青藏高原放牧强度空间化方法与应用

人类活动强度空间化是分析人类活动区域差异及其变化过程的基础,也是准确辨识土地变化驱动因素、合理调控人类活动的科学依据。当前人类活动强度研究多以数理方法对代用指标进行空间化,缺乏对人类活动机理过程的反映,也制约了人类活动强度空间异质性的展现。本文以青藏高原放牧活动为研究对象,在综合放牧喜好和草地管理策略的基础上,从放牧行为机理的角度,提出了区分放牧区与非放牧区的方法;以放牧密度衡量草地整体放牧压力,以放牧概率刻画放牧活动的空间差异,构建了区域放牧强度空间化模型。并以高原典型牧业县—泽库县为例,基于乡镇级牧业数据和自然地理基础信息进行了实证研究。结果表明：空间化结果较好反映了泽库县放牧强度的空间特征;直接指标的选取和客观的赋值方法提高了放牧强度空间化结果的准确性;比现有研究结果更能体现出县域内放牧强度的空间差异,且放牧强度变化过程与同期NDVI值变化具有较好的耦合性。本文为人类活动空间化方法研究提供了有益参考。     

岩溶地区人类活动的水文效应研究现状及展望

在全球气候变化背景下,加之岩溶生态系统的脆弱性及敏感性,地表水与地下水交换迅速,岩溶水动力系统对人类活动及其造成的生态环境变化反馈敏感。岩溶地区人类活动导致的植被退化、石漠化等环境问题已对岩溶地区的水文水循环过程造成了严重影响,水资源问题已成为岩溶地区发展的重要限制因素。本文在对岩溶生态系统及水文环境特性分析的基础上,从土地利用变化的水文效应,人类活动对降水—径流的影响、岩溶水资源的开发利用、岩溶地下水污染及水文模型在岩溶地区的应用等方面,概述了岩溶地区人类活动水文效应的相关研究现状与不足,总结了未来岩溶地区人类活动水文效应的5个研究趋势,并探讨了研究中的重点及难点问题。     

Human’s digital footprints on the Qinghai-Tibet Plateau: Variations during festivals and impacts on nature reserves

Mobile internet and wireless communication technologies have produced unprecedented location-aware data. Such big geospatial data can be used as a proxy measure of the ‘digital footprints' left by us on the planet and provide a valuable opportunity to understand the dynamic and short-term human disturbance on the nature at fine scales. This study investigated the spatiotemporal variations of human's digital footprints on the Qinghai-Tibet Plateau using smartphone-users-generated Tencent's location request data. The results showed that human's digital footprints cover less than 5% of Qinghai and Tibet, exhibiting either a U-shaped or an N-shaped temporal change pattern during the major festivals. Spatial changes of the digital footprints manifested a transition process from dispersion to concentration in Xining and Lhasa. Human disturbance assessment of seven large nature reserves on the plateau showed that the Qinghai Lake is the most disturbed one as shown by 14.6% of its area is stained with human digital footprints and the areal average of footprint intensity is 1.59, and the disturbance was significantly escalated during the National Day holiday. By contrast, the Qangtang and Hoh Xil are the least affected nature reserves with the two indices less than 1% and 0.1, respectively.     

利用δ53Cr定量评价Cr(VI)还原程度的实验研究

地下水污染的原位修复是当今国际上净化地下水最具发展前景的新技术,但对铬污染地下水原位修复尚未有科学有效的评价方法。定量评价地下水中Cr(Ⅵ)的被还原程度成为保护与修复铬污染地下水的关键问题。通过室内Cr(Ⅵ)的还原实验,分析Cr(Ⅵ)在还原过程中铬稳定同位素变化规律,研究其分馏机理,探索利用铬同位素定量评价地下水中Cr(Ⅵ)还原程度的可行性。研究结果表明:Cr(Ⅵ)在被还原成Cr(Ⅲ)过程中,发生明显的同位素分馏,即反应物中53Cr逐渐富集,同时生成物中52Cr逐渐富集;分馏过程可用瑞利分馏模型描述,分馏系数α为常数0.99842。表明δ53Cr能够定量评价水体中Cr(Ⅵ)的还原程度,为评价地下水铬污染修复提供了新途径。     

溶胶凝胶法制备（Eu^2＋，Dy^3＋）SrAl2O4

采用无机盐溶胶-凝胶法制备了颗粒均匀的形态为针状的(Eu2+,Dy3+)SrAl2O4纳米粉体.通过TG-DTA分析和X射线衍射和扫描电镜分析方法,对样品进行了微观结构和表面形态的表征.研究了纳米(Eu2+,Dy3+)SrAl2O4粉体在不同烧结温度下固相反应过程和成相规律.实验结果表明,当样品的烧结温度为500 ℃时是单一的Sr(NO3)2晶相;750 ℃左右生成了Sr3Al2O6,并伴有少量SrAl2O4晶体;1 100 ℃是生成了结晶度良好的针状纳米(Eu2+,Dy3+)SrAl2O4粉体.通过计算,样品粉体晶粒平均为80～100 nm.该晶体粒度随烧结温度升高而逐渐变大.     

