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41.
高温高压下水岩界面反应与金的迁移富集 总被引:1,自引:0,他引:1
高温高压下水岩界面反应与金的迁移富集王玉荣阚小凤王志强(中国科学院广州地球化学研究所,广州510640)关键词水岩界面反应自发电池实验地球化学本实验以哈达门沟[1]及东坪金矿[2]为地质背景,研究钾长石岩中金矿化富集的物理化学条件。该区金矿既与早期变... 相似文献
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Three meromictic lakes in the World Heritage Area of south-west Tasmania possess unusual microbiological communities. Their meromixis is maintained by periodic incursions of brackish water from the nearby Gordon River which, in its lower reaches, is a salt-wedge estuary. In 1977 the construction of a dam in the middle reaches of the river restricted penetration of the salt-wedge and meromixis rapidly declined in all three lakes. A palaeolimnological study was carried out on one of the lakes, Lake Fidler, firstly to determine the history of meromixis and its associated microbiological communities, and secondly to assess whether the recent and rapid decline of meromixis is inconsistent with natural rates of development of the Gordon River meromictic lakes. One part of this study included the analysis of the stratigraphy of fossil diatoms from a 17-metre sediment core dating back 8000 yrs. Detrended Correspondence Analysis and Analog Matching were used to compare diatom species assemblages in core samples with diatom samples from a reference dataset consisting of a selection of lake and river sites in the lower Gordon River valley. Five distinct stratigraphic zones were identified in the core. These zones indicated specific stages in the development of the Gordon River lakes from river backwaters to ectogenically-maintained meromictic lakes which will, finally, become terrestrialised by encroaching rainforest. The onset of a stratified water column was identified by the emergence of a dominant freshwater algal flora which suggested that the lake had developed a mixolimnion and become meromictic ca. 2070 ± 50 14C yrs ago. In the context of this long history of meromixis, the rapid demise in meromictic stability following construction of the dam is judged to be inconsistent with natural rates of development. The palaeolimnological studies, of which this paper is one part, prompt recommendations for a management strategy to prevent the further decay of these meromictic lakes in the World Heritage Area. 相似文献
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本文以等物质的量的反应规则建立了岩盐、芒硝中各种化合物的质量分数的计算公式。这些公式既符合法定计量单位的要求,又方便计算。 相似文献
45.
Oxygen Isotope Exchange Kinetics Between Coexisting Minerals and Water in the Aral Granite Pluton of the Altay Mountains, Northern Xinjiang 总被引:2,自引:0,他引:2
Liu Wei Research Center of Mineral Resources Exploration Chinese Academy of Sciences Chinese Academy of Sciences BeijingHe Baichu Changsha Institute of Geotectonics Chinese Academy of Sciences Changsh Hunanand Chen ZhenshengYichang Institute of Geology Mineral Resources Chinese Academy of GeologicalSciences Yichang Hubei 《《地质学报》英文版》1996,70(4)
Coexisting quartz, feldspar and biotite vary widely in their δ18O values and display a remarkable 18O/16O disequilibrium relation; especially, a quartz-feldspar reversal (△ 18OQUartz_feldspar< 0) exsists in the Aral granite pluton of the Altay Mountains, northern Xinjiang. The 18O / 16O exchange reaction definitely occurred between granite and water. Initial δ18O values of the granite and exotic fluid are evaluated by the mass balance consideration. The conventional method of discrimination between various magma derivations simply with δ18O values of either whole rock or separate minerals is misleading and unreliable. Experiments carried out by the authors show that the 18O / 16O exchange reaction is not accompanied by what geologists describe as petrological and mineralogical alteration effect. This decoupling relation implies that exchange reaction occurs at a relatively high temperature during subsolidus-postmagmatic cooling of magmas. The exchange mechanism is mainly diffusion-controlled. It is 相似文献
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本文对Ni40Mn30Fe30合金与在不同焙烧温度下得到的含水叶蜡,在高温超高压下的反应进行了实验研究,温度测至1420℃,压是至5.5GPa,研究了该反应的物质-化学机制,以及反应速率与温度,压力,含水量等参数的关系,对高压下物质迁移运动的固有特征进行了探讨。 相似文献
48.
This paper presents a method of establishing a hydrothermal ore-forming reaction system.On the basis of the study of four typical hydrothermal deposits,the following conclusions concerning geochemical dynamic controlling during hydrothermal mineralization have been sions concerning geochemical dynaamic controlling during hydrothermal mineralization have been drawn:(1)The regional tectonic activities control the concentration and dispersion of elements in the ore-forming process in terms of their effects on the thermodynamic nature and conditions of the ore-forming reaction system.(2)During hydrothermal mineralization the activites of ore-bearing faults can be divideb into two stages:the brittle splitting stage and the brittle-tough tensing stage,which would create characteristically different geodynamic conditions for the geochemical thermodynamic ore-forming system.(3)The hydrothermal ore-forming reaaction system is an open dynamic system.At the brittle splitting stage the system was so strongly supersaturated and unequilibrated as to speed up and enhance the crystallization and differentiation of ore-forming fluids.And at the brittle-tough tensing stage,the ore-forming system was in a weak supersaturated state;with decreasing temperature and pressure the crystallization of oreforming material would show down,and it can be regarded as an equilibrated state.(4)In the lates stages of hydrothermal evolution,gold would be concentrated in the residual ore-forming solution.The pulsating fracture activite in this stage led to the crush of pyrite ore and it was then filled with gold-enriched solution,forming high-grage“fissure”gold ore.This ore-forming process could be called the coupling mechanism of ore formation. 相似文献
49.
Ralph Lehmann 《Journal of Atmospheric Chemistry》2004,47(1):45-78
When the output of a complex chemical model is analysed, a typical topic isthe determination of pathways, i.e., reaction sequences, that produce ordestroy a chemical species of interest.A representative example is the investigation of catalytic ozone destruction cycles in the stratosphere.An algorithm for the automatic determination of pathways in any given reactionsystem is presented. Under the assumption that reaction rates are known, it finds all significant pathways, i.e., all pathways with a rate above a prescribed threshold.The algorithm forms pathways step by step, starting from single reactions.The chemical species in the system are consecutively considered as `branching points'.For every branching-point species, each pathway producing it is connected witheach pathway consuming it.Rates proportional to `branching probabilities' are calculated.Pathways with a rate that is smaller than a prescribed threshold arediscarded.If a newly formed pathway contains sub-pathways, e.g., null cycles, it is split into these simpler pathways.In order to demonstrate the performance of the algorithm, it has been applied to the determination of catalytic ozone destruction cycles and methaneoxidation pathways in the stratosphere. 相似文献
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