-Velocity Clouds (IVCs and HVCs). (3) Spirals are known to have extended and warped outer layers of HI. It is not clear how these have formed, and how and for how long the warps can be sustained. Gas infall has been proposed as the origin. (4) The majority of galactic disks are lopsided in their morphology as well as in their kinematics. Also here recent accretion has been advocated as a possible cause. In our view, accretion takes place both through the arrival and merging of gas-rich satellites and through gas infall from the intergalactic medium (IGM). The new gas could be added to the halo or be deposited in the outer parts of galaxies and form reservoirs for replenishing the inner parts and feeding star formation. The infall may have observable effects on the disk such as bursts of star formation and lopsidedness. We infer a mean “visible” accretion rate of cold gas in galaxies of at least . In order to reach the accretion rates needed to sustain the observed star formation (), additional infall of large amounts of gas from the IGM seems to be required.