Production of high titania slag by Electro-Slag Crucible Melting (ESCM) process

In this research, ilmenite concentrate of Iran region successfully was smelted by Electro-Slag Crucible Melting (ESCM) process to produce TiO₂-rich slag as primary product and pig iron as by-product. Moreover, effects of reductant (carbon) amount and smelting time on TiO₂ and FeO content of slag and iron recovery were studied. It is found that addition of carbon excess to stoichiometric amount decreases the iron recovery and TiO₂ content in slag. If the smelting time keeps between 0 to 17 min, the TiO₂ content and iron recovery will be increased, whereas smelting time in excess of 17 min will cause products decline significantly. At optimum conditions, TiO₂ content in slag and the iron recovery are 70 wt.% and 84%, respectively. Kinetic studies proved that the reduction of equivalent FeO was first-order reaction. The studies made by X-ray diffraction analysis showed that formation of the titanium sub-oxides (Ti₃O₅ and Ti₂O₃) causes the decrease in iron recovery and TiO₂ content.     

Diffusion-controlled corona reaction and overstepping of equilibrium in a garnet granulite, Yenisey Ridge, Siberia

Diffusion modelling is applied to layered garnet–pyroxene–quartz coronas, formed by a pressure-induced reaction between plagioclase and primary pyroxene in a metabasic granulite. The reconstructed reaction involves some change in composition of reactant minerals. The distribution of minerals between layers is satisfactorily explained by diffusion-controlled reaction with local equilibrium, in which the diffusion coefficient for Al was smaller than those for Fe, Mg and Ca by a factor of approximately four. Diffusion of Mg towards plagioclase implies a chemical-potential gradient for MgO component in a direction opposite to the changing Mg content of garnet; this is explained by the influence of Al₂O₃ on the chemical potential of the pyrope end-member. Grain-boundary diffusion is suggested to have operated, possibly with composition gradients different from those in the bulk minerals. Chemical-potential differences across the corona are estimated from the variation in garnet composition, enabling affinity (the free energy change driving the reaction) to be estimated as 6.9±1.8  kJ per 24-oxygen mole of garnet produced. This implies that the pressure for equilibrium among the minerals was overstepped by 1.4±0.4  kbar. The probable P–T conditions of reaction were in the range 650–790  °C, 8–10  kbar. Assuming a timescale of reaction between 10⁶ and 10⁸ years, estimated diffusion coefficients for Fe, Mg and Ca are in the range 9×10⁻²³ to 5×10⁻²⁰ m² s⁻¹. These are consistent with experimental values in the literature for solid-state diffusion, including grain-boundary diffusion.     

纳米铁还原高浓度硝基苯的实验

采用液相还原法制备纳米铁粒子,粒径约为50 nm,主要成分为ɑ-Fe。实验研究了纳米铁还原高浓度硝基苯的效果及反应动力学。结果表明:自制的纳米铁具有很高的活性,短时间内能将高浓度硝基苯彻底还原,效果远优于普通铁粉。当摩尔比满足n纳米铁∶n硝基苯=4∶1时,纳米铁还原硝基苯属于一级反应动力学,反应速率常数和半衰期分别为0.159 3 h-1和4.351 2 h。整个实验过程中,ρ(DO)在0.5 mg/L以下,pH值约为9.0,体系呈弱碱性的厌氧环境,有利于厌氧微生物的生长。纳米铁反应后的产物为Fe6(OH)12CO3和MgFe3O4,且以Fe6(OH)12CO3为主。纳米铁反应后较以前比粒径变化不大,分散性较好,但表面被严重腐蚀。     

硅灰石与盐酸快速反应规律及应用研究

在反应体系pH≤1．5时，硅灰石与盐酸快速反应，经40－100min反应后，体系分为固液两相，固相为水合 二氧化硅沉淀及少量酸不溶性杂质矿物，液相为以溶胶形式存在的二氧化硅和大量CaCl2；当反应pH值在0．3－0．6时，液相中以硅溶胶形式存在的二氧化硅量最大，占总量46％以上。快速反应中仍存在少量具有慢速反应特征的柱状颗粒，该颗粒中心CaSiO3很难反应完全。快速反应产物经表面积较大，若在酸反应前添加有机助剂聚乙二醇（PEG）,反应pH值在0．3－0．6。反应时间40－100min，反应后用KOH溶液中和到pH＝4，可制备高比表面积多孔SiO2，比表面积＞430m^2／g，孔径1－2nm。     

福建龙湖40多年来环境地质演化及其警示

本文首次报道福建境域湖泊沉积物中有毒元素含量的变化。根据对晋江市龙湖 4 0多年来沉积柱的环境地质演化的研究 ,发现其污染度自 1976～ 2 0 0 2年呈急速上升态势。其中上升最快的元素为 Cd、Hg、As、Pb、Cu、Zn、Cr,尤以 Cu最为典型 ,其污染度变化可分为三个时段 :11976～ 1984年污染指数 0 .6 7,为微污染 ;21984～ 1993年污染指数 0 .86 ,为轻污染 ;31993～ 2 0 0 2年污染指数 2 .37,为重污染。第二时段的污染度为第一时段的 1.3倍 ,第三时段的污染度为第一时段的 3.5倍。表明污染度增加是十分迅速和严峻的。值得引起我们高度关注的是 ,1984～ 2 0 0 2年 ,19年间龙湖中剧毒元素 Hg、As、Pb的平均含量均超越国家标准 ,为污染环境。 2 0 0 2年 4月龙湖表面沉积中这 3种剧毒元素分别为 1976～ 1984年时段含量最低值的 4 6 .3倍、3.3倍、1.9倍 ,已大大超过其“警戒线”(如 Hg为标准值的 4 .4倍 ) ,显示龙湖污染的严重性。龙湖环境地质条件的日益恶化 ,对人群健康已造成一定影响 (如癌症病人日益增加 ) ,这也警示着日本水俣病可能在该地区重演