Extension of Biot theory to the problem of saturated microporous elastic media with isolated cracks or/and vugs

The purpose of this paper is to develop the macroscopic model of hydro‐mechanical coupling for the case of a porous medium containing isolated cracks or/and vugs. In the development, we apply the asymptotic expansion homogenization method. It is shown that the general structure of Biot's model is the same as in the case of homogeneous medium, but the poro‐elastic parameters are modified. Two numerical examples are presented. They concern the computations of Biot's parameters in isotropic and anisotropic cases. It can also be seen how the presence of near‐zero‐volume cracks influences Biot's parameters of the porous matrix. It can significantly affect the coupled hydro‐mechanical behaviour of damaged porous medium. Copyright © 2012 John Wiley & Sons, Ltd.     

A self‐consistent approach for micro–macro modeling of elastic–plastic deformation in polycrystalline geomaterials

This paper is devoted to multi‐scale modeling of elastic–plastic deformation of a class of geomaterials with a polycrystalline microstructure. We have extended and improved the simplified polycrystalline model presented in [Zeng T. et al., 2014. Mech. Mater. 69 (1):132–145]. A rigorous and fully consistent self‐consistent (SC) scheme is proposed to describe the interaction among plastic mineral grains. We have also deeply discussed the numerical issues related to the numerical implementation of the proposed micromechanical model. The efficiency of the proposed model and the related numerical procedure is evaluated in several representative cases. We have compared the numerical results respectively obtained from the fully SC model and two simplified ones. It is found that the SC model produces a softer stress–strain response than that of the simplified models. The comparisons between the estimation of overall behavior of a granite in different loading conditions and experimental data are also conducted. Copyright © 2015 John Wiley & Sons, Ltd.     

Multi‐species diffusion analysis in porous media under various dry density and temperature conditions: molecular dynamics simulation,homogenization analysis,and finite element method

In porous media, chemical species that dissolve in pore water can be transported via diffusion mechanisms or advective fluxes, close to or far away from where precipitation occurs. In the case of a high‐level radioactive waste disposal system, compacted bentonite is used in a buffer material in an engineering barrier system to minimize the amount of specific nuclides that breach into the surrounding host rock. To minimize breaching, it is very important to understand the transport mechanism of multiple chemical species in porous media. In the following research, we introduced FEM analysis methods using the results of the molecular dynamics simulation and homogenization analysis (MD/HA) method. First, the diffusion coefficients of ions (Cl^?, I^?, and Na⁺) in different water layers of Na‐beidellite were calculated using the MD/HA procedure under various dry density (1.2, 1.6, and 2.0 Mg/m³) and temperature (293, 323, and 363 K) conditions. Next, using FEM analysis that used the MD/HA results as input parameters, the diffusion behaviors of ions in porous media were calculated. The results indicate that the diffusion coefficients of the interlayer water in Na‐beidellite are different from the diffusion coefficients under dry density conditions. Further, the concentration profiles (C_t/C₀) of iodine and chloride are proportional to temperature but inversely proportional to dry density. Copyright © 2014 John Wiley & Sons, Ltd.     

Chloride transfer in cement‐based materials. Part 2. Experimental study and numerical simulations

This second part of the work deals firstly with carrying out materials characterization, mainly mercury intrusion porosimetry and chloride electrodiffusion tests on two cement pastes. Experimental data allowed fixing the perturbation parameter ? and other dimensionless numbers highlighted in part I of this work. Secondly, a series of parametric simulations were performed in order to compute the chloride diffusion coefficient through a gradual complexity of the elementary cell, approaching as close as possible the real microstructure of the cement pastes tested. Results highlighted that taking into account microstructure parameters (porosity, tortuosity and constrictivity) allows to approach the experimental diffusion coefficient. However, they also showed that electrochemical interactions between ions and the liquid‐solid interface, and the multi‐scale character of cementitious material microstructure, must be considered. Copyright © 2012 John Wiley & Sons, Ltd.     

Permeability determination of porous media using large‐scale finite elements and iterative solver

The problem of finite element simulation of incompressible fluid flow in porous medium is considered. The porous medium is characterized by the X‐ray microtomography technique in three dimensions. The finite calculus‐based stabilization technique is reviewed to implement the equal order finite element interpolation functions for both velocity and pressure. A noble preconditioner, the nodal block diagonal preconditioner, is considered whose performance is thoroughly investigated. Combining this preconditioner with a standard iterative solver during the computational homogenization procedure, it is possible to carry out the large‐scale fluid flow simulation for estimating permeability of the porous medium with reasonable accuracy and reliability. Copyright © 2013 John Wiley & Sons, Ltd.     

A micromechanical modeling of ductile behavior of a porous chalk: Formulation,identification, and validation

Porosity strongly affects the overall ductile behavior of cohesive geomaterials undergoing plastic deformation. In the present paper, we proposed an original micromechanical approach that suitably couples Drucker–Prager‐type plasticity, evolving porosity under general triaxial loadings. The resulting model has the advantage to be based on a single macroscopic yield function, which also plays the role of plastic potential. It is shown that this yield function is particularly appropriate to account for the pore collapse and plastic shearing mechanisms that govern the mechanical behavior of the studied Lixhe chalk. Finally, the new model is implemented and validated by comparison to triaxial tests data, covering a wide range of confining pressures. Copyright © 2011 John Wiley & Sons, Ltd.     

内蒙古宜里钼矿流体包裹体特征及其地质意义

内蒙古宜里钼矿是大兴安岭北段新近发现的具有大型钼矿前景的中型斑岩型钼矿床。矿区地质特征简单,已发现钼矿体主要分布在F4断层的上盘,辉钼矿呈细(网)脉状产出。赋矿围岩主要为二长花岗岩、正长花岗岩和卧都河组地层。流体包裹体研究表明,宜里钼矿石英脉中的流体包裹体主要呈星散状随机分布或成群分布,其大小集中在3~10μm,形态多样,包裹体类型主要有气液两相、纯液相、纯气相包裹体、含子晶矿物的多相包裹体。包裹体均一温度和盐度呈现出双峰式分布特征,均一温度峰值分别集中在165℃~215℃和265℃~340℃,w(NaCl)%峰值分别集中在为3~7和11~14。成矿流体的密度主要集中在0.613 g/cm3~0.972 g/cm3。综合成矿阶段和成矿特征,成矿流体类型为高温低盐度和中温低盐度的中等密度的成矿流体。根据成矿压力估算,矿床形成古深度约为1.24~1.52km。包裹体激光拉曼光谱分析表明包裹体中气相和液相成分均以H2O、CO2为主,并发现有含黄铜矿子晶包裹体,代表了成矿阶段的流体特征。     

Application of Hydrothermal Diamond Anvil Cell to Homogenization Experiments of Silicate Melt Inclusions

The homogenization of silicate melt inclusions （SMIs）,small droplets of silicate melt trapped in magmatic minerals,is an important component of petrogenetic and magmatic research.Conventional homogenization experiments on SMIs use microscope-mounted heating stages capable of producing high temperatures at 1 atm and cold-seal high-pressure vessels.Heating stages are generally used for SMIs with low internal pressures and allow in situ observations of the homogenization processes.In contrast,cold-seal high-pressure vessels are generally used to heat SMIs that have high internal pressures,although the homogenized SMIs can only be observed after quenching in this approach.Here we outline an alternative approach that uses a hydrothermal diamond anvil cell （HDAC） apparatus to homogenize SMIs.This is the only current method wherein phase changes in high-internal-pressure SMIs can be observed in situ during homogenization experiments,which represents an advantage over other conventional methods.Using an HDAC apparatus prevents high-internal-pressure SMIs from decrepitating during heating by elevating their external pressure,in addition to allowing in situ observations of SMIs.The type-V HDAC that is currently being used has a shorter distance between the sample chamber and the observation window than earlier types,potentially enabling continuous observation of the processes involved in heating and SMI homogenization through an objective lens with a long working distance.Homogenization experiments using HDAC require that a number of steps,including HDAC preparation,sample preparation,sample loading,preheating,and formal heating,be carefully followed.Homogenization experiments on SMIs within granite samples from the Jiajika pegmatite deposit （Sichuan,China） are best performed using an HDAC-based approach,because the elevated proper external pressure of these SMIs,combined with a short heating duration,helps to suppress material leakage and any reactions within the SMIs,in addition to allowing in situ observatio     

The homogenization temperature in the fluid inclusions of Ordovician halite and paleoclimatic implication

正1 Introduction The homogenization temperature of fluid inclusions reflects the temperatures of the brines from which halite crystals grew.Therefore,it is a powerful mean to reveal the paleoclimate.Northern Shaanxi Salt Basin is located in the central and eastern of Ordos Basin.We have detail petrographical research and the homogenization     

A comparative micromechanical analysis of the effective properties of a geomaterial: Effect of mineralogical compositions

In order to provide a physical interpretation of the variation of the mechanical properties of Callovo-Oxfordian argillite with mineral composition, we implement three linear homogenization schemes. The argillite is modeled as a three phase material composed of a clay matrix and inclusions of quartz and calcite. It is shown that, unlike the dilute scheme and the self-consistent scheme, the Mori-Tanaka model describes the in situ experimental data well. The determined properties are finally used in a finite element computation. The aim is to evaluate the effect of mineral composition on the elastic response of the excavation of a vertical shaft in the context of the underground laboratory of Meuse/Haute Marne.